Dissolved oxygen dynamics in a eutrophic estuary,Upper Newport Bay,California

Eutrophication often causes hypoxia in estuarine and coastal systems, but the mechanisms that control hypoxic events vary among estuaries and are often difficult to discern. We monitored surface and bottom dissolved oxygen (DO) in the Upper Newport Bay (UNB), a tidally mixed estuary in southern California subject to anthropogenic nutrient loading, eutrophication and hypoxia. Our goal was to identify the environmental factors regulating DO dynamics. Six hypoxic events occurred between June and November and were associated with a combination of low solar radiation, increased freshwater discharge following precipitation, and enhanced haline stratification during reduced tidal range periods. At the head of the estuary, high macroalgal biomass and pronounced haline stratification resulted in high DO in the surface layer and low DO in the bottom layer. Oxygen-rich and oxygen-poor waters were transported down-estuary by ebb tides, resulting in DO heterogeneity throughout the UNB. Cross-wavelet analysis illustrated the down-estuary propagation of high/low DO signal correlated with the phases of diurnal photosynthetic and semi-diurnal tidal cycles.     

Uranium Behavior in the Process of Primary Pitchblende Ores Alteration by the Post‐ore Hydrothermal Solutions: An Application to Assessment of Uranium Migration from Underground Spent Nuclear Fuel Repositories

It has been shown that the main uranium ore mineral, pitchblende (uranium dioxide), is a natural analog of synthetic uraninite (also uranium dioxide), which constitutes 96% of spent nuclear fuel (SNF). Geochronological studies of the U‐Pb isotope systems in unaltered pitchblende from the orebodies reveal that these systems remained completely closed over the entire period (approximately 135 Ma) since the formation of the deposits. The bulk of the primary uranium ores within the Streltsovskoye ore field was influenced to various degrees by post‐ore hydrothermal solutions that led to pitchblende spherulites being replaced by pseudomorphs of an amorphous phase with a U‐Si composition; this phase also re‐precipitated in veinlets proximal to the pitchblende pseudomorphs. A technique specially developed by the authors was used to carry out quantitative counts of the abundance of uranium minerals by calculating the uranium mass balance in one of the orebodies subjected to hydrothermal alteration. The calculations reveal minimal uranium loss from the orebody. Uranium liberated in the process of the pseudomorphic replacement of pitchblende was immediately fixed, in situ, in the newly formed coffinite‐like amorphous U‐Si phase as a result of the development of an efficient geochemical barrier that prevented the long‐distance migration of uranium. In assessing the long‐term safety of underground SNF repositories, the results of the present study give us confidence that SNF uraninite, in terms of the preservation of its integrity as a mineral phase, provides for the reliable long‐term isolation of uranium, transuranium elements, and fission products that are “sealed” in the uraninite matrix. In the case of the mineral transformation of the uraninite matrix by hydrothermal solutions, the liberated uranium would be efficiently immobilized by the newly formed amorphous U‐Si phase.     

俄罗斯东北部提高寒冻土壤稳定性与肥力的工程措施

The rational usage of low productive cryogenic landscapes in the North-Eastern part of Russia is impossible without carrying out special engineering preparation [1]. The preventing from negative that often has destructive cryogenic processes in the area of ice-covered permafrost soils, provided by its thawing into the marginally necessary depth in the whole area. The simplest and the most effective engineering method of faulting as an age-old stock (reserve) of surplus moisture in the form of ice from the upper parts of permafrost soils is the creation of continuous furrows net on the whole surface. This method also raises the fertility of soils, reduces acidity, and raises microbiological activity and the degree of internal structure decaying. Thermophysical calculations and the results of the field study in the experimental firing grounds are the available evidences of this method which raises the thermal stability of cryogenic landscapes while mastering of global climate changes in different parts of cryolithozone.     

A major change in magma sources in late Mesozoic active margin of the circum-Sea of Japan domain: Geochemical constraints from late Paleozoic to Paleogene mafic dykes in the Sergeevka belt,southern Primorye,Russia

More than 30 mafic dykes crop out in the Sergeevka belt in the coastal South Primorye, Far East Russia, of which geologic settings have been unclear for years. This study conducted major- and trace elements characterization, Sr–Nd isotope analyses, and Ar–Ar amphibole and U–Pb zircon datings for these rocks in order to identify their origin. The results demonstrated that all dykes are characterized by high Ba/Yb and low Nb/Y, Zr/Y, and Th/Yb ratios, which suggest their origin from arc melts derived from thin wedge mantle and shallow-dipping slab. These dykes are clearly separated into two distinct age/geochemistry suites; that is, the Paleogene and Early Cretaceous one with dolerites/basalts and adakitic rocks, and the Permian–Triassic one with high-Mg and high-Al gabbro-dolerite varieties. Their geochemistry suggests that the older suite was sourced from a primitive depleted MORB mantle (DMM)-type mantle, whereas the younger suite from an enriched mantle II (EM2)-type mantle domain. The transition in source type from DMM to EM2 occurred during the Jurassic-earliest Cretaceous time, probably by a strong influence of a mantle plume onto the long-continuing subduction-related magmatism. The plume influence reached the maximum when the unique meimechite-picrite complex formed in the region.     

On the impact of atmospheric vs oceanic resolutions on the representation of the sea surface temperature in the South Eastern Tropical Atlantic

Climate Dynamics - Despite the efforts of the modelling community to improve the representation of the sea surface temperature (SST) over the South Eastern Tropical Atlantic, warm biases still...     

Impact of geochemical barriers on the accumulation of heavy metals in urban soils

Based on multidimensional statistical models that connect the levels of contents of heavy metals and metalloids in the soils of the Eastern Administrative Okrug of Moscow with landscape and anthropogenic factors, a comparative estimation of the capacity of the complex geochemical barriers in the surface layers of urban and background soils is carried out. The share of heavy metals fixed in the urban soils due to the technogenous transformation of their physical and chemical properties, which amounted to 40–50% of the total content for Bi, Pb, Cd, Sb, As, and up to 26–30% for Zn and Cu, is calculated. The growth in the content of Bi, Sb, As, Cu, Pb, and Zn in urban soils is caused by an increase in the quantity of iron and manganese oxides. The increase in the content of Sb, As, and Pb is related to organic matter; and the rise in Bi, Cd, and Cu has resulted from the increasing amounts of the silt and clay particles in the soils, which indicates the leading role of sorption geochemical barriers. Cu, Zn, and Cd also accumulate on alkaline barriers.     

Natural Metrics in the Spaces of Elliptic Orbits

Different natural metrizations by Hölder type on the five dimensional space of Keplerian elliptic orbits are introduced. Certain applications of topological and metrical properties of the space of Keplerian elliptic orbits to several problems of Celestial Mechanics are discussed.     

Multispectral polarimetry as a tool to investigate texture and chemistry of lunar regolith particles

We report results of telescope polarimetric imaging of the Moon with a CCD LineScan Camera at large phase angles, near 88°. This allows measurements of the polarization degree with an absolute accuracy better than 0.3% and detection of features with polarization contrast as small as 0.1%. The measurements are carried out in two spectral bands centered near 0.65 and 0.42 μm. We suggest characterizing the lunar regolith with the parameter a(Pmax)A, where Pmax,A, and a are the degree of maximum polarization, albedo, and the parameter describing the linear regression of the correlation Pmax-A. The parameter bears significant information on the particle characteristic size and packing density of the lunar regolith. We also suggest characterizing the lunar regolith with color-ratio images obtained with a polarization filter at large phase angles. We here consider the color-ratios C||(0.65/0.42 μm) and C_⊥(0.65/0.42 μm). Using light scattering model calculations we show that the color-ratio images obtained with a polarization filter at large phase angles suggest a new tool to study the lunar surface. In particular, it turns out that the color-ratios C||(0.65/0.42 μm) and C_⊥(0.65/0.42 μm) are sensitive to somewhat different thicknesses of the surfaces of regolith particles. We consider the applicability of the Hubble Space Telescope, the Very Large Telescope (ESO), and a spacecraft on a lunar polar orbit for polarimetric observations of the lunar surface.