Submerged caves of Croatia: distribution,classification and origin

Presently, 235 submerged caves and pits have been recorded along the Croatian coast and islands, partly or completely submerged by sea water. Contrary to the inland situation, recorded submerged features are predominantly horizontal (60%), though there are indications that the real situation is similar to that of the continental part where 69% are vertical pits. Completely marine conditions are established in 126 caves and the rest are anchihaline caves and submarine springs. Speleothems are found in more than 140 caves. By their origin, the investigated caves are all continental features formed in Mesozoic and Palaeogene carbonates, subsequently submerged owing to sea transgression. Due to the relatively low wave energy, rapid sea level rise and maturity of the host rock, they do not fit into concepts of a sea cave or a flank margin cave development, but they fulfil several conditions for being the blue holes. Since the term ‘blue hole’ is mainly associated with the Bahamian karst, our attempt is only to show the possible similarities with no intention of ascribing that term to the Croatian caves. Beside karstological issues, Croatian submerged caves are unique environmental, archaeological and tourism assets.     

Modeling aqueous alteration of CM carbonaceous chondrites

Abstract— Results from an inorganic geochemical modeling study support a scenario in which low‐temperature aqueous alteration of an anhydrous CM asteroidal parent body and melt water from H₂O and CO₂ ices produces the altered assemblage observed in CM carbonaceous chondrites (chrysotile, greenalite, tochilinite, cronstedtite and minor calcite and magnetite). We consider a range of possible precursor mineral assemblages, varying with respect to the Fe‐oxidation state of the initial anhydrous phases. The aqueous solutions produced by this alteration are generally strongly basic and reducing and a large quantity of H₂, and possible CH₄, gas can be released during aqueous alteration.     

The effect of thermal pollution on benthic foraminiferal assemblages in the Mediterranean shoreface adjacent to Hadera power plant (Israel)

The thermal pollution patch of Hadera power plant was used as a natural laboratory to evaluate the potential long-term effects of rise in Eastern Mediterranean SST on living benthic foraminifera. Their sensitivity to environmental changes makes foraminifera ideal for this study. Ten monthly sampling campaigns were performed in four stations located along a temperature gradient up to 10 °C from the discharge site of heated seawater to a control station. The SST along this transect varied between 25/18 °C in winter and 36/31 °C in summer. A significant negative correlation was found between SST in all stations and benthic foraminiferal abundance, species richness and diversity. The total foraminiferal abundance and species richness was particularly low at the thermally polluted stations especially during summer when SST exceeded 30 °C, but also throughout the entire year. This indicates that thermal pollution has a detrimental effect on benthic foraminifera, irrelevant to the natural seasonal changes in SST.     

Hydrological and meteorological data from research catchments at the Marcell Experimental Forest,Minnesota, USA

The Marcell Experimental Forest (MEF) in northern Minnesota, USA, with hydrological research and monitoring of peatland catchments in a low-topographic relief landscape, contrasts with the mountainous terrain that typifies most research catchments. Six research catchments were instrumented and hydrological and meteorological monitoring was initiated during 1960. Paired-catchment studies, which started during 1969, have been used to assess land management and environmental change effects on forests, water availability, and biogeochemistry. Over the decades, the research and collaborations have proliferated to include new monitoring and ecosystem experiments. We provide an overview of available datasets and access information for hydrological and meteorological data. Data on streamflow, water table elevation, precipitation, snow, ground frost, air temperature, soil moisture, upland runoff, and water chemistry are discoverable with associated metadata and are archived through several Web-based, community repositories. The research programme is ongoing and we anticipate updates on an annual or more frequent basis. Additionally, we aim to release other physical, chemical, and isotopic measurements associated with long-term catchment monitoring and studies at the MEF.     

The contribution of Dutch landscape painters to the conservation of geoheritage

Landscape images are a way to register geoheritage, and we have applied it here in a consideration of the landscapes of the Netherlands. Before the 1950s these landscapes were documented chiefly by landscape painters; with useful photographs of limited availability. We have looked through a large number of paintings of Dutch landscapes to assess their geoheritage value, and present here a first reconnaissance.     

Fourier transform infrared spectroscopy,a new method for rapid determination of total organic and inorganic carbon and biogenic silica concentration in lake sediments

We demonstrate the use of Fourier transform infrared spectroscopy (FTIRS) to make quantitative measures of total organic carbon (TOC), total inorganic carbon (TIC) and biogenic silica (BSi) concentrations in sediment. FTIRS is a fast and cost-effective technique and only small sediment samples are needed (0.01 g). Statistically significant models were developed using sediment samples from northern Sweden and were applied to sediment records from Sweden, northeast Siberia and Macedonia. The correlation between FTIRS-inferred values and amounts of biogeochemical constituents assessed conventionally varied between r = 0.84–0.99 for TOC, r = 0.85–0.99 for TIC, and r = 0.68–0.94 for BSi. Because FTIR spectra contain information on a large number of both inorganic and organic components, there is great potential for FTIRS to become an important tool in paleolimnology.     

Wetland development, permafrost history and nutrient cycling inferred from late Holocene peat and lake sediment records in subarctic Sweden

Permafrost in peatlands of subarctic Sweden is presently thawing at accelerated rates, which raises questions about the destiny of stored carbon and nutrients and impacts on adjacent freshwater ecosystems. In this study we use peat and lake sediment records from the Stordalen palsa mire in northern Sweden to address the late Holocene (5,000 cal BP-present) development of the mire as well as related changes in carbon and nutrient cycling. Formation, sediment accumulation and biogeochemistry of two studied lakes are suggested to be largely controlled by the development of the mire and its permafrost dynamics. Peat inception took place at ca. 4,700 cal BP as a result of terrestrialisation. Onset of organic sedimentation in the adjacent lakes occurred at ca. 3,400 and 2,650 cal BP in response to mire expansion and permafrost aggradation, respectively. Mire erosion, possibly due to permafrost decay, led to re-deposition of peat into one of the lakes after ca. 2,100 cal BP, and stimulated primary productivity in the other lake at ca. 1,900–1,800 cal BP. Carbonate precipitation appears to have been suppressed when acidic poor fen and bog (palsa) communities dominated the catchment mire, and permafrost-induced changes in hydrology may further have affected the inflow of alkaline water from the catchment. Elevated contents of biogenic silica and diatom pigments in lake sediments during periods of poor fen and bog expansion further indicate that terrestrial vegetation influenced the amount of nutrients entering the lake. Increased productivity in the lake likely caused bottom-water anoxia in the downstream lake and led to recycling of sediment phosphorous, bringing the lake into a state of self-sustained eutrophication during two centuries preceding the onset of twentieth century permafrost thaw. Our results give insight into nutrient and permafrost dynamics in a subarctic wetland and imply that continued permafrost decay and related vegetation changes towards minerotrophy may increase carbon and nutrient storage of mire deposits and reduce nutrient fluxes in runoff. Rapid permafrost degradation may on the other hand lead to widespread mire erosion and to relatively short periods of significantly increased nutrient loading in adjacent lakes.     

Geoid and topography of Venus in various thermal convection models

Important though indirect information about the internal structure of Venus is provided by its topography and geoid. In the last decades this information has been used to constrain the Venus mantle viscosity structure and its dynamic regime. Recently, the geodynamic inversion of the Venus?? geoid and topography resulted in a group of best fitting viscosity profiles. We use these viscosity models here as an input to our mantle convection code. We carry out simulations of the Venus?? mantle evolution in a 3D spherical shell with depth dependent viscosity and check whether the character of the dynamic topography and the geoid represented by their power spectra fits the observed quantities. We compare the results with several other models obtained for different viscosity stratifications (constant, constant with highly viscous lithosphere, linear increase of viscosity). Further, we estimate the effect of other factors such as internal heating and varying Rayleigh number. We use a 2D spherical axisymmetric convection code to study the effect of lateral viscosity variations. In these 2D models we monitor the topography and the geoid developing above the axisymmetric plume and compare them with the observed elevations of Venus?? geoid and topography in several Regia. Though none of the models fits observed data perfectly, we can generally conclude, that the best fit between the observed and predicted quantities is reached for viscosity profiles with 200 km thick lithosphere followed by a gradual increase of viscosity with depth and with the upper mantle viscosity of 2 × 10 ²¹ Pa s. For all viscosity profiles the predicted geoid and topography spectra match the observed ones only up to the degree 40, thus indicating other than dynamic origin of these quantities for higher degrees.     

Anthrosols in Iron Age Shetland: Implications for arable and economic activity

The soils surrounding three Iron Age settlements on South Mainland, Shetland, were sampled and compared for indicators of soil amendment. Two of the sites (Old Scatness and Jarlshof) were on lower‐lying, better‐drained, sheltered land; the third (Clevigarth) was in an acid, exposed environment at a higher elevation. The hypothesis, based on previous regional assessments, soil thicknesses, and excavations at Old Scatness, was that the lowland sites would have heavily fertilized soils and that the thin upland soil would show little if any amendment. Our findings indicate that the Middle Iron Age soils at Old Scatness had extremely high phosphorus levels, while the soil at Jarlshof had lower levels of enhancement. At Clevigarth, where charcoal from the buried soil was 14C dated to the Neolithic and Bronze Age, there was no evidence of arable activity or soil amendment associated with the Iron Age phases of settlement. These observations indicate that not all sites put the same amount of effort into creating rich arable soils. The three sites had very different agricultural capacities, which suggests the emergence of local trade in agricultural commodities in Iron Age Shetland. © 2008 Wiley Periodicals, Inc.