Tectonic reconstruction of the northern Andean blocks: Oblique convergence and rotations derived from the kinematics of the Piedras–Girardot area, Colombia

A detailed kinematic study in the Piedras–Girardot area reveals that approximately 32 km of ENE–WSW oblique convergence is accommodated within a northeast-trending transpressional shear zone with a shear strain of 0.8 and a convergence factor of 2. Early Campanian deformation is marked by the incipient propagation of northeast-trending faults that uplifted gentle domes where the accumulation of sandy units did not take place. Maastrichtian unroofing of a metamorphic terrane to the west is documented by a conglomerate that was deformed shortly after deposition developing a conspicuous intragranular fabric of microscopic veins that accommodates less than 5% extension. This extensional fabric, distortion of fossil molds, and a moderate cleavage accommodating less than 5% contraction, developed concurrently, but before large-scale faulting and folding. Paleogene folding and southwestward thrust sheet propagation are recorded by syntectonic strata. Neogene deformation took place only in the western flank of this foldbelt. The amount, direction, and timing of deformation documented here contradict current tectonic models for the Cordillera Oriental and demand a new tectonic framework to approach the study of the structure of the northern Andes. Thus, an alternative model was constructed by defining three continental blocks: the Maracaibo, Cordillera Central, and Cordillera Oriental blocks. Oblique deformation imposed by the relative eastward and northeastward motion of the Caribbean Plate was modeled as rigid-body rotation and translation for rigid blocks (derived from published paleomagnetic and kinematic data), and as internal distortion and dilation for weak blocks (derived from the Piedras–Girardot area). This model explains not only coeval dextral and sinistral transpression and transtension, but also large clockwise rotation documented by paleomagnetic studies in the Caribbean–northern Andean region.     

A quantitative study relating observed shear in photospheric magnetic fields to repeated flaring

In this paper we present a quantitative evaluation of the shear in the magnetic field along the neutral line in an active region during an epoch of flare activity. We define shear as the angular difference in the photosphere between the potential magnetic field, which fits the boundary conditions imposed by the observed line-of-sight field, and the observed magnetic field. For the active region studied, this angular difference (shear) is non-uniform along the neutral line with maxima occurring at the locations of repeated flare onsets. We suggest that continued magnetic evolution causes the field's maximum shear to exceed a critical value of shear, resulting in a flare around the site of maximum shear. Evidently, the field at the site of the flare must relax to a state of shear somewhat below the critical value (but still far from potential), with subsequent evolution returning the field to the critical threshold. We draw this inference because several flares occurred at sites of maximum photospheric shear which were persistent in location.NOAA, Boulder, Colorado.     

Cyclical period changes in the dwarf novae V2051 Oph and V4140 Sgr

We report on the identification of cyclical changes in the orbital period of the eclipsing dwarf novae V2051 Ophiuchi and V4140 Sagittarii. We used sets of white dwarf mid-eclipse timings to construct observed-minus-calculated diagrams covering, respectively, 25 and 16 yr of observations. The V2051 Oph data present cyclical variations that can be fitted by a linear plus sinusoidal function with period of  22 ± 2 yr  and amplitude of  17 ± 3 s  . The statistical significance of this period by an F-test is larger than 99.9 per cent. The V4140 Sgr data present cyclical variations of similar amplitude and period of  6.9 ± 0.3 yr  which are statistically significant at the 99.7 per cent level. We derive upper limits for secular period changes of     and     for V2051 Oph and V4140 Sgr, respectively.
We have combined our results with those in the literature to construct a diagram of the amplitude versus period of the modulation for a sample of 11 eclipsing cataclysmic variables (CVs). If the cyclical period changes are the consequence of a solar-type magnetic activity cycle in the secondary star, then magnetic activity is a widespread phenomenon in CVs, being equally common among long- and short-period systems. This gives independent evidence that the magnetic field (and activity) of the secondary stars of CVs do not disappear when they become fully convective. We also find that the fractional cycle period changes of the short-period CVs are systematically smaller than those of the long-period CVs.     

Organic contaminant distributions in sediments, polychaetes (Nereis virens) and American lobster (Homarus americanus) from a laboratory food chain experiment.

A laboratory experiment was conducted to investigate the transfer of organic contaminants from an environmentally contaminated marine sediment through a simple marine food chain. The infaunal polychaete, Nereis virens, was exposed to contaminated sediment collected from the Passaic River, NJ, USA, for 70 days. These polychaetes were then fed to the American lobster, Homarus americanus, for up to 112 days. Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), 2,4,6,8-tetrachlorodibenzothiophene (TCDT), polychlorinated biphenyls (PCBs), and several chlorinated pesticides were accumulated by polychaetes following exposure to the contaminated sediment. Some of these contaminants were also accumulated by lobsters which were exposed to the contaminated sediment and/or fed contaminated polychaetes. Only the lesser chlorinated PCDDs and PCDFs (mostly tetra- and pentachlorinated congeners) and 2,4,6,8-TCDT were detected in the polychaetes and lobster. Significant alterations were noted in the PCB patterns found in both species, particularly the lobster. The non-ortho-substituted PCBs (such as congeners 77 and 126) became enriched in the PCB mixtures of the polychaetes and especially the lobsters relative to the sediment, probably because these congeners were not metabolized. These congeners and the 2,3,7,8-tetrachlorodibenzo-p-dioxin toxicity equivalents of the PCB mixtures were enriched by a factor of about six in the lobsters relative to the sediment. Elimination of PCB congeners containing vicinal hydrogens in the meta-para region is consistent with cytochrome P450IIB-type metabolism. Based on the concentration trends for some PCB congeners and chlorinated pesticide ratios measured in the lobsters during this experiment, it appears that this metabolic system is inducible in the American lobster.     

Geotechnical characteristics of mississippi delta sediments,southeast Louisiana

An investigation of the geotechnical properties of sediments from 57 boreholes drilled in West Delta and South Pass OSC Lease Areas, offshore Louisiana, indicated that sediment texture, shear strength, water content, and liquid limit vary significantly laterally and with depth. Samples are predominantly soft, fine‐grained sediments with high water content and medium to high plasticity. Firm, coarser‐grained sediments were obtained near the shoreline in South Pass OCS Lease Area and in the northern and eastern parts of West Delta OCS Lease Area. Trends in the distribution of geotechnical properties appear to be influenced by sediment texture and rate of sedimentation.     

Nature and degree of aqueous alteration in CM and CI carbonaceous chondrites

We investigated the petrologic, geochemical, and spectral parameters that relate to the type and degree of aqueous alteration in nine CM chondrites and one CI (Ivuna) carbonaceous chondrite. Our underlying hypothesis is that the position and shape of the 3 μm band is diagnostic of phyllosilicate mineralogy. We measured reflectance spectra of the chondrites under dry conditions (elevated temperatures) and vacuum (10^?8 to 10^?7 torr) to minimize adsorbed water and mimic the space environment, for subsequent comparison with reflectance spectra of asteroids. We have identified three spectral CM groups in addition to Ivuna. “Group 1,” the least altered group as determined from various alteration indices, is characterized by 3 μm band centers at longer wavelengths, and is consistent with cronstedtite (Fe‐serpentine). “Group 3,” the most altered group, is characterized by 3 μm band centers at shorter wavelengths and is consistent with antigorite (serpentine). “Group 2” is an intermediate group between group 1 and 3. Ivuna exhibits a unique spectrum that is distinct from the CM meteorites and is consistent with lizardite and chrysotile (serpentine). The petrologic and geochemical parameters, which were determined using electron microprobe analyses and microscopic observations, are found to be consistent with the three spectral groups. These results indicate that the distinct parent body aqueous alteration environments experienced by these carbonaceous chondrites can be distinguished using reflectance spectroscopy. High‐quality ground‐based telescopic observations of Main Belt asteroids can be expected to reveal not just whether an asteroid is hydrated, but also details of the alteration state.     

Framework silica structures generated using simulated annealing with a potential energy function based on an H6Si2O7 molecule

A simulated annealing technique was used to search for global and local minimum energy structures of a potential energy model for silica. The model is based on ab initio SCF MO calculations on the disilicic acid molecule, H₆Si₂O₇. Starting with 4 SiO₂ units, with the atoms randomly distributed in the unit cell, 23 distinct silica tetrahedral framework structures were found, with a variety of space group symmetries and cell dimensions. Despite the assumption of P 1 space group symmetry for the starting structure, only 7 of the local minimum energy structures were found to possess triclinic symmetry with the remainder exhibiting symmetries ranging from P c to to within 0.001 Å. Although the interaction potential for the disilicic acid molecule has a single minimum energy SiO bond length and SiOSi angle, the local minimum energy structures exhibit angles that range between 105° and 180° and bond lengths that range between 1.55 and 1.68 Å. The correlation observed for coesite and the other silica polymorphs between SiO bond length and f_s(O) is reproduced. The generated structures show a wide variety of coordination sequences, ring sizes and framework densities, the later ranging from 19.8 to 35.5 Si/1000 ų. The energies of these structures correlate with their framework densities, particularly for higher energy structures.     

Influence of the natural oxidation of the leachate organic fraction from a landfill on groundwater quality, Belo Horizonte: Minas Gerais, south-eastern Brazil

The objective of this work was to evaluate the influence of the natural degradation of the leachate organic fraction from the Belo Horizonte landfill on groundwater chemical evolution. The work focused on the modifications introduced by redox reactions in the presence of terminal electron acceptors. Twenty-one sampling points distributed along 13 monitoring wells were selected for the analysis of the chemical indicators of interest (TDS, SO ₄ ^?2 , Fe⁺², Ba, pH and Eh). The behaviour of the variables involved in the alteration of the water quality was assessed by the spatial distribution of target parameters, elaboration of redox diagrams and chemical modelling that focused on the determination of mineral saturation indexes. The study showed a trend toward pyrite precipitation, which leads to the removal of chemical species such as divalent iron and sulphur as sulphide from the system. This removal disturbs the chemical equilibrium, typically by moving the reactions to replenish the sulphate concentration present in the groundwater. This process occurs primarily through the dissolution of compounds that have sulphate in their chemical composition, such as barite, suggesting that part of the barium concentration in the subsurface can be of geogenic origin. This study demonstrated the importance of knowing the nature of the geochemical processes in groundwater contaminated by urban solid waste.