Biostratigraphic and detrital zircon age constraints on the basement of the Himalayan Foreland Basin: Implications for a Proterozoic link to the Lesser Himalaya and cratonic India

The Himalayan Foreland Basin in the Ganga Valley is key to assessing the pre‐collision relationship between cratonic India and the Himalaya – the world's largest mountain chain. The subsurface Ganga Supergroup, representing the sedimentary basement of the Ganga Valley, has been interpreted as a northern extension of the Proterozoic Vindhyan Supergroup in cratonic India. This interpretation is contentious because the depositional age of the Ganga Supergroup is not resolved: whereas the lower Ganga Supergroup is widely regarded as Proterozoic, the upper Ganga Supergroup has been variously inferred to include Neoproterozoic, lower Palaeozoic, or Cretaceous strata. Here, we integrate biostratigraphic and detrital zircon data from drill cores to show that the entire Ganga Supergroup is likely Proterozoic and can be correlated with Proterozoic successions on the northern Indian craton and in the Lesser Himalaya. This helps redefine the first‐order stratigraphic architecture and indicates broad depositional continuity along the northern Indian margin during the Proterozoic.     

A global assessment of the impact of climate change on water scarcity

This paper presents a global scale assessment of the impact of climate change on water scarcity. Patterns of climate change from 21 Global Climate Models (GCMs) under four SRES scenarios are applied to a global hydrological model to estimate water resources across 1339 watersheds. The Water Crowding Index (WCI) and the Water Stress Index (WSI) are used to calculate exposure to increases and decreases in global water scarcity due to climate change. 1.6 (WCI) and 2.4 (WSI) billion people are estimated to be currently living within watersheds exposed to water scarcity. Using the WCI, by 2050 under the A1B scenario, 0.5 to 3.1 billion people are exposed to an increase in water scarcity due to climate change (range across 21 GCMs). This represents a higher upper-estimate than previous assessments because scenarios are constructed from a wider range of GCMs. A substantial proportion of the uncertainty in the global-scale effect of climate change on water scarcity is due to uncertainty in the estimates for South Asia and East Asia. Sensitivity to the WCI and WSI thresholds that define water scarcity can be comparable to the sensitivity to climate change pattern. More of the world will see an increase in exposure to water scarcity than a decrease due to climate change but this is not consistent across all climate change patterns. Additionally, investigation of the effects of a set of prescribed global mean temperature change scenarios show rapid increases in water scarcity due to climate change across many regions of the globe, up to 2 °C, followed by stabilisation to 4 °C.     

Shark interactions in pelagic longline fisheries

Substantial ecological, economic and social problems result from shark interactions in pelagic longline fisheries. Improved understanding of industry attitudes and practices towards shark interactions assists with managing these problems. Information on fisher knowledge and new strategies for shark avoidance may benefit sharks and fishers. A study of 12 pelagic longline fisheries from eight countries shows that incentives to avoid sharks vary along a continuum, based on whether sharks represent an economic disadvantage or advantage. Shark avoidance practices are limited, including avoiding certain areas, moving when shark interaction rates are high, using fish instead of squid for bait and deeper setting. Some conventionally employed fishing gear and methods used to target non-shark species contribute to shark avoidance. Shark repellents hold promise; more research and development is needed. Development of specifically designed equipment to discard sharks could improve shark post release survival prospects, reduce gear loss and improve crew safety. With expanding exploitation of sharks for fins and meat, improved data collection, monitoring and precautionary shark management measures are needed to ensure that shark fishing mortality levels are sustainable.     

Methylmercury production in sediments of Chesapeake Bay and the mid-Atlantic continental margin

Methylmercury (MeHg) concentration and production rates were studied in bottom sediments along the mainstem of Chesapeake Bay and on the adjoining continental shelf and slope. Our objectives were to 1) observe spatial and temporal changes in total mercury (HgT) and MeHg concentrations in the mid-Atlantic coastal region, 2) investigate biogeochemical factors that affect MeHg production, and 3) examine the potential of these sediments as sources of MeHg to coastal and open waters. Estuarine, shelf and slope sediments contained on average 0.5 to 1.5% Hg as MeHg (% MeHg), which increased significantly with salinity across our study site, with weak seasonal trends. Methylation rate constants (k_meth), estimated using enriched stable mercury isotope spikes to intact cores, showed a similar, but weaker, salinity trend, but strong seasonality, and was highly correlated with % MeHg. Together, these patterns suggest that some fraction of MeHg is preserved thru seasons, as found by others [Orihel, D.M., Paterson, M.J., Blanchfield, P.J., Bodaly, R.A., Gilmour, C.C., Hintelmann, H., 2008. Temporal changes in the distribution, methylation, and bioaccumulation of newly deposited mercury in an aquatic ecosystem. Environmental Pollution 154, 77] Similar to other ecosystems, methylation was most favored in sediment depth horizons where sulfate was available, but sulfide concentrations were low (between 0.1 and 10 μM). MeHg production was maximal at the sediment surface in the organic sediments of the upper and mid Bay where oxygen penetration was small, but was found at increasingly deeper depths, and across a wider vertical range, as salinity increased, where oxygen penetration was deeper. Vertical trends in MeHg production mirrored the deeper, vertically expanded redox boundary layers in these offshore sediments. The organic content of the sediments had a strong impact on the sediment:water partitioning of Hg, and therefore, on methylation rates. However, the HgT distribution coefficient (K_D) normalized to organic matter varied by more than an order of magnitude across the study area, suggesting an important role of organic matter quality in Hg sequestration. We hypothesize that the lower sulfur content organic matter of shelf and slope sediments has a lower binding capacity for Hg resulting in higher MeHg production, relative to sediments in the estuary. Substantially higher MeHg concentrations in pore water relative to the water column indicate all sites are sources of MeHg to the water column throughout the seasons studied. Calculated diffusional fluxes for MeHg averaged  1 pmol m^− 2 day^− 1. It is likely that the total MeHg flux in sediments of the lower Bay and continental margin are significantly higher than their estimated diffusive fluxes due to enhanced MeHg mobilization by biological and/or physical processes. Our flux estimates across the full salinity gradient of Chesapeake Bay and its adjacent slope and shelf strongly suggest that the flux from coastal sediments is of the same order as other sources and contributes substantially to the coastal MeHg budget.     

A wave model for the Great Barrier Reef

A new wind wave generation model, WAMGBR, is presented that has been adapted from WAM especially for use in the complex geometry of the Great Barrier Reef. A technique (reef parameterization) has been presented that incorporates sub-grid scale dissipation caused by coral reefs. Three other improvements to WAM have been proposed. An explicit/implicit finite difference scheme has been implemented that allows for more efficient modelling (longer time steps) while maintaining diffusive characteristics that are at least as good as those of WAM. An offset in discrete angles creates more uniform diffusive characteristics. And, a transformed spherical coordinate system allows for more efficient grid sizes and smaller grid dependent refraction. Comparisons between modelling techniques and between model and measured data show that WAMGBR produces very good results in the difficult challenge of modelling both non-cyclonic and tropical cyclone waves in the geographically complex environment of the Great Barrier Reef.     

Nonequilibrium Processes in the Solar Corona,Transition Region,Flares, and Solar Wind <Emphasis Type="Italic">(Invited Review)</Emphasis>

We review the presence and signatures of the non-equilibrium processes, both non-Maxwellian distributions and non-equilibrium ionization, in the solar transition region, corona, solar wind, and flares. Basic properties of the non-Maxwellian distributions are described together with their influence on the heat flux as well as on the rates of individual collisional processes and the resulting optically thin synthetic spectra. Constraints on the presence of high-energy electrons from observations are reviewed, including positive detection of non-Maxwellian distributions in the solar corona, transition region, flares, and wind. Occurrence of non-equilibrium ionization is reviewed as well, especially in connection to hydrodynamic and generalized collisional-radiative modeling. Predicted spectroscopic signatures of non-equilibrium ionization depending on the assumed plasma conditions are summarized. Finally, we discuss the future remote-sensing instrumentation that can be used for the detection of these non-equilibrium phenomena in various spectral ranges.     

Resource depletion,peak minerals and the implications for sustainable resource management

Today's global society is economically, socially and culturally dependent on minerals and metals. While metals are recyclable, terrestrial mineral deposits are by definition ‘non-renewable’ over human timescales and their stocks are thus finite. This raises the spectre of ‘peak minerals’ – the time at which production from terrestrial ores can no longer rise to meet demand and where a maximum (peak) production occurs. Peak minerals prompts a focus on the way minerals can be sustainably used in the future to ensure the services they provide to global society can be maintained.As peak minerals approaches (and is passed in some cases), understanding and monitoring the dynamics of primary mineral production, recycling and dematerialisation, in the context of national and global discussions about mineral resources demand and the money earned from their sale, will become essential for informing and establishing mechanisms for sustainable mineral governance and use efficiency into the future. Taking a cross-scale approach, this paper explores the economic and productivity impacts of peak minerals, and how changes in the mineral production profile are influenced not only by technological and scarcity factors, but also by environmental and social constraints. Specifically we examine the impacts of peak minerals in Australia, a major global minerals supplier, and the consequences for the Asia-Pacific region, a major destination for Australia's minerals.This research has profound implications for local and regional/global sustainability of mineral and metal use. The focus on services is useful for encouraging discussion of transitions in how such services can be provided in a future more sustainable economy, when mineral availability is constrained. The research also begins to address the question of how we approach the development of strategies to maximise returns from mineral wealth over generations.     

Element zoning trends in olivine phenocrysts from a supposed primary high-magnesian andesite: an electron- and ion-microprobe study

Electron and ion-probe microanalysis have been used to obtain zoning profiles for major and trace elements in olivine phenocrysts from a high-magnesian andesite from Shodo-Shima island, southwest Japan. This rock was previously thought to represent undifferentiated, primary magma. Some crystals have unzoned cores, while others show cores which are reversely zoned with respect to Mg/ (Mg+Fe), Ni, Mn and Cr. In addition, some Ni profiles show a normally zoned hump at the most central portions of the reversely zoned crystals. All crystals show normally zoned rims. The Li concentrations are constant throughout the cores of all crystals studied, but rise sharply, by a factor of up to at least six, in the rims. The Ca and Co concentrations are essentially constant throughout all the crystals. Mechanisms for producing the observed zoning profiles are discussed, and it is concluded that the reverse zoning was produced by the introduction of crystals into a less differentiated magma than that in which they grew. The reversely zoned crystals could therefore represent xenocrysts which were introduced into an undifferentiated magma, or phenocrysts introduced into a more primitive magma by a magma mixing process. The Ni profiles are used to estimate the residence time of these crystals in the more primitive magma. The following trace element partition co-efficients have been estimated for the olivine-groundmass system in this rock: D ^Ni=16; D ^Mn=1.1; D ^Co=4.2; D ^Ca =0.02; D ^Ti=0.005; D ^V=0.05; D ^Sc=0.2; D ^Na=0.0002. Studies of trace element zoning will become increasingly important as the new generation of trace element microprobes become available but a larger database of experimentally determined values for trace element partition coefficients and diffusion coefficients in crystals and magmas, and a better understanding of other disequilibrium processes are required to fully exploit the new data.