Intra-annual perturbations of stable isotopes in tufas: Effects of hydrological processes

Tufas, which are freshwater carbonates, are potential archives of terrestrial paleoclimate. Time series of stable isotopic compositions commonly show regular seasonal patterns controlled by temperature-dependent processes, and some perturbation intrinsic to the locality. We examined three tufa-depositing sites in southwestern Japan with similar temperate climates, to understand the origin of local characteristics in the isotopic records. Seasonal change in the oxygen isotope is principally reflected by temperature-dependent fractionation between water and calcite but was perturbed after heavy rainfalls overwhelming the stability of the δ¹⁸O value of the groundwater at one site. Isotopic mass balance indicates an undersaturated and relatively small aquifer at this locality. Water δ¹⁸O values at the other two sites were stable, reflecting a regular seasonal change in the δ¹⁸O value of tufa. Perturbation of the δ¹³C values in tufa is largely due to CO₂ degassing from the stream, which significantly increases the δ¹³C values of dissolved inorganic carbon (DIC). At a site with remarkably high pCO₂ in springwater and a sensitive response of flow rate to rainfall, the amount of CO₂ degassing changed distinctly with flow rate. In contrast, the other two sites having low pCO₂ springwater reflect a regular seasonal pattern of δ¹³C in DIC and tufa specimens.     

Groundwater contamination in Japan

Problems on groundwater contamination in Japan are briefly summarized in this paper. Although normal physical conditions in Japan restrict the possibilities of groundwater contamination, human activities are threatening groundwater resources. A survey by the Environment Agency of Japan showed nationwide spreading of organic substances, such as trichloroethylene as well as nitrogen compounds. Synthetic detergents have also been detected even in rural areas and in deep confined aquifers, although their concentrations are not as high. Public awareness of agrichemical or pesticides abuse, especially from golf courses, is apparent. Other problems such as nitrate-nitrogen, leachate from landfills, and the leaking of underground storage tanks are also discussed.     

Mineralogy and geothermometry of high-temperature rhyolites from the central and western Snake River Plain

Voluminous mid-Miocene rhyolitic ash-flow tuffs and lava flows are exposed along the northern and southern margins of the central and western Snake River Plain. These rhyolites are essentially anhydrous with the general mineral assemblage of plagioclase ±sanidine ± quartz + augite + pigeonite ± hypersthene ± fayalitic olivine + Fe-Ti oxides + apatite + zircon which provides an opportunity to compare feldspar, pyroxene, and Fe-Ti oxide equilibration temperatures for the same rocks. Estimated pyroxene equilibration temperatures (based on the geothermometers of Lindsley and coworkers) range from 850 to 1000°C, and these are well correlated with whole-rock compositions. With the exception of one sample, agreement between the two-pyroxene thermometers tested is well within 50°C. Fe-Ti oxide geothermometers applied to fresh magnetite and ilmenite generally yield temperatures about 50 to 100°C lower than the pyroxene temperatures, and erratic results are obtained if these minerals exhibit effects of subsolidus oxidation and exsolution. Results of feldspar thermometry are more complicated, and reflect uncertainties in the thermometer calibrations as well as in the degree of attainment of equilibrium between plagioclase and sanidine. In general, temperatures obtained using the Ghiorso (1984) and Green and Usdansky (1986) feldspar thermometers agree with the pyroxene temperatures within the respective uncertainties. However, uncertainties in the feldspar temperatures are the larger of the two (and exceed ±60°C for many samples). The feldspar thermometer of Fuhrman and Lindsley (1988) produces systematically lower temperatures for many of the samples studied. The estimated pyroxene temperatures are considered most representative of actual magmatic temperatures for these rhyolites. This range of temperatures is significantly higher than those for rhyolites from many other suites, and is consistent with the hypothesis that the Snake River Plain rhyolitic magmas formed by partial fusion of relatively dry (e.g. granulitic) crustal lithologies.     

Expansion of the Nishinomiya Built Environment Database

The Nishinomiya Built Environment Database, which can be used to analyze the disaster process of the 1995 Hanshin-Awaji Earthquake Disaster in Nishinomiya City, has been expanded with new data entries. The database contains the following very detailed datasets: (1) the urbanization area base map, (2) casualty data, (3) three sets of building damage data surveyed by the Nishinomiya City, the Architectural Institute of Japan and the City Planning Institute of Japan, and the Kobe University, (4) building property data based on the real estate tax roll, (5) photographs of the damaged buildings with the information on the place and orientation of the picture, and (6) the estimated distribution of the seismic ground motion. The seismic ground motion was simulated for the southern part of Nishinomiya City and two verification sites in Kobe City and Amagasaki City. In the simulation, the borehole data of public facilities were used to model the surface soils as one-dimensional layers, taking into consideration the fact that the spatial distribution of the sediment/basement interface forms a slope. The model of the fault rupture process simulated the characteristics of the seismic motion at basement level, and amplification effects of the surface layers were evaluated based on multiple reflection theory. The distribution of peak ground acceleration and peak ground velocity was estimated from acceleration response spectra at each borehole point. In addition, the relationship between simulated seismic ground motion and building damage was studied based on newly proposed band-passed spectrum intensity using the expanded database. This confirmed that detailed categorization is necessary in order to evaluate the fragility functions, especially for reinforced concrete structures. The database should provide fundamental information for identifying the relationship between the ground motions and the extent and pattern of building damage, or the pattern of the occurrence of casualties.Presently     

A satellite cross-calibration experiment

Recently, the Advanced Earth Observing Satellite 2 (ADEOS-2) was launched (December 14, 2002) successfully, and the Global Imager (GLI) onboard the ADEOS-2 satellite became operational in April 2003. In a first calibration checkup, the radiometric performance of GLI was compared relatively to that of other sensors on different satellites with different calibration backgrounds. As a calibration site, a large snowfield near Barrow, Alaska, was used, where space sensors in polar orbits view the same ground target on the same day with small differences in the local crossing times. This is why GLI, the Moderate Resolution Imaging Spectroradiometer (Terra, Aqua), the Sea-viewing Wide Field-of-view Sensor, the Advanced Very High Resolution Radiometer (N16, N17), the Medium Resolution Imaging Spectrometer, and the Advanced Along Track Scanning Radiometer datasets were selected for the following clear-sky condition days: April 14 and 26, 2003. At the same time, ground-truth experiments (e.g., measurements of ground reflectance, bidirectional reflectance distribution function, aerosol optical thickness) were carried out. Thereinafter, top-of-atmosphere (TOA) radiance/reflectance was forward calculated by means of radiative transfer code for each sensor, each band, and each day. Finally, the vicariously retrieved TOA signal was compared to TOA sensor Level 1B data. As a result, GLI's performance is encouraging at that time of the mission. GLI and the other seven sensors deliver similar sensor output in the range of about 5% to 7% around the expected vicariously calculated TOA signal.     

A model of ocean-crust accretion for the Superior province, Canada

One of the keys to understanding the origin of Archaean greenstone belts lies in the geological relationships between mafic and ultramafic greenstones, felsic to intermediate volcanic rocks and terrigenous sediments. Traditional models for greenstone belt evolution have been based on in-situ stratigraphic relationships. Most of these models, for example an oceanic island-arc developed on oceanic basement, back-arc basins, and the recently popular plume model, predict concordant stratigraphic relationships among the various greenstone belt lithologies. However, rather than being depositional in nature, several authors have indicated that many of the relationships between the different lithologies in greenstone belts are in fact tectonic, suggesting an allochthonous origin for most greenstone sequences. All of these latter models make analogies to Phanerozoic tectonic processes involving accretion of oceanic materials with volcanism related to both plate subduction and rifting.

In this paper, we have evaluated the geological relationships between volcanic rocks and sediments in three regions in the Superior province, where the accretion of oceanic material can be documented, and direct comparisons are made to geological processes in Phanerozoic accretionary complexes. In the Malartic area in the southeastern Abitibi Subprovince, 3 to 4 km thick slices of komatiite and tholeiite, with intercalated terrigenous sediment, are tectonically imbricated and are overlain by calc-alkaline volcanics which postdate tectonic stacking. In both the Larder Lake region of the southwestern Abitibi belt and in the Beardmore-Geraldton belt, at the south-eastern limit of the Wabigoon belt, slices of iron-rich tholeiite and chemical sediments of an oceanic origin are tectonically imbricated with terrigenous sediment.

The Malartic-Val d'Or area is considered to be an example of accretion of an Archaean oceanic plateau, while the Larder Lake and the Beardmore-Geraldton regions are potentially typical of accretion of normal oceanic crust in an arc-environment. Phanerozoic accretion of oceanic crust is accompanied by a step-back in subduction, and in this paper we suggest that oceanic crust accretion may have been the principal mechanism by which the locus of subduction migrated towards the south of the Superior province. Asthenospheric upwelling associated with the isolated sinking plate may have been responsible for widespread late-magmatism. This scenario requires that magmas be erupted through previously accreted volcanic, plutonic and sedimentary material. Furthermore, later ridge subduction will result in transpressional tectonics and eruption of mafic sequences over mature and immature volcano-plutonic sequences. The combined result of the plate tectonic scenario envisaged would result in the well-described “cyclic stratigraphy” of many granite greenstone sequences.     

Distributed object‐based software environment for urban system integrated simulation under urban‐scale hazard—Part II: Application

A software prototype of a simulation service software environment, called DOSE (distributed object‐based software environment), is developed to realize the integrated simulation of an urban system under the risk of urban‐scale hazards such as earthquakes. DOSE infrastructure is built on three basic building blocks, namely: modularity, scalability, and interoperability. In this paper, the application of DOSE to real‐world urban systems is described in order to provide an evidence for DOSE modularity and scalability. An overview of DOSE is presented and then followed by a beverage application to simulate earthquake hazard in an urban system. The urban system is developed for the city of Kobe (Kobe district) with dimensions of 700 × 500 (m) and Bunkyo ward (Tokyo district) with dimensions of 800 × 600 (m) where DOSE simulation participants are identified for each district. The effectiveness of data exchange among different participants through a distributed service exchange network is described as an evidence for DOSE modularity that facilitates the integration process. On the other hand, the effectiveness of processing time when applying the simulation to different urban system sizes and/or using different third‐party applications is described as an evidence for DOSE scalability. The details of the underlying infrastructure of DOSE are beyond the scope of this paper and are presented in an accompanying paper work. Copyright © 2007 John Wiley & Sons, Ltd.     

Distributed object‐based software environment for urban system integrated simulation under urban‐scale hazard—Part I: Infrastructure

In this paper, a distributed object‐based software environment (DOSE) has been developed to facilitate the integrated simulation of an urban system under the risk of urban‐scale hazards such as earthquakes. It is understood that individual simulation participants perform their simulation services in separate environments, bartering service exchange relationships to get what they need to resolve their part of the problem. This is the communication gap between the scientists on one side and the end users who need to understand knowledge and employ it on the other side. The authors envision a distributed simulation service software environment running in parallel with the activities of simulation participants. DOSE has lent itself to integrate interdisciplinary participants through an infrastructure that has three basic building blocks, namely: modularity, scalability, and interoperability. The modular, object‐based, design of DOSE architecture is described in terms of key functionalities of four distinct layers, namely: resource, core, domain, and interface layers. DOSE scalability in terms of urban system size and participant third‐party application complexity is enabled through the interface layer. A message passing model is developed using the Message Passing Interface standard and a control room is provided to schedule the interaction/communication among model processes. DOSE interoperability with the vulnerability analysis third‐party applications is enabled through the Industry Foundation Classes (IFC) standard. An adopted analogy between DOSE and construction industry is employed to provide interpretation and implementation for DOSE interoperability. While interfacing IFC object model to solve DOSE interoperability questions, an extension model for the structural view of IFC is proposed and accepted by the International Alliance for Interoperability. The DOSE application for real‐world urban systems is beyond the scope of this paper and is presented in an accompanying paper work. Copyright © 2007 John Wiley & Sons, Ltd.     

Origins of building blocks of life: A review

How and where did life on Earth originate? To date, various environments have been proposed as plausible sites for the origin of life. However, discussions have focused on a limited stage of chemical evolution, or emergence of a specific chemical function of proto-biological systems. It remains unclear what geochemical situations could drive all the stages of chemical evolution, ranging from condensation of simple inorganic compounds to the emergence of self-sustaining systems that were evolvable into modern biological ones. In this review, we summarize reported experimental and theoretical findings for prebiotic chemistry relevant to this topic, including availability of biologically essential elements(N and P) on the Hadean Earth, abiotic synthesis of life's building blocks(amino acids, peptides, ribose, nucleobases, fatty acids, nucleotides, and oligonucleotides), their polymerizations to bio-macromolecules(peptides and oligonucleotides), and emergence of biological functions of replication and compartmentalization. It is indicated from the overviews that completion of the chemical evolution requires at least eight reaction conditions of(1) reductive gas phase,(2) alkaline pH,(3) freezing temperature,(4)fresh water,(5) dry/dry-wet cycle,(6) coupling with high energy reactions,(7) heating-cooling cycle in water, and(8) extraterrestrial input of life's building blocks and reactive nutrients. The necessity of these mutually exclusive conditions clearly indicates that life's origin did not occur at a single setting; rather, it required highly diverse and dynamic environments that were connected with each other to allow intratransportation of reaction products and reactants through fluid circulation. Future experimental research that mimics the conditions of the proposed model are expected to provide further constraints on the processes and mechanisms for the origin of life.