Atmospheric boundary-layer structure observed during a haze event due to forest-fire smoke

During a haze event in Baltimore, U.S.A. from July 6 to 8, 2002, smoke from forest fires in the Québec region (Canada), degraded air quality and impacted upon local climate, decreasing solar radiation and air temperature. The smoke particles in and above the atmospheric boundary layer (ABL) served as a tracer and provided a unique opportunity to investigate the ABL structure, especially entrainment. Elastic backscatter lidar measurements taken during the haze event distinctly reveal the downward sweeps (or wisps) of smoke-laden air from the free atmosphere into the ABL. Visualisations of mechanisms such as dry convection, the entrainment process, detrainment, coherent entrainment structures, and mixing inside the ABL, are presented. Thermals overshooting at the ABL top are shown to create disturbances in the form of gravity waves in the free atmosphere aloft, as evidenced by a corresponding ripple structure at the bottom of the smoke layer. Lidar data, aerosol ground-based measurements and supporting meteorological data are used to link free atmosphere, mixed-layer and ground-level aerosols. During the peak period of the haze event (July 7, 2002), the correlation between time series of elastic backscatter lidar data within the mixed layer and the scattering coefficient from a nephelometer at ground level was found to be high (R=0.96 for z =324 m, and R=0.89 for z=504 m). Ground-level aerosol concentration was at a maximum about 2 h after the smoke layer intersected with the growing ABL, confirming that the wisps do not initially reach the ground.     

ESEEM of industrial quartz powders: insights into crystal chemistry of Al defects

A set of raw industrial materials, that is, pure quartz and quartz-rich mixtures, were investigated through electron paramagnetic resonance and electron spin echo-envelope modulation spectroscopies, with the aim of evaluating the effective role played by defect centres and of assessing whether they can be used to monitor changes in the physical properties of quartz powders with reference to their health effects. The obtained results point to two interactions of the Al defect centres with H⁺, hosted in sites within the channels parallel and perpendicular to the c axis of quartz, respectively. These two Al/H⁺ (h_Al) centres exhibit a weak chemical bond, and their relative amounts appear to be modified/controlled by the thermo-mechanical processes underwent by powders. Indeed, a mechanically promoted inter-conversion between the two kinds of site is suggested. As a consequence, the h_Al centres are effective in monitoring even modest activations of powders, through thermal or mechanical processes, and they are also supposed to play a specific, relevant role in quartz reactivity during the considered industrial processes.     

Analysis of the exoplanet containing system Kepler-13

We have applied the close binary system analysis program WinFitter, with its physically detailed fitting function, to an intensive study of the complex multiple system Kepler-13 using photometry data from all 13 short cadence quarters downloaded from the NASA Exoplanet Archive (NEA) (http://exoplanetarchive.ipac.caltech.edu). The data-point error of our normalized, phase-sequenced and binned (380 points per bin: 0.00025 phase interval) flux values, at 14 ppm, allows the model’s specification for the mean reference flux level of the system to a precision better than 1 ppm. Our photometrically derived values for the mass and radius of KOI13.01 are \(6.8\pm0.6~\mbox{M}_{\mathrm{J}}\) and \(1.44\pm0.04~\mbox{R}_{\mathrm{J}}\). The star has a radius of \(1.67\pm0.05~\mbox{R}_{\odot}\). Our modelling sets the mean of the orbital inclination \(i\) at \(94.35\pm0.14^{\circ}\), with the star’s mean precession angle \(\phi_{p}\)—\(49.1\pm5.0^{\circ}\) and obliquity \(\theta_{o}\)\(67.9 \pm 3.0^{\circ}\), though there are known ambiguities about the sense in which such angles are measured.Our findings did not confirm secular variation in the transit modelling parameters greater than their full correlated errors, as argued by previous authors, when each quarter’s data was best-fitted with a determinable parameter set without prejudice. However, if we accept that most of the parameters remain the same for each transit, then we could confirm a small but steady diminution in the cosine of the orbital inclination over the 17 quarter timespan. This is accompanied by a slight increase of the star’s precession angle (less negative), but with no significant change in the obliquity of its spin axis. There are suggestions of a history of strong dynamical interaction with a highly distorted planet rotating in a 3:2 resonance with its revolution, together with a tidal lag of \(\sim30~\mbox{deg}\). The mean precessional period is derived to be about 1000 y, but at the present time the motion of the star’s rotation axis appears to be supporting the gravitational torque, rather than providing the balance against it that would be expected over long periods of time.The planet has a small but detectable backwarming effect on the star, which helps to explain the difference in brightness just after transit and just before occultation eclipses. In assessing these findings it is recognized that sources of uncertainty remain, notably with possible inherent micropulsational effects, variations from other components of the multiple star, stellar activity, differential rotation and the neglect of higher order terms (than \(r_{1}^{5}\)) in the fitting function, where \(r_{1}\) is the ratio of the radius of the star to the mean orbital separation of planet and host star.     

《大气和海洋科学快报》征稿启事

{{@ convertAbstractHtml(article.abstractinfoCn, "cn")}}   {{if article.graphicalAbstractinfoCn && article.graphicalAbstractinfoCn != ""}}{{@ article.graphicalAbstractinfoCn}}{{/if}}     

Triggering of El Niño by westerly wind events in a coupled general circulation model

Two ten-members ensemble experiments using a coupled ocean-atmosphere general circulation model are performed to study the dynamical response to a strong westerly wind event (WWE) when the tropical Pacific has initial conditions favourable to the development of a warm event. In the reference ensemble (CREF), no wind perturbation is introduced, whereas a strong westerly wind event anomaly is introduced in boreal winter over the western Pacific in the perturbed ensemble (CWWE). Our results demonstrate that an intense WWE is capable of establishing the conditions under which a strong El Niño event can occur. First, it generates a strong downwelling Kelvin wave that generates a positive sea surface temperature (SST) anomaly in the central-eastern Pacific amplified through a coupled ocean-atmosphere interaction. This anomaly can be as large as 2.5°C 60 days after the WWE. Secondly, this WWE also initiates an eastward displacement of the warm-pool that promotes the occurrence of subsequent WWEs in the following months. These events reinforce the initial warming through the generation of additional Kelvin waves and generate intense surface jets at the eastern edge of the warm-pool that act to further shift warm waters eastward. The use of a ten-members ensemble however reveals substantial differences in the coupled response to a WWE. Whereas four members of CWWE ensemble develop into intense El Niño warming as described above, four others display a moderate warming and two remains in neutral conditions. This diversity between the members appears to be due to the internal atmospheric variability during and following the inserted WWE. In the four moderate warm cases, the warm-pool is initially shifted eastward following the inserted WWE, but the subsequent weak WWE activity (when compared to the strong warming cases) prevents to further shift the warm-pool eastwards. The seasonal strengthening of trade winds in June–July can therefore act to shift warm waters back into the western Pacific, reducing the central-eastern Pacific warming. This strong sensitivity of the coupled response to WWEs may therefore limit the predictability of El Niño events, as the high frequency wind variability over the warm pool region remains largely unpredictable even at short time lead.     

High temperature gas–solid reactions in calc–silicate Cu–Au skarn formation; Ertsberg,Papua Province,Indonesia

The 2.7–3 Ma Ertsberg East Skarn System (Indonesia), adjacent to the giant Grasberg Porphyry Copper deposit, is part of the world’s largest system of Cu–Au skarn deposits. Published fluid inclusion and stable isotope data show that it formed through the flux of magma-derived fluid through contact metamorphosed carbonate rock sequences at temperatures well above 600° C and pressures of less than 50 MPa. Under these conditions, the fluid has very low density and the properties of a gas. Combining a range of micro-analytical techniques, high-resolution QEMSCAN mineral mapping and computer-assisted X-ray micro-tomography, an array of coupled gas–solid reactions may be identified that controlled reactive mass transfer through the ~ 1 km³ hydrothermal skarn system. Vacancy-driven mineral chemisorption reactions are identified as a new type of reactive transport process for high-temperature skarn alteration. These gas–solid reactions are maintained by the interaction of unsatisfied bonds on mineral surfaces and dipolar gas-phase reactants such as SO₂ and HCl that are continuously supplied through open fractures and intergranular diffusion. Principal reactions are (a) incongruent dissolution of almandine-grossular to andradite and anorthite (an alteration mineral not previously recognized at Ertsberg), and (b) sulfation of anorthite to anhydrite. These sulfation reactions also generate reduced sulfur with consequent co-deposition of metal sulfides. Diopside undergoes similar reactions with deposition of Fe-enriched pyroxene in crypto-veins and vein selvedges. The loss of calcium from contact metamorphic garnet to form vein anhydrite necessarily results in Fe-enrichment of wallrock, and does not require Fe-addition from a vein fluid as is commonly assumed.     

Impact of single-point GPS integrated water vapor estimates on short-range WRF model forecasts over southern India

Specifying physically consistent and accurate initial conditions is one of the major challenges of numerical weather prediction (NWP) models. In this study, ground-based global positioning system (GPS) integrated water vapor (IWV) measurements available from the International Global Navigation Satellite Systems (GNSS) Service (IGS) station in Bangalore, India, are used to assess the impact of GPS data on NWP model forecasts over southern India. Two experiments are performed with and without assimilation of GPS-retrieved IWV observations during the Indian winter monsoon period (November–December, 2012) using a four-dimensional variational (4D-Var) data assimilation method. Assimilation of GPS data improved the model IWV analysis as well as the subsequent forecasts. There is a positive impact of ～10 % over Bangalore and nearby regions. The Weather Research and Forecasting (WRF) model-predicted 24-h surface temperature forecasts have also improved when compared with observations. Small but significant improvements were found in the rainfall forecasts compared to control experiments.     

Tectono-sedimentary evolution of the Miocene Oued Dayr Formation (Ghomaride Complex,Internal Domain of the Maghrebian Rif Belt,Morocco)

This work deals with sedimentological, petrographic, and structural analyses of a middle Miocene late-orogenic sedimentary cycle, denoted Oued Dayr Formation, recognized in the Rifian sector of the Maghrebian Chain (Morocco). The analyzed Formation (75 m thick) starts with 15–20 m of light colored polymict conglomerates, with minor sandstone beds, lying on the Paleozoic basement and Mesozoic cover of the Ghomaride Nappe. Facies analysis indicates a fining-upward deposition in a marine environment characterized by increasing deepening, reflecting a subsidence rate that exceeds sedimentary supply. Petrographic analysis points out that sandstones are represented by litharenites originated by erosion of recycled orogen. The conglomerates pebbles and cobbles consist of Alpine low- to high-grade metamorphic rocks as metarenites, phyllites, mylonitic quartzites, micaschists, augen gneisses deriving from the exhumed deep metamorphic basement, the overlying metasedimentary of the Sebtide Nappes and of sedimentary rocks as sandstones, jaspes, limestones, and shales deriving from the Ghomaride Nappes and their sedimentary cover. Data reveal mixed provenance indicating that the Oued Dayr Formation was fed by the Internal Nappes stack of the Maghrebian Chain. Structural analysis shows that the Oued Dayr Formation accumulated in a Thrust-Top basin, during an early extension (D₀ phase), recorded by synsedimentary normal faults within middle Langhian deposits on the rear of the Internal Nappes stack. Subsequent ductile and brittle compressional (D₁, D₂, D₃) and extensional (D₄) deformation phases occurred during and/or after the stacking, exhumation, and early unroofing of Sebtide Complex coeval with the opening of the western Mediterranean back-arc basins since middle Miocene time.     

Experimental and numerical investigations of stresses in a fully grouted rock bolts

Rock bolts are widely used for rock reinforcement in hard-rock mining and civil engineering since a long time. However the use of fully grouted rock bolts and cable bolts is limited in coal mines. In order to improve performance of the rock bolts as a supplementary roof support system for any type of roof condition in coal measured formations, it is necessary to have a good understanding of the behavior of the bolt–grout and grout–rock interactions as well as the mechanism of load transfer in rock bolts.As the performance of grouted bolts depends on bond strength, extensive laboratory pullout as well as pushout tests were conducted in the present investigations with the variations in the bolt diameters, length and cement–water mixing ratios of grout. The load–displacement curves were developed and were verified with the numerical results obtained from finite element analysis using ALGOR software.Numerical models were validated for pushout tests and a detailed analysis was carried out to know the displacement, stress, strain distribution along the bolt.