Detection of nitrate sources in urban groundwater by isotopic and chemical indicators,Hangzhou City,China

The sources of nitrate in the shallow groundwater at urban area, Hangzhou City, China were investigated using chemical and isotopic techniques. Groundwater electric conductivity was high in the study area and ranged from 369–1,544 S/cm. Most of the groundwater was weakly alkaline and the groundwater chemistry was seriously influenced by land use in the city. There was a high frequency of groundwater (43% of total) with nitrate above World Heath Organizations standards of 10 mg NO₃/L. The different land-use areas had different nitrate concentrations (0.04–34.41 mgN/L) and ¹⁵N _NO3 values (7.8~35.5). Domestic wastewater was the major nitrate source of shallow groundwater in the urban area, and the point source (septic tank) still existed in residential settings. At agricultural settings manure was the major NO₃ sources. High ¹⁵N _NO3 value (>20) and temporal variations of the ¹⁵N _NO3 value suggested that in residential areas it probably resulted from denitrification.     

Flow and patterns of nitrate pollution in groundwater: a case study of an agricultural area in Tsukuba City, Japan

A numerical simulation was applied to first characterize the groundwater flow and patterns of nitrate pollution of a small-agricultural catchment in Tsukuba City, Japan, for a 10-year period. There was a good performance of the flow simulation. In contrast, although the transport model calculated the evolution of the plume, it only provided estimates of solute concentrations. Groundwater contamination increased exponentially during the first 594 days of the simulation, reaching then a near-equilibrium state. Fertilizer applications are responsible for most of the leaching of NO₃⁻ to groundwater, therefore, shifting of crops and the associated agricultural practices may translate into decreases of contamination levels. A series of hypothetical scenarios demonstrated that replacing grasslands by other crops may reduce the contamination levels up to 12%. As the chosen field is a representative of many other agricultural areas in Japan, the approach and results should also be applicable to similar cases around the country.     

GEOGRAPHICAL LITERATURE IN JAPAN

This is the third in a series of reports on Japanese geographic research prepared in cooperation with the Association of Japanese Geographers (AJG). Like the two previous reports, which appeared in the August and November issues, it has been modified for the English-speaking readership of THE PROFESSIONAL GEOGRAPHER. However, unlike the previous articles, each of which aimed at providing data regarding Japanese research on specific geographic topics, this paper is intended to supply the reader with an inventory of those materials that will be needed for the conduct of research in Japan. —H. Jesse Walker, Member, U.S. National Committee, IGU.     

Origin of cyclicity in Triassic-Jurassic radiolarian bedded cherts of the Mino accretionary complex from Japan

Abstract The abundance of magnetic microspherules in a Triassic-Jurassic continuous sequence of alternating chert and shale beds in the Mino accretionary complex, central Japan, was measured systematically. Depending on time, the magnetic microspherules extracted from shale beds change in abundance considerably from the minimum 0.9ppm/cm³ at latest Triassic ( ca 208Ma) and the maximum 75ppm/cm³ at late Early Jurassic ( ca 187Ma); however, the abundance is always higher approximately 10–100 (average 70) times than those from adjacent chert bed at any stratigraphic horizon. Such systematic difference reveals the origin of radiolarian bedded chert as cyclic-rapid accumulation of biogenic SiO₂ under extremely slow accumulative environments of shale with probable aeolian dust in origin. The accumulation data for individual shale and chert beds were obtained based on the microspherule abundance and radiolarian biostratigraphy, i.e., ca 0.018g/cm²Ka for lower Jurassic shale beds and ca 1.9g/cm²Ka for adjacent chert beds.
Duration time to make a chert-shale couplet corresponds to a dominantly 15–20Ka interval (average 23 Ka) in Upper Triassic bedded cherts with a low paleolatitude, whereas a 40–45 Ka interval (average 42 Ka) in Lower Jurassic ones which may been formed in higher latitude than Triassics before the final accretion to the Asian continental margin. Depending on paleolatitude, the cyclicity of 23 and 42 Ka may correspond to Milankovitch cycles which have been well documented in deep-sea sediments.     

Origin of hybrid ferrolatite lavas from Magic Reservoir eruptive center,Snake River Plain,Idaho

The mineralogy and geochemical characteristics of intermediate composition ferrolatites and related lavas from the Magic Reservoir eruptive center (central Snake River Plain) have been investigated to evaluate the origin and petrologic significance of these hybrid lavas. The ferrolatites are chemically uniform, but contain a disequilibrium phenocryst/xenocryst assemblage derived in part from mixed rhyolitic and basaltic magmas that are closely represented by extrusive units in the area. The hybrid lavas also contain xenoliths of Archean granulites and have high ⁸⁷Sr/ ⁸⁶Sr and low ¹⁴³Nd/¹⁴⁴Nd ratios, all of which suggest significant magma-crust interaction. Quantitative models including magma mixing, minor crystal fractionation, and crustal contamination very closely reproduce the observed compositions of these ferrolatites; closed system fractionation and (or) simple bulk contamination models are not as successful and can be ruled out. It appears that preexisting mafic and silicic magmas from distinct sources (e.g., mantle and crust) encounter one another in crustal-level magma chambers under conditions where intimate mixing may occur despite wide differences in the physical properties of these liquids.     

Quartz microstructures and deformation conditions in the Hatagawa shear zone, north-eastern Japan

Abstract Meso- and microscale structural analyses were carried out in the Hatagawa shear zone, north-eastern Japan. The shear zone is a sinistral strike–slip ductile shear zone, and has a 1-km wide north-south trending region where quartz mean grain size of approximately 35 μm does not vary significantly. Two types of quartz microstructures, A and B, occur in the western and eastern part of the shear zone, respectively. The lattice preferred orientation (LPO) patterns are characterized by a type I crossed girdle in the samples with the quartz microstructure A, and a Y maximum in the samples with the quartz microstructure B. The microstructures under optical and transmission electron microscopes indicates that the quartz recrystallization occurred predominantly by progressive subgrain rotation in microstructure A, and by both progressive subgrain rotation and grain boundary migration in microstructure B. This suggests different deformation conditions in the western and eastern parts of the shear zone. Quartz LPO patterns, presence of myrmekite, feldspar compositions, and dislocation density also suggest difference in the deformation conditions. The syn-deformation temperature in the western part of the shear zone was lower than that of the eastern part of the shear zone. The stress in the western part of the shear zone was higher than that of the eastern part of the shear zone. The difference in the deformation conditions would affect not only the quartz microstructure, but also the quartz LPO patterns and the presence of myrmekite around K-feldspar porphyroclasts.     

Consideration of natural hazards in the design and risk management of industrial facilities

Recent chemical accidents precipitated by natural disasters have prompted governments in the United States, Japan, and Europe, among other countries, to re-evaluate current practices in the design and risk management of industrial facilities. This paper presents an overview of natural hazard design considerations and external events risk management requirements in the industrial sector, with particular emphasis on industrial practices in the United States, Japan, and Europe. The analysis shows that although regulations exist to ensure industrial plant structures are built to resist natural hazards (up to the design level), there are few laws to address the performance of non-structural elements and safety and emergency response measures during a natural disaster. Laws usually also refer to natural hazards only indirectly, and provisions to prevent or respond to simultaneous disasters from single or multiple sources concurrent with the natural disaster are usually not present.

Building Damage and Casualties after an Earthquake

The relationship between building damage patterns and human casualties in Nishinomiya City – one of the most heavily damaged cities in the 1995 Hanshin-Awaji Earthquake Disaster – was investigated using photographs of damaged buildings. First, the photographs of buildings in which casualties occurred were identified, and the building damage patterns were judged based on the photographs considering the existence of survival space. Then the relationship between the building damage pattern and casualty occurrence, and the characteristics of casualty distribution, were investigated. The main findings were as follows: Most casualties occurred in relatively old two-story wooden buildings in which the ground floor completely collapsed without survival space; casualties occurred at all building damage levels including ``no damage', and it can be seen that building damage is the major, but not the sole cause, of casualties in an earthquake; in Nishinomiya City, the regional distributions of casualties due to the collapse of buildings that left no survival space is similar to that of casualties due to other types of building damage.     

High molecular weight organic matter in seawater

The presence and nature of high molecular weight organic matter in seawater was critically reviewed and its biogeochemical cycle was discussed.Organic matter that passes through a filter of 0.5–1 μm pore size is called dissolved and that which does not pass through such a filter is defined as particulate. The size of colloidal particles ranges from 0.001 to 1 μm, and therefore, they are included in the dissolved fraction having high molecular weight.High molecular weight organic matter greater than 100,000 molecular weight was found in the seawater of Tokyo Bay. The values ranged from 0.1 to 1.5 mgC/l, and accounted for 8–45% of the total dissolved organic matter.Decomposition experiments on dissolved organic matter showed that macromolecular organic matter is refractory to bacterial attack. However, macromolecular organic materials tend to aggregate or adsorb on small particles to a sufficient size for precipitation. Organic aggregates thus formed sink to the bottom of the sea and bioelements included in them are removed from water column. High molecular weight organic materials are, therefore, considered to play an important role in transportation and distribution of matter in seawater.In order to elucidate the chemical and biological properties of macromolecular organic matter, concentration and isolation of this material are important, using methods such as adsorption on organic adsorbents or ultrafiltration.     

Cold air formation and advection over Eurasia during “dzud” cold disaster winters in Mongolia

Large negative temperature anomalies due to cold air advection have been observed over the Eurasian continent in recent years. During the 2009/2010 winter, a large amount of snow accumulated across Central Asia and China, which along with a strong cold air outbreak, resulted in extremely high livestock mortality in Mongolia. The present study examined the surface inversion development over the Eurasian continent in terms of the cold air advection, accumulation, and breaking processes at ground level. Meteorological analyses shown trends toward earlier onsets of snow and subsequent cold air advection from the Arctic through western Siberia during the last decade, which is a possible driver of the persistent enhanced surface cooling observed in mid-winter in Mongolia. Cyclones are shown to be drivers of early snowfall onset at the beginning of winter and the subsequent migration of cold air from the Arctic, and are thus the key to understanding and predicting the frequency and intensity of persistent surface cooling, which is a substantial physical precursor for the cold disaster in Mongolia “dzud.”