Complex resistivity of mineral rocks in the context of the generalised effective‐medium theory of the induced polarisation effect

This paper develops the generalised effective‐medium theory of induced polarisation for rock models with elliptical grains and applies this theory to studying the complex resistivity of typical mineral rocks. We first demonstrate that the developed generalised effective‐medium theory of induced polarisation model can correctly represent the induced polarisation phenomenon in multiphase artificial rock samples manufactured using pyrite and magnetite particles. We have also collected representative rock samples from the Cu–Au deposit in Mongolia and subjected them to mineralogical analysis using Quantitative Evaluation of Minerals by Scanning Electron Microscopy technology. The electrical properties of the same samples were determined using laboratory complex resistivity measurements. As a result, we have established relationships between the mineral composition of the rocks, determined using Quantitative Evaluation of Minerals by Scanning Electron Microscopy analysis, and the parameters of the generalised effective‐medium theory of induced polarisation model defined from the laboratory measurements of the electrical properties of the rocks. These relationships open the possibility for remote estimation of types of mineralisation and for mineral discrimination using spectral induced polarization data.     

Wind- and density-driven circulation in a bay on the Sanriku ria coast,Japan: study of Shizugawa Bay facing the Pacific Ocean

Flow fields in Shizugawa Bay on the Sanriku ria coast, which faces the Pacific Ocean, were investigated using hydrographic observations for the purpose of understanding oceanographic conditions and the process of water exchanges in the bay after the 2011 earthquake off the Pacific coast of Tohoku. In spring to summer, density-driven surface outflow is part of estuarine circulation and is induced by a pressure gradient force under larger longitudinal gradients in density along with lower salinity water in the innermost part of the bay, regardless of wind forcing. In winter to summer, another density-driven current with a thermal structure is induced by a pressure gradient force under the smaller longitudinal density gradients in calm wind conditions. Particularly in winter, Tsugaru Warm Current water can be transported in the surface layer inside the bay. Wind-driven bay-scale circulation with downwind and upwind currents in the surface and deeper layers, respectively, is induced by strong longitudinal wind forcing under the smaller longitudinal density gradients, irrespective of season. Particularly in fall to spring, this circulation can cause the intrusions of oceanic water associated with Oyashio water and Tsugaru Warm Current water in the deeper layer. These results suggest that wind- and density-driven currents can produce the active exchange of water from inside and outside the bay throughout the year.     

A Proposed Method to Estimate In Situ Dissolved Gas Concentrations in Gas‐Saturated Groundwater

Gas‐saturated groundwater forms bubbles when brought to atmospheric pressure, preventing precise determination of its in situ dissolved gas concentrations. To overcome this problem, a modeling approach called the atmospheric sampling method is suggested here to recover the in situ dissolved gas concentrations of groundwater collected ex situ under atmospheric conditions at the Horonobe Underground Research Laboratory, Japan. The results from this method were compared with results measured at the same locations using two special techniques, the sealed sampler and pre‐evacuated vial methods, that have been developed to collect groundwater under its in situ conditions. In gas‐saturated groundwater cases, dissolved methane and inorganic carbon concentrations derived using the atmospheric sampling method were mostly within ±4 and ±10%, respectively, of values from the sealed sampler and pre‐evacuated vial methods. In gas‐unsaturated groundwater, however, the atmospheric sampling method overestimated the in situ dissolved methane concentrations, because the groundwater pressure at which bubbles appear (P_critical) was overestimated. The atmospheric sampling method is recommended for use where gas‐saturated groundwater can be collected only ex situ under atmospheric conditions.     

Structural architecture and low‐grade metamorphism of the Mikabu‐Northern Chichibu accretionary wedge,SW Japan

To understand tectono‐metamorphic processes within or close to the brittle–ductile transition of quartz‐rich crustal rocks in an accretionary wedge, an integrated field, petrological, geochronological and Raman spectroscopic study was conducted on the Mikabu‐Northern Chichibu belt in SW Japan. Field mapping in central Shikoku reveals that the Northern Chichibu belt is comprised of a pile of four tectono‐stratigraphic units, referred to as A, B, C and D units. The A unit (dominated by pelagic sedimentary rocks) represents the structurally lowest and youngest accretionary complex that forms a composite unit with the Mikabu ophiolitic suite. The B unit (consisting of chert‐clastic rock sequences) overlies the A unit and is overlain by the C and D units (mudstone‐matrix mélange units). Raman spectroscopy of carbonaceous material constrains the peak temperature of each unit to be ~290°C for the A unit, 270–290°C for the B unit, 230–250°C for the C unit and ~220°C for the D unit. Ductile deformation and pervasive metamorphism are limited to rocks in the Mikabu, A and B units. Alkali pyroxene and sodic amphibole occur in metabasite from the Mikabu, A and B units, and the widespread occurrence of prograde veins containing lawsonite+quartz pseudomorphs after laumontite was newly recognized from the C unit. Phase petrological data constrain the peak pressure of each unit to be ~0.65 GPa for the Mikabu‐A unit (aragonite stable), ~0.45–0.6 GPa for the B unit (jadeite+albite stable in the structurally lower part), and ~0.35 GPa for the C unit (prehnite+lawsonite stable). The peak metamorphic pressure increases towards structurally lower and younger accretionary complexes, but the thickness of the preserved strata is insufficient to account for the inferred pressure range. The structural–metamorphic relations imply thickening of the accretionary wedge by underplating was followed by a significant phase of thinning by both ductile and brittle processes.     

Vertical distribution of various elements in sediment cores from the Japan Sea

Deep-sea sediment cores ranging up to 30,000–80,000 yrs in age were taken from a southern region of the Japan Sea and subjected to analyses for 5 major and 11 trace elements by means of instrumental photon activation analysis with 30 MeV bremsstrahlung. These elements were Ca, Fe, Mg, Na, Ti, Ba, Ce, Co, Cr, Mn, Nb, Ni, Rb, Sr, Y and Zr. Additionally, Al was determined spectrophotometrically. Distribution patterns of these elements with depth in the sediment columns were derived. Enrichments of Ca and Sr by biogenous process were observed; these Ca maxima are well correlated with Mn maxima. Below the Holocene—Pleistocene boundary, continuous transportation of poorly degraded continental debris, which was low in metallic constituents, was noted. A distinct enrichment of the top layer of the sediments in Mn was observed. This is the result of post-depositional upward migration of Mn. Fe, Co and Ni were also enriched in the top layers. In the central part of the basin, the oxidized post-glacial zone appears to be a typical pelagic sediment.     

Identification of typical synoptic patterns causing heavy rainfall in the rainy season in Japan by a Self-Organizing Map

In order to systematically and visually understand well-known but qualitative and complex relationships between synoptic fields and heavy rainfall events in Kyushu Islands, southwestern Japan, during the BAIU season, these synoptic fields were classified using the Self-Organizing Map (SOM), which can convert complex non-linear features into simple two-dimensional relationships. It was assumed that the synoptic field patterns could be simply expressed by the spatial distribution of (1) wind components at the 850 hPa level and (2) precipitable water (PW) defined by the water vapor amount contained in a vertical column of the atmosphere. By the SOM algorithm and the clustering techniques of the U-matrix and the K-means, the synoptic fields could be divided into eight kinds of patterns (clusters). One of the clusters has the notable spatial features represented by a large PW content accompanied by strong wind components known as low-level jet (LLJ). The features of this cluster indicate a typical synoptic field pattern that frequently causes heavy rainfall in Kyushu during the rainy season.In addition, an independent data set was used for validating the performance of the trained SOM. The results indicated that the SOM could successfully extract heavy rainfall events related to typical synoptic field patterns of the BAIU season. Interestingly, one specific SOM unit was closely related to the occurrence of disastrous heavy rainfall events observed during both training and validation periods. From these results, the trained SOM showed good performance for identifying synoptic fields causing heavy rainfall also in the validation period. We conclude that the SOM technique may be an effective tool for classifying complicated non-linear synoptic fields and identifying heavy rainfall events to some degree.     

Hg, Zn and Cu levels in the muscle and liver of tiger sharks (Galeocerdo cuvier) from the coast of Ishigaki Island, Japan: relationship between metal concentrations and body length

We analyzed Hg, Zn and Cu concentrations in the liver and muscle of tiger sharks (Galeocerdo cuvier) from the coast of Ishigaki Island, Japan. The Hg concentration in the muscle increased proportionally with body length in the tiger sharks, whereas that in the liver increased rapidly after maturity (defined by a length of over 2.7 m). Muscle Hg levels were higher than liver concentrations in immature sharks, with the inverse trend observed in mature sharks. Notably, the Zn and Cu concentrations in the liver tended to decrease with increasing body length. This rapid increase in hepatic Hg concentration concurrent with the onset of maturity in sharks may result from the continuous intake of Hg via food and the slower growth of mature sharks. The high concentrations of the essential metals Zn and Cu in immature sharks may be explained by the physiological demands related to rapid growth.