Production of nuclei from ammonia and nitric acid

Summary The size and charge distribution of nuclei obtained by passing air over ammonia and nitric acid are examined. In agreement with McHenry it was found that the average radius is less than 1.0×10^–6 cm. The heterogeneity of the nuclei is discussed.

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Zusammenfassung Es wurde die Grösse und Ladungsverteilung von Kernen, welche erhalten wurden, wenn Luft über Lösungen von Ammoniak und Salpetersäure streicht, untersucht. In Übereinstimmung mit McHenry wurde gefunden, dass der durchschnittliche Radius der Kerne kleiner als 1.0×10^–6 cm ist. Es wird die Ungleichartigkeit der Kerne diskutiert.

     

Determination of silica activity in Bushveld rocks

Values of silica activity have been calculated for Bushveld rocks from an extension of the mafic layered sequence north of the town of Bethal in the south-eastern Transvaal as well as the Roossenekal area in the eastern limb of the Complex. The samples examined contain the coexisting assemblage olivine, Ca-poor pyroxene, Ca-rich pyroxene and plagioclase. This enabled silica activities to be calculated from the following reactions: (Mg, Fe)₂SiO₄+SiO₂2(Mg, Fe)SiO₃, CaAl₂SiO₆+SiO₂CaAl₂Si₂O₈. Parallel curves of increasing silica activity with fractionation were established 0.20 log units apart. This represented a pressure of emplacement for the top of the layered zone in the Bethal area of 2.72±0.79 kbars. A value of 1.47±0.62 kbars was obtained for the Roossenekal area. These values are equivalent to 9.1±2.6 km and 4.9±2.1 km respectively, the latter figure being consistent with the minimum thickness of 4550 m of felsite and granophyre originally overlying the layered sequence and still preserved in the area west of Roossenekal.     

Factors effecting the stability field of Ca-poor pyroxene and the origin of the Ca-poor minimum in Ca-rich pyroxenes from tholeiitic intrusions

Ca-poor pyroxene ceases to crystallise towards the end of fractionation in tholeiitic intrusions and is usually replaced by Fe-rich olivine. Using the data of Nicholls et al. (1971), the \(a_{{\text{SiO}}_2 }\) at which olivine and pyroxene can coexist has been calculated at different temperatures and pressures. From these calculations it is clear that the Fe/Mg ratio of the last Ca-poor pyroxene to crystallise from a melt is increased by raising the temperature or pressure of crystallisation. The Ca-poor pyroxene-Fe-rich olivine relationship is also dependent on the \(a_{{\text{SiO}}_2 }\) of the melt. In magmas which crystallise Fe-rich olivine before quartz, inicreasing their \(a_{{\text{SiO}}_2 }\) will raise the Fe/Mg ratio of the last Ca-poor pyroxene to crystallise. If the \(a_{{\text{SiO}}_2 }\) of the magma is so high that SiO₂ saturation is reached before the appearance of cumulus Fe-rich olivine, any further increase in the \(a_{{\text{SiO}}_2 }\) of the melt will not influence the stability field of Ca-poor pyroxene. The replacement of Ca-poor pyroxene by Fe-rich olivine requires the magma to reach a high level of a _FeO late in its fractionation. If a magma fractionates with an FeO depletion trend, Ca-poor pyroxene is replaced by Ca-rich pyroxene. The reaction is initiated by the appearance of cumulus K-feldspar which results in a marked reduction in the amount of anorthite crystallising from the magma. This increases the a _CaO of the melt so that Ca-poor pyroxene is replaced by Ca-rich pyroxene.     

Drought 2002 in Colorado: An Unprecedented Drought or a Routine Drought?

The 2002 drought in Colorado was reported by the media and by public figures, and even by a national drought-monitoring agency, as an exceptionally severe drought. In this paper we examine evidence for this claim. Our study shows that, while the impacts of water shortages were exceptional everywhere, the observed precipitation deficit was less than extreme over a good fraction of the state. A likely explanation of this discrepancy is the imbalance between water supply and water demand over time. For a given level of water supply, water shortages become intensified as water demands increase over time. The sobering conclusion is that Colorado is more vulnerable to drought today than under similar precipitation deficits in the past.     

Radar observations of Comet 2P/Encke during the 2003 apparition

The nucleus of Comet 2P/Encke was detected with the Arecibo radar during the close approach of November, 2003, making this the first comet to yield radar detections at two different apparitions. Although the measured radar cross section of 1.0 km² was close to that obtained in 1980, the Doppler bandwidth was nearly four times larger. Most of this bandwidth difference can simply be attributed to a different observing aspect relative to the spin axis proposed by Sekanina [1988, Astron. J. 95, 911] and Festou and Barale [2000, Astron. J. 119, 3119]. Comparison of the 2003 Doppler bandwidth with infrared-based size estimates supports an 11-h dominant rotation period and excludes slower 15- and 22-h periods that have also been suggested. If one assumes a short-axis-mode rotation with an 11-h period, then the Doppler bandwidth indicates that the nucleus is an oblong object with a long-axis dimension of 9 km. The estimated radar albedo of 0.05 is similar to that measured for C/IRAS-Araki-Alcock, providing further evidence that comet nuclei have relatively low surface densities of ∼0.5-1.0 g cm⁻³. No broadband echo component was detected from large coma grains despite predictions, based on optical/infrared models, that such a component might be detectable.     

Kiglapait geochemistry VII: Yttrium and the rare earth elements

Based on 51 wholerock analyses by XRF and summation over the layered group, the Kiglapait Intrusion contains 4.7_?1.6^+1.2 ppm Y, which resides principally in augite and apatite. Using liquid compositions calculated by summation, the partition coefficient D^AUG/L_Y is 0.95 ± 0.12 from 84 to 97 PCS (percent solidified) and 1.5 ± 0.4 above 97 PCS. For feldspar, the most likely value for D is 0.028 ± 0.02 (N = 6).REE analyses for 13 whole rocks were interpreted with the aid of yttrium models to yield trends for wholerocks and liquids vs PCS. Summations over the rocks of the layered group gave La = 2.5, Ce = 5.8, Nd = 3.9, Sm = 1.0, Eu = 0.8, Tb = 0.17, Yb = 0.37, and Lu = 0.06 ppm, with 2 s.d. errors near ± 30%. All these elements are highly incompatible until the arrival of augite, which affects chiefly the HREE, and apatite, which affects all (but more strongly, the LREE). The net result is that after apatite arrival at 94 PCS, the liquid compositions are nearly constant, hence D^WR/L_REE ≈ 1.0. These results are compatible with the mineralogy of the intrusion and the estimated partition coefficients for feldspar, olivine, augite, apatite, and Fe-Ti oxide minerals. For pre-apatite liquids, D^FSP/L_REE vary regularly with the normative di content of the liquid and change by an order of magnitude, hence the bulk liquid composition must be considered in any attempt to invert the compositions of feldspars to parent liquids.The Eu anomaly at first decreases in Kiglapait liquids due to plagioclase fractionation, but then increases due to removal of augite and apatite with negative Eu anomalies. The features dominantly responsible for Eu partitioning are liquid structure and, for monoclinic ternary feldspars, crystal structure. The former is best monitored by the augite or diopside content of the liquid and the latter, by the K content of the feldspar.The chondrite-normalized REE pattern for the intrusion has La_N = 7.4, Lu_N = 1.6, (Ce/Yb)_N = 3.6, and Eu/Eu* = 2.4, indicating its feldspar-rich nature. The chilled margin of the nearby Hettasch Intrusion has a similar but more evolved pattern, corresponding roughly to the Kiglapait liquid at 70 PCS. As with other data, those for the REE suggest source differences for the two intrusions rather than a relationship due to fractionation.     

Radar observations of 8P/Tuttle: A contact-binary comet

Arecibo radar imagery of Comet 8P/Tuttle reveals a 10-km-long nucleus with a highly bifurcated shape consistent with a contact binary. A separate echo component was also detected from large (>cm-size), slow-moving grains of the type expected to contribute to the Ursid meteor stream.     

Determining asteroid spin states using radar speckles

Knowing the shapes and spin states of near-Earth asteroids is essential to understanding their dynamical evolution because of the Yarkovsky and YORP effects. Delay-Doppler radar imaging is the most powerful ground-based technique for imaging near-Earth asteroids and can obtain spatial resolution of <10 m, but frequently produces ambiguous pole direction solutions. A radar echo from an asteroid consists of a pattern of speckles caused by the interference of reflections from different parts of the surface. It is possible to determine an asteroid’s pole direction by tracking the motion of the radar speckle pattern. Speckle tracking can potentially measure the poles of at least several radar targets each year, rapidly increasing the available sample of NEA pole directions. We observed the near-Earth asteroid 2008 EV5 with the Arecibo planetary radar and the Very Long Baseline Array in December 2008. By tracking the speckles moving from the Pie Town to Los Alamos VLBA stations, we have shown that EV5 rotates retrograde. This is the first speckle detection of a near-Earth asteroid.     

Changes in beach gravel lithology caused by anthropogenic activities along the southern coast of Lake Michigan, USA

The southern coast of Lake Michigan is the most urbanized and most densely populated area in the Great Lakes region. Development of steel mills, harbors, and municipalities in NW Indiana and in NE Illinois in the last century and a half altered the nearshore environment so much that native beach gravel (>8 mm) now exist only in the exhumed paleo-beach remnants from the Nipissing Phase (~4,500 years ago) of Lake Michigan. Native gravel, collected from paleo-beach remnants at Mount Baldy Dune and Beach House Blowout, contain predominantly beach shingle, very platy siltstones (71–78 %), with secondary crystalline pebbles (18 %) in the east, and carbonate pebbles (12 %) in the west. A large amount of anthropogenic fill (steel industry waste, waste from power generating plants, construction debris, railroad, and road fill) has been added since the late 1800s to fill Lake Michigan and expand industrial land. Four areas of major coastal structures—Michigan City Pier and Breakwater, Burns Harbor Pier and Breakwater, Gary Works Pier, and Indiana Harbor Peninsula—altered the natural littoral drift and created four independent sectors on Indiana’s coast—Northeastern, Eastern, Central, and Western—between which no natural transfers of coarse sediments occur. Downdrift from the coastal structures, severe beach erosion has prompted extensive beach nourishment with non-native sandy gravel. Four distinct populations of modern beach gravel now exist along Indiana’s coast of Lake Michigan: (1) native gravel with diluted beach nourishment influence, (2) native gravel with a minor industrial influence, (3) compact gravel of nourished origin, and (4) anthropogenic gravel of industrial origin. Native gravel with diluted nourishment influence is found in the western, downdrift areas of the Northeastern (from Long Beach to Washington Park Beach) and Eastern Sectors (from eastern Indiana Dunes State Park to western Dune Acres) and contains up to 40 % compact carbonate and crystalline pebbles in addition to native beach shingle. Native gravel with minor industrial influence is found in the Central Sector of Indiana’s coast (from central Ogden Dunes to Marquette Beach) and contains predominantly beach shingle, platy clastic lithology, but also up to 30 % of chert and other pebbles released by industry. Compact gravel of nourished origin contains 60–90 % of carbonate and crystalline pebbles, and is found in the eastern, updrift areas of the Northeastern (Michiana Beach and Duneland Beach) and Eastern Sectors (from Crescent Beach to the western Beverly Shores). Anthropogenic gravel of industrial origin contains 70–90 % compact chert and slag and is found in every beach of the Western Sector and in the westernmost beach of the Central Sector. Streams draining into southern Lake Michigan generally contain little coarse sediment except in their channels near the roads and railroads, where angular to subangular anthropogenic pebbles predominate (70–90 %). However, streams have very little influence on gravel lithology along the coast because they seldom discharge anthropogenic gravel into Lake Michigan. Recent changes in gravel lithology along the southern Lake Michigan coast may affect changes in nearshore benthic flora and fauna as well as algal and bacterial blooms during warm summer months.