Contamination by Persistent Organochlorines in Small Cetaceans from Hong Kong Coastal Waters

Blubber samples of 2 cetacean species, the Indo-Pacific hump-backed dolphin (Sousa chinensis) (n=11) and finless porpoise (Neophocaena phocaenoides) (n=9), collected from Hong Kong coastal waters were analysed for persistent organochlorines. Mean concentration in the blubber of DDTs was ranked first (46 μg/g wet wt.), followed by PCBs (24 μg/g wet wt.), HCHs (0.76 μg/g wet wt.), chlordane compounds (0.38 μg/g wet wt.) and HCB (0.07 μg/g wet wt.). The present cetacean species may potentially be faced with high risk due to the elevated level of DDTs and PCBs. Relatively high concentrations of PCBs and DDTs can be attributed to the continuous environmental input of these compounds in the Far East region including Hong Kong. Highly chlorinated PCBs such as IUPAC Nos. 138, 153, 180 were the prominent congeners, accounting for 39% of the total PCBs. Mean concentrations of 6 non- and mono-ortho coplanar congeners were 2.1 and 2.8 μg/g wet wt. in the hump-backed dolphin and finless porpoise, respectively. Among highly toxic coplanar PCBs, mono-ortho congener IUPAC No. 118 and non-ortho congener IUPAC No. 126 were estimated to have the greatest toxicity contribution. Tris(4-chlorophenyl) methane (TCPMe) and tris(4-chlorophenyl) methanol (TCPMeOH), which have been the most recently identified microcontaminants, were also detected with the highest concentration of 290 and 300 ng/g (wet wt. basis), respectively. The concentrations of TCPMe relative to TCPMeOH in cetaceans from Hong Kong coastal waters were significantly higher than those found in various seals collected from other parts of the world, suggesting the different metabolic system of these two compounds between seals and cetaceans. Correlations between the concentrations of tris-chlorophenyl compounds with other persistent organochlorines such as HCHs, CHLs, DDTs and PCBs were significant, suggesting their accumulation nature similar to these organochlorines.     

Probing the evolution of early-type galaxies using multicolour number counts and redshift distributions

We investigate pure luminosity evolution models for early-type (elliptical and S0) galaxies (i.e. no number density change or morphological transition), and examine whether these models are consistent with observed number counts in the B , I and K bands, and redshift distributions of two samples of faint galaxies selected in the I and K bands. The models are characterized by the star formation time-scale τ _SF and the time t _gw when the galactic wind starts to blow, in addition to several other conventional parameters. We find that the single-burst model ( τ _SF=0.1 Gyr and t _gw=0.353 Gyr), which is known to reproduce the photometric properties of early-type galaxies in clusters, is inconsistent with the redshift distributions of early-type galaxies in the field environment, owing to overpredictions of the number of galaxies at z ≳1.4 even with strong extinction which is at work until t _gw. In order for dust extinction to be more effective, we treat τ _SF and t _gw as free parameters, and find that models with τ _SF≳0.5 Gyr and t _gw>1.0 Gyr can be made consistent with both the observed redshift distributions and the number counts, if we introduce strong extinction [ E ( B − V )≥1 as a peak value]. These results suggest that early-type galaxies in the field environment do not have the same evolutionary history as described by the single-burst model.     

Upwelling of oxygen-depleted water (Sumishio) in Omura Bay,Japan

Wind-induced circulation and the distribution of hypoxia corresponding to the upwelling of oxygen-depleted water (called “Aoshio” in Japan and “Sumishio” locally in Omura Bay) in Omura Bay, Japan, was examined field observations and by three-dimensional modeling. During the calm weather in summer, well-mixed strait water, in rich oxygen at the mouth of the bay intruded into the middle layer of the bay, southward and northward along the west and east coast, respectively, forming basin-scale cyclonic circulation. A stagnant water mass was formed below the center of this cyclonic circulation, and it became hypoxic water. As a result of the prevailing strong southeast (northeast) wind, the bottom hypoxia moved in a southeasterly (northeasterly) direction. This induces the upwelling of hypoxic water, accompanied by mass mortality of marine organisms.     

Interannual variations of the planktonic ecosystem in the slope water and Kuroshio south of Japan in February in the years 1990–2002

To determine recent interannual variations in the planktonic ecosystem of the slope water south of Japan, an area between 1000 m isobath on the continental slope and assumable Kuroshio front, in reference to preceding reports on the Kuroshio, we examined interannual variations of physical factors, sea surface chlorophyll concentration (SSChl), size-fractioned copepod biomass and the abundance of Calanus sinicus, one of the dominant copepods in the region, in February from 1990 to 2002. In the slope water, SSChl concentration had generally shown a higher value than in the Kuroshio and increase of the SSChl in both areas started in February but lasted longer in the slope water. The regional distribution of copepod biomass and C. sinicus abundance was similar to that of phytoplankton in that they were distributed more densely in the slope water than in the Kuroshio, reflecting assumed higher nutrient supply. The interannual variation in sea surface temperature in the slope water was explained by the rise of air temperature in 1998, a strong El Niño year, and subsequent change in the Kuroshio path (1999–2001). The interannual variation of the planktonic community, i.e. sea surface chlorophyll concentration and copepod biomass, was attributed to the effects of those physical events through the direct effect of local temperature and/or variation in surface irradiance, except for a prominent increase of copepods in the slope water in 2000. The effect of interannual change in the vertical mixing, suggested in previous studies, was not apparent in February, when the primary production is not limited by nutrient concentration which would be more important in regulating biological production in later months.     

Abundance of nauplii and protein synthesis activity of adult female copepods in the Kuroshio front during the Japanese sardine spawning season

In order to point out the potential importance of the Kuroshio front as a feeding ground for the early post larvae of the Japanese sardine, distributions of copepod nauplii—the principal food for the larvae—were investigated.Nauplii were abundant in and near the front and in a warm water mass off Ensyu-nada, where the concentration of chlorophylla was high. Adult females ofParacalanus sp. were dominant in the copepod group there, and the protein synthesis activity shown by the RNA/DNA ratio was high. It is expected that copepod egg productivity is enhanced in the area where food phytoplankton is abundant, because the RNA/DNA ratio showed a positive correlation to chlorophylla in situ.In and near the front, high chlorophylla concentration—which is probably supported by nutrient supply caused by local upwelling and/or eddies at the front—contributes to the high RNA/DNA ratio of the copepods. The relatively large biomass of copepod nauplii at the front may be supported by female's high egg productivity. It is supposed, as a result, that food availability for the early post larvae of the Japanese sardine is increased in and near the Kuroshio front.     

Impacts of vehicles on natural terrain at seven sites in the San Francisco Bay area

The impacts of off-road vehicles on vegetation and soil were investigated at seven representative sites in the San Francisco Bay area. Plant cover of grass and chaparral (with shrubs to 4 m tall) have been stripped by the two- and four-wheel vehicles in use. Impacts on loamy soils include increased surface strength (as much as 275 bars), increased bulk density (averaging 18%) to depths of 90 cm or more, reduction of soil moisture by an average 43% to 30 cm depths, greatly reduced infiltration, extension of the diurnal temperature range by as much as 12°C, and reduction of organic carbon by an average 33% in exposed soils. Very sandy soils respond similarly to vehicular use except that moisture is increased and surface strength of beach sand is decreased. These physical and chemical impacts reduce the land's capability of restoring its vegetative cover, which in turn adversely affects animal populations. Both the loss of plant cover and the physical changes caused by vehicles promote erosion. Measured soil and substrate losses from vehicular use zones range from 7 to 1180 kg/m². The estimated erosion rate of the Chabot Park site exceeds the rate of erosion considered a serious problem by a factor 30, it exceeds United States Soil Conservation Service tolerance values by a factor of 46, and it exceeds average San Francisco Bay area erosion rates by a factor of 17. The resulting soil losses are effectively permanent. Neither the increased sediment yield nor the increased runoff is accomodated on the sites of use, and both are causing adverse effects to neighboring properties.     

Experimental implementation and verification of multi‐degrees‐of‐freedom effective force testing

This paper presents an experimental implementation and verification of multi‐degrees‐of‐freedom effective force testing (MDOF‐EFT). An experimental setup that consists of a two‐degrees‐of‐freedom structural system and two hydraulic actuators at the Johns Hopkins University was utilized in this study. First, experimental system identification was performed to develop compatible analytical models for the multi‐input and multi‐output systems. Dynamics of the control plant, that is, the valve‐to‐force relations, were modeled with a rational polynomial transfer function matrix and delay components. By using the analytical model, a centralized decoupling loop‐shaping force feedback controller was designed such that the forces are uncoupled and the loop transfer functions have desirable dynamic characteristics in the frequency domain. Then, a series of harmonic force and earthquake simulation tests were performed to assess capabilities and limitations of MDOF‐EFT. Experimental results showed that the dynamic forces in the two actuators were accurately controlled to provide tracking while the system was stable and robust for the entire period of the experiment. Furthermore, earthquake simulation tests with increased levels of the reference forces demonstrated the feasibility of MDOF‐EFT with highly nonlinear test structures. Copyright © 2013 John Wiley & Sons, Ltd.     

Substructure shake table test method using a controlled mass: formulation and numerical simulation

This study proposes a new substructure shake table test method that allows for experimental investigation of the lower portion of structures while the upper part is numerically analyzed. Compatibility conditions are derived to ensure that the dynamic characteristics of the substructured system are equivalent to the reference entire structure. This method utilizes controlled masses to incorporate interface forces from the computational substructure to the experimental substructure. A feasible implementation procedure for the interface force compatibility is developed using a series of conversions and signal processing. For validation of the capabilities and limitations of the proposed substructure method, numerical simulations are performed using detailed models including dynamics of the controlled mass systems. Results from the numerical simulations showed that the proposed substructure method produced comparable results to the reference entire simulations. The average error between top floor displacements produced by substructured and entire responses for earthquake inputs was 7.1%. Numerical studies showed that the substructure method has potential to serve as an alternative to shaking table tests of entire structures. Copyright © 2012 John Wiley & Sons, Ltd.     

(Au,Ag)Te2 Minerals from Epithermal Gold Deposits in Japan

Chemical composition and mode of occurrences of (Au, Ag)Te₂ minerals such as calaverite (AuTe₂), sylvanite (AuAgTe₄) and krennerite ((Au, Ag)Te₂) in epithermal gold telluride ores from Suzaki, Kawazu and Teine are examined. In the ores from Suzaki, (Au, Ag)Te₂ minerals occur in microbands of tellurides and fine quartz. The minerals in telluride bands change from krennerite, via calaverite‐native tellurium, to sylvanite, in the order of crystallization. A sample from Kawazu contains sylvanite and native tellurium with stutzite, hessite and tetradymite in the coarser gray quartz part. The Teine sample also contains sylvanite and native tellurium with barite and quartz. The peak patterns of XRD of calaverite, krennerite and sylvanite from Suzaki are almost identical to that of JCPDS 43–1472, JCPDS 8–20 and JCPDS 9–477, respectively. The Te, Au, Cu, and Ag contents of calaverite from Suzaki range from 56.4 to 57.9 wt.%, from 41.6 to 42.6 wt.%, from 0.28 to 0.45 wt.% and from 0.14 to 0.31 wt.%, respectively, corresponding to the formula Au_0.97Ag_0.01Cu_0.02Te₂. The Te, Au, Ag, and Cu contents of krennerite from Suzaki range from 59.6 to 61.4 wt.%, from 31.3 to 33.6 wt.%, from 4.91 to 6.13 wt.% and from 0.66 to 0.80 wt.%, respectively, corresponding to the formula Au_0.71Ag_0.22Cu_0.05Te₂ with Au and Ag ranging from 0.68 to 0.74 and from 0.20 to 0.25, respectively. The Te, Au, Ag, and Cu contents of sylvanite from Suzaki range from 61.5 to 63.4 wt.%, from 24.1 to 27.4 wt.%, from 10.0 to 12.5 wt.% and from 0.00 to 0.12 wt.%, respectively. The Te, Au, Ag, and Cu contents of sylvanite from Kawazu range from 62.7 to 63.3 wt.%, from 23.5 to 24.1 wt.%, from 12.0 to 12.5 wt.% and from 0.09 to 0.16 wt.%, respectively. The Te, Au, Ag, Cu and Fe contents of sylvanite from Teine range from 61.8 to 63.5 wt.%, from 23.6 to 24.7 wt.%, from 11.9 to 13.3 wt.%, from 0.01 to 1.65 wt.% and from 0.00 to 0.02 wt.%, respectively. The average formulae of sylvanite from Suzaki, Kawazu, and Teine are expressed as Au_1.06Ag_0.94Cu_0.02Te₄, Au_1.00Ag_0.95Cu_0.02Te₄ and Au_1.01Ag_0.95Cu_0.06Te₄, respectively. Judging from the mineral assemblages of these ores and other localities, Au–Te mineralization in the Japanese Islands can be divided into four types: native gold–calaverite at Date and Agawa, krennerite(?native tellurium) at Osore‐zan and Mutsu, sylvanite–native tellurium–hessite at Teine, Kawazu, Kobetsuzawa, and Kato, and polyminerallic assemblages at Suzaki and Kushikino. The pH–Eh diagram of aqueous tellurium species and tellurium minerals at 250°C indicates that (Au, Ag)Te₂ minerals in epithermal gold telluride mineralization would have been formed under middle to low Eh and acidic (to intermediate) pH conditions. It is possible that dilute tellurium‐containing fluid would scavenge dilute gold.