Recognition of shear heating on a long‐lived major fault using Raman carbonaceous material thermometry: implications for strength and displacement history of the MTL,SW Japan

The extent to which movement on major faults causes long term shear heating is a contentious issue and an important aspect in the debate about the strength of major faults in the crust. Comparing the results of experimental work on the kinetics of crystallization of carbonaceous material with results of thermal modeling show that the Raman carbonaceous material (CM) geothermometer is well suited to studying shear heating on geological time scales in suitable lithologies exposed around exhumed major fault zones. The Median Tectonic Line (MTL), SW Japan, is the largest on‐land fault in Japan with a length of > 800 km. Application of Raman CM thermometry to pelitic schist adjacent to the fault reveals the presence of a rise in peak temperature of around 60 °C over a distance of around 150 m perpendicular to the MTL fault plane. The spatial association of this thermal anomaly with the fault implies it is due to shear heating. Thermal modeling shows the recorded thermal anomaly and steep temperature gradient is compatible with very high rates of displacement over time scales of a few thousand years. However, the implied displacement rates lie outside those generally observed. An alternative explanation is that an originally broader thermal anomaly that developed during strike slip faulting was shortened due to the effects of normal faulting. Constraints on displacement rate, width of the original anomaly, duration of heating and peak temperature imply a coefficient of friction, μ, greater than 0.4.     

Distributed object‐based software environment for urban system integrated simulation under urban‐scale hazard—Part I: Infrastructure

In this paper, a distributed object‐based software environment (DOSE) has been developed to facilitate the integrated simulation of an urban system under the risk of urban‐scale hazards such as earthquakes. It is understood that individual simulation participants perform their simulation services in separate environments, bartering service exchange relationships to get what they need to resolve their part of the problem. This is the communication gap between the scientists on one side and the end users who need to understand knowledge and employ it on the other side. The authors envision a distributed simulation service software environment running in parallel with the activities of simulation participants. DOSE has lent itself to integrate interdisciplinary participants through an infrastructure that has three basic building blocks, namely: modularity, scalability, and interoperability. The modular, object‐based, design of DOSE architecture is described in terms of key functionalities of four distinct layers, namely: resource, core, domain, and interface layers. DOSE scalability in terms of urban system size and participant third‐party application complexity is enabled through the interface layer. A message passing model is developed using the Message Passing Interface standard and a control room is provided to schedule the interaction/communication among model processes. DOSE interoperability with the vulnerability analysis third‐party applications is enabled through the Industry Foundation Classes (IFC) standard. An adopted analogy between DOSE and construction industry is employed to provide interpretation and implementation for DOSE interoperability. While interfacing IFC object model to solve DOSE interoperability questions, an extension model for the structural view of IFC is proposed and accepted by the International Alliance for Interoperability. The DOSE application for real‐world urban systems is beyond the scope of this paper and is presented in an accompanying paper work. Copyright © 2007 John Wiley & Sons, Ltd.     

Electrical conduction and polarization of calcite single crystals

The electrical conductivity and polarization properties of calcite single crystals with three orientations, namely, a (00.1) plane perpendicular to the crystallographic c axis (10.0) plane parallel to the crystallographic c axis, and a (10.4) cleavage plane, were studied by both complex impedance and thermally stimulated depolarization current (TSDC) measurements. Conductivities for (00.1)-, (10.0)-, and (10.4)-oriented single calcite crystals at 400–600?°C were 1.16?×?10^?7?–?1.05?×?10^?5, 7.40?×?10^?8?–?4.27?×?10^?6, and 4.27?×?10^?7?–?2.86?×?10^?5 Ω^?1 m^?1, respectively, and the activation energies for conduction were 112, 103, and 101?kJ?mol^?1, respectively. The TSDC spectra verified the electrical polarizability of calcite crystals. The activation energy for depolarization, estimated from TSDC spectra, of the (00.1)-, (10.0)-, and (10.4)-oriented calcite substrates were 112, 119, and 114?kJ?mol^?1, respectively. Considering the correlation between the processes of conduction and electric polarization, we proposed the mechanisms of conduction and polarization in calcite on the assumption of oxide ion transport.     

Tributyltin in blood of marine fish collected from a coastal area of northern Kyushu, Japan

We investigated levels of the pollutant tributyltin (TBT) in blood of pufferfishes (six species), Japanese sea perch, red sea bream, Japanese common goby, Japanese flounder, rockfish, conger eel, and sea mullet collected off the coast of northern Kyushu, Japan. We found considerable levels of TBT (1.4-190 ng/mL) accumulated in the blood of these fish. Blood TBT concentrations were 1.3-22.5 times liver concentrations and 4.9-78 times muscle concentrations, except in conger eel and mullet. We detected TBT (16-111 ng/mL-blood) in the plasma of the fine-patterned puffer (Takifugupoecilonotus) year-round, without any apparent seasonal trend. These results suggest that fish inhabiting coastal areas of Kyushu, Japan, continue to be contaminated with TBT.     

Hydration-dehydration interactions between glycine and anhydrous salts: Implications for a chemical evolution of life

Polymerizations of organic monomers including amino acids, nucleotides and monosaccharides are essential processes for chemical evolution of life. Since these reactions proceed with “dehydration” reactions, they are possibly promoted if combined with thermodynamically favorable “hydration” reactions of minerals and salts. To test the possibility, we conducted heating experiments of the simplest amino acid “glycine (Gly)” mixed with four simple anhydrous salts (MgSO₄, SrCl₂, BaCl₂ and Li₂SO₄) at 140 °C up to 20 days. Gly polymerization was strongly promoted by mixing with the salts in the order of MgSO₄ > SrCl₂ > BaCl₂ > Li₂SO₄. Up to 6-mer of Gly polymers were synthesized in the Gly-MgSO₄ mixture, and a total yield of Gly polymers attained about 7% of the initial amount of Gly by the 20 days heating. The total yield was about 200 times larger than that from the heating of Gly alone. XRD measurements of the Gly-MgSO₄ mixture revealed the generation of MgSO₄ monohydrate during Gly polymerization. These observations indicate that Gly polymerization was promoted by the salt hydrations through the hydration-dehydration interactions. Based on the observations, we tried to find a relationship between thermodynamic characteristics of the interactions and the promotion effects of each salt on Gly polymerization. It was found that the salts having lower hydration Δ_rG⁰ (easier to hydrate) promote Gly polymerization more strongly. The relationship was used to estimate promotion effects of simple oxide minerals on Gly polymerization. The estimations were consistent with previous observations about the effects of these minerals on Gly polymerization. The fact suggests that the hydration-dehydration interactions between amino acids and minerals are an important mechanism for amino acids’ polymerizations on minerals.     

日本南海弧前西端之下俯冲的九州—帕劳海岭的地震构造意义

作为菲律宾海板块残余岛弧的九州—帕劳海岭正沿着日本南海海槽的最西端俯冲于欧亚板块之下。沿走向布设的地震反射剖面显示出沿弧前增生楔前缘俯冲的九州—帕劳海岭70km宽的构造影像。地磁异常特征、海底地形特征、广角折射数据和陆地地貌证据等使得我们能够将俯冲海岭在弧前的延伸段一直追踪至九州岛的东部。正在俯冲的九州—帕劳海岭携带有大量冗余物质,可能具有相对较大浮力,因此在深部俯冲时与上覆板块的碰撞具有较大的抗性。有鉴于此,我们推测在俯冲海岭和上覆板块基底的接触区之间存在局部大应力构造。此局部大应力区人们已标出有历史冲断层型中等级别地震(6~7级)。当九州—帕劳海岭俯冲至深部时,漂浮的俯冲海岭其两侧的翼部更容易被撕裂而形成板块破裂。我们认为,俯冲的九州—帕劳海岭在深部不仅起到地震凹凸体的作用,而且产生板块破裂作为地震障碍体抑制邻近的日向段巨大逆冲地震的破裂传播。     

Long-term (36-year) observations on the dynamics of the fish-killing raphidophyte Chattonella in Harima-Nada,eastern Seto Inland Sea,Japan

Long-term changes of the fish-killing raphidophyte Chattonella spp. (Chattonella antiqua, Chattonella marina and Chattonella ovata) were examined in relation to environmental factors at 19 sampling stations in Harima-Nada, eastern Seto Inland Sea, Japan, for 36 years from 1973 to 2008. Long-term trends in the dynamics of Chattonella populations were considered to relate to environmental factors such as nutrient concentrations and water temperature. High nutrient levels during the period from the 1970s to the early 1980s have contributed to the high cell density and large-scale red tides of Chattonella spp. in Harima-Nada. However, nutrient levels exhibited a decreasing trend thereafter, and it is thought that Chattonella spp. cannot form large-scale blooms under the present conditions. After the mid-1990s, the occurrence period of vegetative cells of Chattonella spp. has been several weeks or 1 month earlier than that of the 1970s and early 1980s, and the appearance frequency of Chattonella spp. has increased in the northern coastal area, although the cell density and the spatial scale of the distribution have become lower and smaller than those in the previous decades. It is suggested that the timing of germination of Chattonella cysts has become earlier as a result of the increase in water temperature, and the chances of vegetative growth have also increased, especially at the northern coast where most of large rivers discharge into the Harima-Nada. In addition, the present results revealed that fewer diatoms were also one of the significant factors for the high abundance of Chattonella spp. in Harima-Nada.     

Flow and patterns of nitrate pollution in groundwater: a case study of an agricultural area in Tsukuba City, Japan

A numerical simulation was applied to first characterize the groundwater flow and patterns of nitrate pollution of a small-agricultural catchment in Tsukuba City, Japan, for a 10-year period. There was a good performance of the flow simulation. In contrast, although the transport model calculated the evolution of the plume, it only provided estimates of solute concentrations. Groundwater contamination increased exponentially during the first 594 days of the simulation, reaching then a near-equilibrium state. Fertilizer applications are responsible for most of the leaching of NO₃⁻ to groundwater, therefore, shifting of crops and the associated agricultural practices may translate into decreases of contamination levels. A series of hypothetical scenarios demonstrated that replacing grasslands by other crops may reduce the contamination levels up to 12%. As the chosen field is a representative of many other agricultural areas in Japan, the approach and results should also be applicable to similar cases around the country.     

Consideration of natural hazards in the design and risk management of industrial facilities

Recent chemical accidents precipitated by natural disasters have prompted governments in the United States, Japan, and Europe, among other countries, to re-evaluate current practices in the design and risk management of industrial facilities. This paper presents an overview of natural hazard design considerations and external events risk management requirements in the industrial sector, with particular emphasis on industrial practices in the United States, Japan, and Europe. The analysis shows that although regulations exist to ensure industrial plant structures are built to resist natural hazards (up to the design level), there are few laws to address the performance of non-structural elements and safety and emergency response measures during a natural disaster. Laws usually also refer to natural hazards only indirectly, and provisions to prevent or respond to simultaneous disasters from single or multiple sources concurrent with the natural disaster are usually not present.