The Early Palaeozoic high-grade metamorphism at the active continental margin of West Gondwana in the Andes (NW Argentina/N Chile)

The evolution of the Early Palaeozoic orogen of West Gondwana in the Cambrian to Ordovician basement of the Andes between ~18° and 32° S is investigated for pressure and temperature conditions and age of metamorphism. It is characterized by mid-crust temperatures commonly above the wet granite solidus (~650°C). Widespread felsic migmatite and rare granulite formed at pressures of ca 0.5?C0.7?GPa, locally 1.0?GPa. These rocks represent the deepest exhumed sections of the Early Palaeozoic crust. High pressure?Clow temperature rocks are absent. The crystallization ages, compiled from the literature in combination with new data, for near peak metamorphic conditions of these high-grade metamorphic rocks in NW Argentina and N Chile are ~530?C500?Ma and ~470?C420?Ma. Both age groups are spatially overlapping. Radiogenic isotope signatures (Sr, Nd, Pb) are used to characterize the Early Palaeozoic basement. The Pb and Sr isotope compositions of the Early Palaeozoic basement indicate mixing arrays between pre-Palaeozoic unradiogenic and radiogenic crust. Crustal residence ages (Sm?CNd T_DM) indicate a prominent event of crust formation around ~2?Ga, which is known continent-wide. This material was recycled during Midproterozoic and Early Palaeozoic orogenies without prominent additions of new crust present in the isotope record, i.e. accretion of compositional exotic material is absent.     

New ages from the Mauritanides Belt: recognition of Archean IOCG mineralization at Guelb Moghrein,Mauritania

The Guelb Moghrein Fe oxide–Cu–Au–Co (IOCG) deposit is located in the northern part of the Mauritanides chain at the western edge of the West African Craton. It is commonly held that the orogenic belt has experienced a polyphase tectonothermal evolution, including two Panafrican and one Variscan event. Dating of two distinct morphological types of hydrothermal monazite and xenotime from Guelb Moghrein yielded in situ U–Pb ages of 2492 ± 9 and 1742 ± 12 Myr respectively. Such ages have not been reported previously from the region which is conspicuous by the widespread occurrence of banded iron formations, more akin to Proterozoic or Archean than to Paleozoic settings. The supracrustal rocks are thought, therefore, to represent a greenstone terrane that was mineralized by hydrothermal fluids during the late Archean and reactivated by middle Proterozoic fluid flow. Final emplacement at the current position on the West African Craton was at ～300 Ma during Gondwana–Laurentia collision.     

Zoisite- and clinozoisite-segregations in metabasites (Tauern Window, Austria) as evidence for high-pressure fluid–rock interaction

High-pressure zoisite- and clinozoisite-bearing segregations are common in garnet- and albite-bearing amphibolites of the Palaeozoic part of the Lower Schieferhülle, south-central Tauern Window, Austria. The zoisite segregations (primary assemblage: Zo+Qtz+Cal) formed during an early to pre-Hercynian high-pressure event (P≫0.6 GPa, T =500–550 °C) by hydrofracturing as a result of protolith dehydration. Zoisite is growth zoned from Fe³⁺-poor cores (Al₂Fe=9 mol%) to Fe³⁺-rich rims (17 mol%), and has high Sr, Pb and Ga contents and LREE-enriched REE patterns, controlling the trace element budget of the segregations. Hercynian deformation at c. 0.7 GPa/600 °C kinked and cracked primary zoisite and enhanced breakdown into secondary zoisite (13 mol% Al₂Fe), clinozoisite (40–55 mol% Al₂Fe), albite (an_<20), calcite and white mica during an Eoalpine high-pressure event at 0.9–1.2 GPa/400–500 °C. The clinozoisite segregations (primary assemblage: Czo+Qtz+Omp+Ttn+Chl+Cal) are mm- to cm-wide, vein-like bodies, cross-cutting fabric elements of the host garnet amphibolite. They formed during the Eoalpine high-pressure event at 0.9–1.2 GPa/400–500 °C. During Alpine exhumation, omphacite was pseudomorphed by amphibole, albite, quartz and clinozoisite. Oxygen isotope data suggest equilibrium between host metabasite and zoisite segregations and indicate an internal fluid source and fluid buffering by the protolith. Mobility of P, Nb and LREE changed the protolith’s trace element composition in the vicinity of the zoisite segregations: Mobilization of LREE is evidenced by decreasing modal amounts of LREE-rich epidote and decreasing LREE contents in LREE-rich epidote towards the segregations, changing the REE patterns of the host metabasite from LREE-enriched to LREE-depleted. Tectonic discrimination diagrams, based on the trace element content of metabasites, should be applied with extreme caution.     

Late orogenic rebound and oblique Alpine convergence: New constraints from subsidence analysis of the Austrian Molasse basin

Subsidence analysis of 16 wells in the Austrian Molasse basin documents major spatial and temporal changes in tectonic subsidence as well as a late-stage surface uplift. The timing of the main phase of tectonic subsidence shifted from early Oligocene in the western part of the peripheral foreland to the early Miocene in the eastern part. These temporal and spatial changes in tectonic subsidence reflect a change from oblique dextral to sinistral convergence between the Alpine nappe stack and its foreland. The main phase of sediment accumulation was delayed to the early Miocene and led to the infill of the basin and a major second, sediment-load driven phase of basement subsidence. Sediment accumulation rates in the basin reflect the build-up of topography in the Alpine mountain chain. Since approximately 6 Ma a pronounced regional uplift of the entire Molasse basin has taken place, marking the transition from lateral extrusion to orthogonal contraction within the Alpine system and deep-seated changes in geodynamic boundary conditions, possibly due to delamination of previously thickened lithosphere. Surface uplift is contemporaneous with similar processes in extra-Alpine Central Europe, where it is interpreted to reflect intra-plate stress changes.     

Transient SH-waves in a wedge-shaped layer

Summary. A generalized ray theory for transient SH -waves in a wedge-shaped layer over an elastic half-space is developed in this paper. The ray integrals for multiply reflected waves in the layer are derived in terms of two systems of coordinates and two sets of local wavenumbers, one along the free surface and the other along the sloped interface. All local wavenumbers are then transformed to a common wavenumber in all ray integrals which are evaluated by the Cagniard method. Results for the first motion approximation are in agreement with previous investigations.     

Waldsteinit

Ohne Zusammenfassung     

Dispersal events of Triassic-Jurassic boundary faunas,and paleoenvironment of Tibetan Himalaya

End-Triassic ammonoid and bivalve faunas of the Germig area, Tibetan Himalaya, lived in a tropical, shallow-water environment during the Triassic-Jurassic boundary interval. High stratigraphic resolution based on ammonite-biochrons allows to tracing the place of origin of several faunal elements. The bivalves Aguilerella and Ctenostreon occurred first in the Tibetan Himalaya and migrated from there to the eastern South Pacific, exhibiting a pantropic dispersal pattern. This dispersal route is supported by the distribution pattern of the ammonites Choristoceras, Discamphiceras, Pleuroacanthites, and Psiloceras calliphyllum. A few taxa, which went extinct everywhere else by the end of the Triassic, survived in the Tibetan Himalaya into early Early Jurassic times. They include the ammonites Choristoceras and Eopsiloceras, and the bivalves Newaagia, Terquemia, Persia, Ryderia guangdongensis, and Cultriopsis angusta. This suggests that the Tibetan Himalaya may have played a refugia role in the course of the end-Triassic mass extinction.     

Seasonal dynamics of microbial sulfate reduction in temperate intertidal surface sediments: controls by temperature and organic matter

The role of microbial sulfate reduction on organic matter oxidation was studied quantitatively in temperate intertidal surface sediments of the German Wadden Sea (southern North Sea) on a seasonal base in the years 1998–2007. The sampling sites represent the range of sediments found in the back-barrier tidal area of Spiekeroog Island: sands, mixed and muddy flats. The correspondingly different contents in organic matter, metals, and porosities lead to significant differences in the activity of sulfate-reducing bacteria with volumetric sulfate reduction rates (SRR) in the top 15 cm of up to 1.4 μmol cm^?3 day^?1. Depth-integrated areal SRR ranged between 0.9 and 106 mmol m^?2 day^?1, with the highest values found in the mudflat sediments and lower rates measured in sands at the same time, demonstrating the impact of both temperature and organic matter load. According to a modeling approach for a 154-km² large tidal area, about 39, 122, and 285 tons of sulfate are reduced per day, during winter, spring/autumn, and summer, respectively. Hence, the importance of areal benthic organic matter mineralization by microbial sulfate reduction increases during spring/autumn and summer by factors of about 2 and 7, respectively, when compared to winter time. The combined results correspond to an estimated benthic organic carbon mineralization rate via sulfate reduction of 78 g C m^?2 year^?1.