The petrology of greek brown coals

Results are given in the petrography of Greek coals collected from most of the major coal-bearing basins in Greece.Rank was determined by measuring reflectances on the maceral varieties eu-ulminite A and eu-ulminite B and on the maceral textinite. Reflectances obtained from these components indicate a coalification stage of brown coal for all samples. Within this group of samples there is, however, a fairly wide scatter of reflectance values indicating for some of them the transition zone from peat to brown coal and for others a coalification stage close to the transition into bituminous coals. Reflectances obtained from eu-ulminite A and eu-ulminite B were found to correlate well with chemical rank parameters such as volatile matter and calorific value.Composition was determined by maceral analysis. The coals are in general characterized by low amounts of macerals of the inertinite group, low to intermediate amounts of macerals of the liptinite group and high amounts of macerals of the huminite group. Within the latter group densinite, attrinite, eu-ulminite and textinite make up the bulk of the samples.Typical macerals observed in the coals are illustrated by two black and white and three colour plates.Cluster analysis based on maceral distribution, mineral matter and reflectance indicates that the samples studied can be divided into three major groups. The first one is dominated by eu-ulminite and densinite with relatively high reflectances. The second is dominated by attrinite, textinite and texto-ulminite with somewhat lower reflectances. The third is represented by a single sample in which textinite and resinite are the most abundant macerals. This sample also has the lowest reflectance.     

Dynamic analysis of stacked rigid blocks

The dynamic behavior of a structural model of two stacked rigid blocks subjected to ground excitation is examined. Assuming no sliding, the rocking response of the system standing free on a rigid foundation is investigated. The derivation of the equations of motion accounts for the consecutive transition from one pattern of motion to another, each being governed by a set of highly nonlinear differential equations. The system behavior is described in terms of four possible patterns of response and impact between either the two blocks or the base block and the ground. The equations governing the rocking response of the system to horizontal and vertical ground accelerations are derived for each pattern, and an impact model is developed by conservation of angular momentum considerations. Numerical results are obtained by developing an ad hoc computational scheme that is capable of determining the response of the system under an arbitrary base excitation. This feature is demonstrated by using accelerograms from the Northridge, CA, 1994, earthquake. It is hoped that the two-blocks model used herein can facilitate the development of more sophisticated multi-block structural models.     

Dissolved organic nitrogen as an indicator of livestock impacts on soil biochemical quality

Soil degradation in the Mediterranean and other arid and semi-arid regions of the world is caused mainly by cultivation and grazing. A consequence of de-vegetation due to overgrazing has been a decrease in organic matter (litter) input to soil and a decrease of aggregate size and stability making soils more susceptible to erosion and to organic matter losses. This study provided evidence linking the Dissolved Organic Nitrogen (DON) export from river basins to livestock grazing intensity and the resulting decrease in vegetation. Koiliaris River Basin in Crete was selected to study the effects of livestock grazing on water quality because it offers a unique morphologic situation due to its karstic hydrogeology draining the upland grazing areas through karstic springs. Mass balance calculations of N loads indicated that organic N is behaving as a conservative substance. It is postulated that the two potential mechanisms of Mineralization–Immobilization-Turnover and Direct Uptake did not operate in the degraded soils of the karst and arguments are presented justifying the hypothesis. De-vegetated soils of the area had lower C and N content, the same bacterial count, but lower microbial activity, lower fungi counts and species richness and lower mineralizable N compared to naturally vegetated soils. DON was the predominant N species in both extracted soluble N pools. De-vegetated soils had lower decomposition potential compared to vegetated soils. Mineralization and plant uptake appeared to be restricted and leaching of soluble low aromaticity organic matter was favored. A linear relationship between DON export and livestock N load was obtained for five Greek basins suggesting a mechanism that operates on regional scales. The de-vegetation of grazing lands in Koiliaris River highland calcaric leptosols was shown to be a primary factor causing the decline of soil biochemical quality and DON can be used as a reliable indicator for livestock grazing impacts to soil biochemical quality.     

Eccentricity evolution in hierarchical triple systems with eccentric outer binaries

We develop a technique for estimating the inner eccentricity in hierarchical triple systems, with the inner orbit being initially circular, while the outer one is eccentric. We consider coplanar systems with well-separated components and comparable masses. The derivation of short-period terms is based on an expansion of the rate of change of the Runge–Lenz vector. Then, the short-period terms are combined with secular terms, obtained by means of canonical perturbation theory. The validity of the theoretical equations is tested by numerical integrations of the full equations of motion.     

Fast-track attribution assessments based on pre-computed estimates of changes in the odds of warm extremes

Climate Dynamics - Regional warming due to anthropogenic influence on the climate is expected to increase the frequency of very warm years and seasons. The growing research area of extreme event...     

Genetic seascape of the threatened Caribbean elkhorn coral,Acropora palmata,on the Puerto Rico Shelf

It has been proposed that the elkhorn coral Acropora palmata is genetically separated into two distinct provinces in the Caribbean, an eastern and a western population admixing in Western Puerto Rico and around the Mona Passage. In this study, the genetic structure of A. palmata sampled at 11 Puerto Rican localities and localities from Curaçao, the Bahamas and Guadeloupe were examined. Analyses using five microsatellite markers showed that 75% of sampled colonies had unique genotypes, the rest being clone mates. Genetic diversity among genets was high (H_E = 0.761) and consistent across localities (0.685–0.844). F_ST ranged from ?0.011 to 0.047, supporting low but significant genetic differentiation between localities within the previously reported eastern and western genetic provinces. Plots of genetic per geographic distances and significant Mantel tests supported isolation‐by‐distance (IBD) within Puerto Rico. Analysis with the software STRUCTURE favored a scenario with weak differentiation between two populations, assigning Eastern Puerto Rican locations (Fajardo and Culebra), Guadeloupe and Curaçao to the Caribbean eastern population and Western Puerto Rican locations (west of Vega Baja and Ponce), Mona and the Bahamas to the Caribbean western population. Vieques and San Juan area harbored admixed profiles. Standardized F_ST per 1000 km unit further supported higher differentiation between localities belonging to different STRUCTURE populations, with IBD being stronger within Puerto Rico than on larger regional scales. This stronger genetic transition seems to separate localities between putative eastern and western provinces in the Eastern Puerto Rican region, but not around the Mona Passage.     

Reducing Groundwater Pumping Cost Using Alternate Pulsed Pumping

This paper deals with water pumping cost minimization, in a confined infinite aquifer, proposing an alternate pulsed pumping schedule. The transient flow analysis is conducted for two wells with equal pumping rates. Specifically, two pumping schedules are analytically compared. In the first case, well users pump simultaneously, and in the second one they cooperate so that they pump alternately. This paper proves that the proposed alternate pumping schedule works as a stabilizer, reducing the high hydraulic drawdowns values, regardless of the aquifer characteristics. Moreover, pumping alternately is better in terms of pumping cost, compared to simultaneous pumping, though benefit become negligible as distance between wells becomes large. Two simplified equations are proposed, one to find the difference of the hydraulic drawdowns between the two pumping schedules and the other one to find the economic benefit of each well from cooperation. The equations are finally applied to a number of cases and their results are compared to the results obtained from an algorithm created to calculate the hydraulic drawdowns and the pumping cost, using the Theis equation. The results can be very useful in irrigation scheduling, as they can be applied to systems of well users/farmers, to reduce pumping cost.     

Probabilistic estimates of recent changes in temperature: a multi-scale attribution analysis

The role of anthropogenic forcings in temperature changes during recent decades is investigated over a range of spatial scales. Changes in the annual mean surface temperature and also in the warmest night of the year, which has implications for human health, are considered. Distributions of regional trends with and without the effect of human activity are produced, using constraints from a global optimal detection analysis. Anthropogenic forcings are estimated to have more than doubled the likelihood of mean warming in all regions considered except central North America, where results are more model dependent. The likelihood of warming of the warmest night has also increased, but the estimated change is more uncertain. Inferences on sub-continental scales are indicative rather than definitive because of the absence of locally important forcings and processes in model simulations, as well as model biases. As model inconsistencies may impact regional analyses, a multi-model approach is essential.     

Nitric acid forming potential of five prototype hydrocarbons

The nitric acid formed from trans-2-butene, propene, ethene, toluene, and n-butane in single hydrocarbon/NO₂/purified air systems was examined in smog chamber experiments. The effect of hydrocarbon and NO₂ concentrations on the maximum HNO₃ yield, defined as percentages of initial NO₂ converted to HNO₃, was studied in two sets of experiments. In every hydrocarbon system, we found no effect of hydrocarbon concentration variation on the nitric acid formed. Out of initially added 100 ppb NO₂, in the hydrocarbon-rich systems, ethene formed most HNO₃ (45%), followed by propene, toluene, and n-butane (24%), and trans-2-butene (13%). When the initial NO₂ concentration was varied with a constant hydrocarbon concentration, the amount of HNO₃ formed was found to linearly increase with the added NO₂ down to |HC|/|NO₂| ratios, which depended on the nature of the hydrocarbon studied. The initial rate of HNO₃ formation in hydrocarbon excess experiments varied between 50, 35, 23, 16, and 8 ppb/hr for butene, propene, toluene, ethene, and butane systems, respectively.     

Some consequences of the decomposition of organic matter in the Elefsis bay,an anoxic basin

Observations in Elefsis Bay, an anoxic basin in the Saronikos Gulf, indicate that the large accumulation of ammonia, phosphates and silicates in the deep water are the result of the decomposition of organic matter during the anoxic period. The processes of denitrification, nitrate reduction and organic decomposition are also evident. Ammonia predominates in the inorganic fraction within the whole water column.