Sulfides in mantle peridotites from Penghu Islands, Taiwan: Melt percolation, PGE fractionation, and the lithospheric evolution of the South China block

Major elements, highly siderophile elements (HSE) and Re-Os isotope ratios were analysed in situ on individual sulfide grains in spinel peridotite xenoliths hosted by Miocene intraplate basalts from the Penghu Islands, Taiwan. The xenoliths represent texturally and compositionally different mantle domains, and the geochemical characteristics of the sulfides show changes in HSE distribution and Re-Os isotope systematics, produced as their host rocks were metasomatised by percolating fluids/melts. In prophyroclastic and partly metasomatised peridotites from the Kueipi (KP) locality, the sulfides have subchondritic to superchondritic ¹⁸⁷Re/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os ratios. Many of these sulfides reflect fluid/melt interaction with residual MSS and/or crystallization of fractionated sulfide melts, which produced high contents of Cu and PPGEs and high Re/Os; inferred melt/rock ratios are low. In contrast, sulfides in equigranular and extensively metasomatised peridotites from the Tungchiyu (TCY) locality are mainly more sulfur-rich Ni-(Co)-rich MSS, with subchondritic to chondritic ¹⁸⁷Os/¹⁸⁸Os and subchondritic ¹⁸⁷Re/¹⁸⁸Os. These sulfides are interpreted as products of interaction between pre-existing MSS and percolating silicate melts. Melt/rock ratios were high and the percolating melt was less differentiated than the melt that percolated the KP peridotites. Sulfides in a TCY pyroxenite are mainly MSS; they have the lowest HSE contents, subchondritic to superchondritic ¹⁸⁷Os/¹⁸⁸Os and subchondritic ¹⁸⁷Re/¹⁸⁸Os, and may have precipitated from sulfide melts that segregated from basaltic melts under S-saturated conditions. In most sulfides melt percolation appears to have induced fractionation among the HSEs and disturbed Re-Os isotope compositions. Despite the metasomatic effects, rare residual MSS, sulfides that from crystallised sulfide melts and sulfides modified by addition of Re (with no evidence for Os addition) can still provide useful chronological information. Such sulfides yield T_RD age peaks of 1.9, 1.7-1.6, 1.4-1.3 and 0.9-0.8 Ga, which may record the timing of melt extraction and/or metasomatic events in the mantle. These periods are contemporaneous with the major crustal events recorded by U-Pb dates and Nd and Hf model ages in the overlying crust. This close correspondence indicates that the sulfide T_RD ages reflect the timing of lithosphere-scale tectonothermal events (such as melting and metasomatism) that affected both the lithospheric mantle and the overlying crust. The sulfide T_RD ages, taken together with the crustal data, suggest that most of the Cathaysia block had formed at least by Paleo-Proterozoic time, and that some domains are Archean in age.     

Remediation scenarios for selenium contamination, Blackfoot watershed, southeast Idaho, USA

Extensive phosphate mining in the Blackfoot watershed of Idaho (USA) has substantially increased the selenium (Se) concentration in the river during both snowmelt and baseflow when groundwater discharge dominates. Phosphate mines create a linkage between Se-laden shale that occurs in the Phosphoria Formation and the underlying regional Wells Formation aquifer. Using a reconnaissance-level transport model, mines in the watershed were prioritized for remediation and for comparing the results of simulations of remediation scenarios with a baseline of no remediation, for which Se concentration in the river will exceed the aquatic standard along an extensive length. An accurate simulation of recharge distribution around the watershed and simulated flux to the river is essential. Remediation of mines north of the river will substantially decrease the size of the Se plume, although significant Se will continue to discharge to the river. Similarly, remediation of three mines south of the river would decrease the Se discharge to the river but allow substantial amounts to remain stored in the groundwater north and far south of the river. A lack of calibration data is not a reason to forgo remediation, but rather ongoing data collection can be used to fine-tune plans as they are implemented.     

Magnetic zones of Mars: Deformation‐controlled origin of magnetic anomalies

Abstract— Intense magnetic anomalies over Martian surface suggest preservation of large volumes of very old crust (>3 Gyr) that formed in the presence of a global magnetic field. The global distribution of the magnetic intensities observed above the Martian crust suggests a division into three zones. Zone 1 is where the magnetic signature is negligible or of relatively low intensity at Mars Global Surveyor (MGS) satellite mapping altitude (400 km). Zone 2 is the region of intermediate crustal magnetic amplitudes and zone 3 is where the highest magnetic intensities are measured. Crater demagnetization near zone 3 reveals the presence of rocks with both high magnetic intensity and coercivity. Magnetic analyses of terrestrial rocks show that compositional banding in orogenic zones significantly enhances both magnetic coercivity and thermal remanent magnetization (TRM) efficiency. Such enhancement offers a novel explanation for the anomalously large intensities inferred of magnetic sources on Mars. We propose that both large magnetic coercivity and intensity near the South Pole is indicative of the presence of a large degree of deformation. Associated compositional zoning creates conditions for large scale magnetic anisotropy allowing magnetic minerals to acquire magnetization more efficiently, thereby causing the distinct magnetic signatures in zone 3, expressed by intense magnetic anomalies. We use a simple model to verify the magnetic enhancement. We hypothesize that magnetically enhanced zone would reside over the down welling plume at the time of magnetization acquisition.     

Pathogenicity of vibrios in fish: An overview

Bacteria of the genus Vibrio are ubiquitously distributed in the marine environment. Due to the rapid expansion of intensive mariculture and the consequent deterioration of culture conditions, more and more Vibrio spp. have been recognized as pathogenic agents in outbreaks of vibriosis, a serious epizootic disease affecting most wild and farmed fish species worldwide, which has become the most important limiting factor for the development of intensive mariculture industry. Attempts have been made to understand the pathogenicity of vibrios in host fish with the ultimate aim of elucidating the best means for disease control. After an extensive literature survey of the recent advances in the field of fish vibriosis, the pathological changes, virulence factors and associated potential pathogenic mechanisms, transmission routes and related environmental factors involved in outbreak of vibriosis, as well as the controlling strategies are reviewed in the present paper.     

Cosmic microwave background polarization due to scattering in clusters

Scattering of the cosmic microwave background (CMB) in clusters of galaxies polarizes the radiation. We explore several polarization components which have their origin in the kinematic quadrupole moments induced by the motion of the scattering electrons, either directed or random. Polarization levels and patterns are determined in a cluster simulated by the hydrodynamical enzo code. We find that polarization signals can be as high as  ∼1 μK  , a level that may be detectable by upcoming CMB experiments.     

On the properties of strange modes

Properties of the so-called strange modes occurring in linear stability calculations of stellar models are discussed. The behaviour of these modes is compared for two different sets of stellar models, for very massive zero-age main-sequence stars and for luminous hydrogen-deficient stars, both with high luminosity-to-mass ratios. We have found that the peculiar behaviour of the frequencies of the strange modes with the change of a control parameter is caused by the pulsation amplitude of a particular eigenmode being strongly confined to the outer part of the envelope, around the density inversion zone. The frequency of a strange mode changes because the depth of the confinement zone changes with the control parameter. Weakly non-adiabatic strange modes tend to be overstable because the amplitude confinement quenches the effect of radiative damping. On the other hand, extremely non-adiabatic strange modes become overstable because the perturbation of radiation force (gradient of radiation pressure) provides a restoring force that can be out of phase with the density perturbation. We discuss this mechanism by using a plane-parallel two-zone model.     

THE AIR PHOTOGRAPH REQUIREMENTS OF GEOLOGISTS

The geologist's use of air photographs and the characteristics studied by photogeologists are briefly described. The influence of photographic factors such as scale, season, time of day, film type, processing, overlap and dimensional accuracy are considered from the geologist's viewpoint.     

Climate Change Impacts for the Conterminous USA: An Integrated Assessment Summary

This special issue of Climatic Change describes an effort to improve methodology for integrated assessment of impacts and consequences of climatic change. Highlights of the seven foregoing Parts (papers) that constitute this special issue are summarized here. The methodology developed involves construction of scenarios of climate change that are used to drive individual sectoral models for simulating impacts on crop production, irrigation demand, water supply and change in productivity and geography of unmanaged ecosystems. Economic impacts of the changes predicted by integrating the results of the several sectoral simulation models are calculated through an agricultural land-use model. While these analyses were conducted for the conterminous United States alone, their global implications are also considered in this summary as is the need for further improvements in integrated assessment methodology.