GEOCHRONOLOGY OF ~(Ar)/~(39)Ar DATING IN THE BASEMENT ROCKS IN EASTERN KUNLUN MOUNTAINS AND ITS TECTONIC IMPLICATIONS

GEOCHRONOLOGY OF ~(Ar)/~(39)Ar DATING IN THE BASEMENT ROCKS IN EASTERN KUNLUN MOUNTAINS AND ITS TECTONIC IMPLICATIONS     

Observations of some sedimentary processes acting on a tidal flat

In order to examine sedimentary processes acting on tidal flats, eighteen foot valves were “plumbed” into a small tidal cove in southern New Hampshire. Transport of suspended sediment was determined by comparing concentrations (determined by filtering) at 15 and 30 cm above the tidal flats throughout a tidal cycle. In general, sediment resuspension occurs more readily on the flood tide than the ebb. The concentration of suspended sediment follows the water mass distribution and is affected to a lesser degree by tidal currents and small amplitude waves. Deposition occurs during slack water shortly after high tide primarily in the bottom regime (15 cm); it is probably related to coarser particle sedimentation. The water mass distribution was not a simple rise and fall perpendicular to the bottom contours, but rather followed a slow clockwise gyre. The net effect on the suspended sediments was to impart a “longshore” component of drift to the suspended load during the tidal cycle.     

Light outburst of a compact galaxy

In a field near M3 photographed in U,B,V from 1963 to 1969 one of 750 compact galaxies shows a brightening of 1 mag in B during 1966/67.     

Caledonian high-pressure metamorphism in the Strona-Ceneri Zone (Southern Alps of southern Switzerland and northern Italy)

The Strona-Ceneri Zone comprises a succession of polymetamorphic, pre-Alpidic basement rocks including ortho- and paragneisses, metasedimentary schists, amphibolites, and eclogites. The rock pile represents a Late Proterozoic or Palaeozoic subduction accretion complex that was intruded by Ordovician granitoids. Eclogites, which occur as lenses within the ortho-paragneiss succession and as xenoliths within the granitoids record a subduction related high-pressure event (D1) with peak metamorphic conditions of 710 ± 30 °C at 21.0 ± 2.5 kbar. After isothermal uplift, the eclogites experienced a Barrowtype (D2) tectonometamorphic overprint under amphibolite facies conditions (570-630 °C, 7-9 kbar). U-Pb dating on zircon of the eclogites gives a metamorphic age of 457 ± 5 Ma, and syn-eclogite facies rutile gives a ²⁰⁶Pb/²³⁸U age of 443 ± 19 Ma classifying the subduction as a Caledonian event. These data show that the main tectonometamorphic evolution of the Strona-Ceneri Zone most probably took place in a convergent margin scenario, in which accretion, eclogitization of MOR-basalt, polyphase (D1 and D2) deformation, anatexis and magmatism all occurred during the Ordovician. Caledonian high-pressure metamorphism, subsequent magmatism and Barrow-type metamorphism are believed to be related to subduction and collision within the northern margin of Gondwana. Editorial handling: Edwin Gnos     

Redistribution of HFSE elements during rutile replacement by titanite

Titanite growth at the expense of rutile during retrograde hydration of eclogite into amphibolite is a common phenomenon. We investigated an amphibolite sample from the Tromsø eclogite facies terrain in Northern Norway to gain insight into the trace element distribution between rutile and titanite during incomplete resorption of the rutile by titanite. Patchy compositional zoning of Al, Ti, and F in titanite relates to the presence of a fluid with variable Ti/Al and/or F during its growth. Laser ablation ICP–MS and electron microprobe data for high field strength elements (HFSE: Nb, Zr, Ta, and Hf) of rutile resorbed by titanite indicate a pronounced enrichment of these elements in the rim of a large single rutile crystal (~8 mm) and a systematic decrease towards uniform HFSE contents in the large core. HFSE contents of smaller rutile grains (~0.5 mm) and rutile inclusions (<100 μm) in the titanite overgrowth are similar or higher than in the rims of large rutile crystals. Element profiles from the rim inward demonstrate that HFSE enrichment in rutile is controlled by diffusion. HFSE ratios in diffusion-altered rutile show systematic variations compared with the uniform core composition of the large rutile. Modelling of Zr and Nb diffusion in rutile indicates that diffusion coefficients in rutile in fluid-dominated natural systems must be considerably higher than those determined experimentally at 1 bar in dry systems. Variations of HFSE contents in the newly formed titanite show no systematic spatial distribution. HFSE ratios in titanite and the rims of rutile are different, indicating different solid/fluid distribution coefficients in these minerals. Element fractionation by diffusion into the relict rutile and during fluid-mediated growth of new titanite could substantially change the HFSE budget of these minerals and could affect their use for geochemical tracing and other applications, such as Zr-based geothermobarometry.     

Pre-Cenozoic intra-plate magmatism along the Central Andes (17–34°S): Composition of the mantle at an active margin

Sr–Nd–Pb isotope ratios of alkaline mafic intra-plate magmatism constrain the isotopic compositions of the lithospheric mantle along what is now the eastern foreland or back arc of the Cenozoic Central Andes (17–34°S). Most small-volume basanite volcanic rocks and alkaline intrusive rocks of Cretaceous (and rare Miocene) age were derived from a depleted lithospheric mantle source with rather uniform initial ¹⁴³Nd/¹⁴⁴Nd ( 0.5127–0.5128) and ⁸⁷Sr/⁸⁶Sr ( 0.7032–0.7040). The initial ²⁰⁶Pb/²⁰⁴Pb ratios are variable (18.5–19.7) at uniform ²⁰⁷Pb/²⁰⁴Pb ratios (15.60 ± 0.05). A variety of the Cretaceous depleted mantle source of the magmatic rocks shows elevated Sr isotope ratios up to 0.707 at constant high Nd isotope ratios. The variable Sr and Pb isotope ratios are probably due to radiogenic growth in a metasomatized lithospheric mantle, which represents the former sub-arc mantle beneath the early Palaeozoic active continental margin. Sr–Nd–Pb isotope signatures of a second mantle type reflected in the composition of Cretaceous (one late Palaeozoic age) intra-plate magmatic rocks (¹⁴³Nd/¹⁴⁴Nd  0.5123, ⁸⁷Sr/⁸⁶Sr  0.704, ²⁰⁶Pb/²⁰⁴Pb  17.5–18.5, and ²⁰⁷Pb/²⁰⁴Pb  15.45–15.50) are similar to the isotopic composition of old sub-continental lithospheric mantle of the Brazilian Shield.

Published Nd and Sr isotopic compositions of Mesozoic to Cenozoic arc-related magmatic rocks (18–40°S) represent the composition of the convective sub-arc mantle in the Central Andes and are similar to those of the Cretaceous (and rare Miocene) intra-plate magmatic rocks. The dominant convective and lithospheric mantle type beneath this old continental margin is depleted mantle, which is compositionally different from average MORB-type depleted mantle. The old sub-continental lithospheric mantle did not contribute to Mesozoic to Cenozoic arc magmatism.     

Partial Melting and Counterclockwise P T Path of Subducted Oceanic Crust (Sierra del Convento Melange, Cuba)

Partial melting of subducted oceanic crust has been identifiedin the Sierra del Convento mélange (Cuba). This serpentinite-matrixmélange contains blocks of mid-ocean ridge basalt (MORB)-derivedplagioclase-lacking epidote ± garnet amphibolite intimatelyassociated with peraluminous trondhjemitic–tonalitic rocks.Field relations, major element bulk-rock compositions, mineralassemblages, peak metamorphic conditions (c. 750°C, 14–16kbar), experimental evidence, and theoretical phase relationssupport formation of the trondhjemitic–tonalitic rocksby wet melting of subducted amphibolites. Phase relations andmass-balance calculations indicate eutectic- and peritectic-likemelting reactions characterized by large stoichiometric coefficientsof reactant plagioclase and suggest that this phase was completelyconsumed upon melting. The magmatic assemblages of the trondhjemitic–tonaliticmelts, consisting of plagioclase, quartz, epidote, ±paragonite, ± pargasite, and ± kyanite, crystallizedat depth (14–15 kbar). The peraluminous composition ofthe melts is consistent with experimental evidence, explainsthe presence of magmatic paragonite and (relict) kyanite, andplaces important constraints on the interpretation of slab-derivedmagmatic rocks. Calculated P–T conditions indicate counterclockwiseP–T paths during exhumation, when retrograde blueschist-faciesoverprints, composed of combinations of omphacite, glaucophane,actinolite, tremolite, paragonite, lawsonite, albite, (clino)zoisite,chlorite, pumpellyite and phengite, were formed in the amphibolitesand trondhjemites. Partial melting of subducted oceanic crustin eastern Cuba is unique in the Caribbean realm and has importantconsequences for the plate-tectonic interpretation of the region,as it supports a scenario of onset of subduction of a youngoceanic lithosphere during the early Cretaceous (c. 120 Ma).The counterclockwise P–T paths were caused by ensuingexhumation during continued subduction. KEY WORDS: amphibolite; Cuba; exhumation; partial melting; trondhjemite; subduction     

Aragonite and calcite preservation in sediments from Lake Iznik related to bottom lake oxygenation and water column depth

This study examines the forcing mechanisms driving long‐term carbonate accumulation and preservation in lacustrine sediments in Lake Iznik (north‐western Turkey) since the last glacial. Currently, carbonates precipitate during summer from the alkaline water column, and the sediments preserve aragonite and calcite. Based on X‐ray diffraction data, carbonate accumulation has changed significantly and striking reversals in the abundance of the two carbonate polymorphs have occurred on a decadal time scale, during the last 31 ka cal bp . Different lines of evidence, such as grain size, organic matter and redox sensitive elements, indicate that reversals in carbonate polymorph abundance arise due to physical changes in the lacustrine setting, for example, water column depth and lake mixing. The aragonite concentrations are remarkably sensitive to climate, and exhibit millennial‐scale oscillations. Extending observations from modern lakes, the Iznik record shows that the aerobic decomposition of organic matter and sulphate reduction are also substantial factors in carbonate preservation over long time periods. Lower lake levels favour aragonite precipitation from supersaturated waters. Prolonged periods of stratification and, consequently, enhanced sulphate reduction favour aragonite preservation. In contrast, prolonged or repeated exposure of the sediment–water interface to oxygen results in in situ aerobic organic matter decomposition, eventually leading to carbonate dissolution. Notably, the Iznik sediment profile raises the hypothesis that different states of lacustrine mixing lead to selective preservation of different carbonate polymorphs. Thus, a change in the entire lake water chemistry is not strictly necessary to favour the preservation of one polymorph over another. Therefore, this investigation is a novel contribution to the carbon cycle in lacustrine systems.     

Unusual occurrence of glauconite in a shallow lagoonal environment (Lower Cretaceous, northern Aquitaine Basin, SW France)

Some minerals are considered to be representative of specific natural environments. Among them glauconite is considered to be formed in marine deep platform conditions. However, the term glauconitic is misused to designate green minerals formed in marine outer-shelf environments. X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray analyses of individual green materials were carried out leading to the identification of glauconite in the Purbeckian facies. Green glauconite grains predominantly occur as burrow fills and occasionally as faecal pellet replacements. Two depositional environments have been identified from bottom to top of the succession: (1) an argillaceous dolomitic lagoonal sediment formed in saline, shallow water; (2) a marl-limestone alternation deposited in a brackish water estuary. The crystallochemical properties of the glauconites change abruptly. These findings show that glauconite may form in coastal environments and not only in mid-shelf to upper deep water platform environments as classically assumed. Moreover, the glauconite composition changes with the chemical conditions imposed by the local environment.     

Simulation of groundwater flow and contaminant transport at a landfill site using models

Numerical and analytical modelling studies were conducted for the analysis of groundwater flow and contaminant transport at the Innisfil landfill site in the Town of Innisfil, County of Simcoe, in Ontario, Canada. Previously conducted field studies categorized the upper stratigraphy at the site into three units: upper sand unit, upper silt/clay unit and Intermediate Sand unit. Essentially horizontal groundwater movement in the two sand units and vertical downward flow in the silt/clay unit were reported by the field hydrogeologists. In the following, application of three computer models (FLOWPATH, USGS MOC and POLLUTE) for the simulation of the groundwater flow and contaminant transport processes at the Innisfil landfill site is described. The paper focuses on the calibration of groundwater flow and contaminant transport systems, and demonstrates how the insight gained during the contaminant transport calibration was used to improve the initial groundwater flow characterization of the hydrogeological system.