Quantifying chemical changes in hydrothermally altered volcanic sequences — silica enrichment as a guide to the crandon massive sulfide deposit,Wisconsin, U.S.A.

A multi-element geochemical study of the wallrocks which host the large Precambrian Crandon deposit (≈ 70 million tons of zinc, copper ore) in Wisconsin, U.S.A. was carried out to identify pathfinder elements which significantly enlarge the size of the deposit as an exploration target. The Crandon deposit occurs in what appears to be a “normal”, subalkaline, intermediate to felsic volcanic sequence. The silica concentration of the wallrocks shows neither a systematic relationship to volcanic stratigraphy nor a distinctive pattern around ore.To determine if silica has been added to the host rocks, a regression analysis was performed on published data from 496 unaltered, subalkaline volcanic rocks from the Abitibi Subprovince of Canada, with silica as the dependent variable and the ratio of “immobile” elements Zr/TiO₂ as the independent variable. Based on the second degree regression curve and the associated standard error of estimate, predicted and residual silica values were calculated and plotted for the Crandon host rocks.The results show that massive sulfide ore was deposited in andesitic rocks with an original SiO₂ content of 52–62%, and that more than 7.4% SiO₂ was added to the rocks stratigraphically beneath the deposit and on strike with the deposit. Silica was added to the hanging wall rocks also, which confirms that hydrothermal activity at Crandon continued after cessation of massive sulfide ore deposition. In contrast to the pattern of silica enrichment at Crandon which significantly enlarges the size of the exploration target, two noneconomic prospects within ten miles of Crandon contain low to moderate levels of silica enrichment and corresponding low base metal values.Silica enrichment occurs in some systems unassociated with mineralization and is therefore not a specific signature of ore-forming processes. However, from the data presented on the Crandon deposit, if silica enrichment does exist in an exploration search area, the chances of finding a massive sulfide ore deposit are improved.     

Calcium levels in <Emphasis Type="Italic">Daphnia</Emphasis> ephippia cannot provide a useful paleolimnological indicator of historical lakewater Ca concentrations

Despite reductions in atmospheric sulphur emissions and the resulting decline in acidic deposition, many lakes on the Canadian Shield that have experienced acidification are either recovering at a rate slower than expected or not recovering at all. This lack of recovery is believed to be partly the consequence of the depletion of exchangeable base cations (principally calcium, Ca) from watershed soils. Although the implications of reduced Ca availability for biological communities remain poorly understood, the effects on crustacean zooplankton populations may be severe, as Ca is the primary structural component of the crustacean zooplankton exoskeleton. Because the daphniid resting egg is protected by a modified portion of the exoskeleton (ephippia) and because these ephippia are well preserved in lake sediments, we investigated whether inter-specific differences in Ca content are recoverable from Daphnia ephippia. However, using two methods, we did not find a recoverable Ca signal in the ephippia, indicating that future efforts should be focused upon sedimentary taxonomic assemblage differences, not differences in ephippial Ca levels.     

Seasonal temperature responses to land-use change in the western United States

In the western United States, more than 79 000 km² has been converted to irrigated agriculture and urban areas. These changes have the potential to alter surface temperature by modifying the energy budget at the land–atmosphere interface. This study reports the seasonally varying temperature responses of four regional climate models (RCMs) – RSM, RegCM3, MM5-CLM3, and DRCM – to conversion of potential natural vegetation to modern land-cover and land-use over a 1-year period. Three of the RCMs supplemented soil moisture, producing large decreases in the August mean (− 1.4 to − 3.1 °C) and maximum (− 2.9 to − 6.1 °C) 2-m air temperatures where natural vegetation was converted to irrigated agriculture. Conversion to irrigated agriculture also resulted in large increases in relative humidity (9% to 36% absolute change). Modeled changes in the August minimum 2-m air temperature were not as pronounced or consistent across the models. Converting natural vegetation to urban land-cover produced less pronounced temperature effects in all models, with the magnitude of the effect dependent upon the preexisting vegetation type and urban parameterizations. Overall, the RCM results indicate that the temperature impacts of land-use change are most pronounced during the summer months, when surface heating is strongest and differences in surface soil moisture between irrigated land and natural vegetation are largest.     

Direct determination of7Be in sediments

Cosmic-ray produced⁷Be (53 days half-life) is directly measurable in freshly collected samples of river and coastal zone sediments using a lithium-drifted germanium detector. Calibration of the detector is discussed and an assessment of overall accuracy and sensitivity presented. The detection limit for a 250-g dry weight sediment sample contained in a Marinelli Beaker and counted for 200 minutes is approximately 0.4 pCi/g. Applications toward locating zones of rapid sedimentation as well as in understanding shallow-water sedimentation dynamics are suggested.     

The distribution and source of organic matter in reservoir sediments

The bottom sediments of two reservoirs, one with significant river sediment input and one without, were analyzed for organic matter content. Lake Texoma sediments average 1.0% organic carbon, of which 0.26% organic carbon is deposited by the river sediments of the Red and Washita River deltas. In Fort Gibson reservoir, where there is minimal river sediment input, the organic carbon averages 1.2% and is deposited with a strong correlation to water depth (+0.9). There is a significant difference between the C/N ratio of Lake Texoma sediments (11.5) and Fort Gibson sediments (9.6). The higher C/N ratio is suggested to be a result of the larger input of terrestrial plant debris (with a high original C/N ratio) by the rivers draining into Lake Texoma and the relatively high resistance of the lignin material in the plant debris to decomposition in the reservoir sediments.