High‐resolution geochemical record of fluid–rock interaction in a mid‐crustal shear zone: a comparative study of major element and oxygen isotope transport in garnet

Garnet grains from an intensely metasomatized mid‐crustal shear zone in the Reynolds Range, central Australia, exhibit a diverse assortment of textural and compositional characteristics that provide important insights into the geochemical effects of fluid–rock interaction. Electron microprobe X‐ray maps and major element profiles, in situ secondary ion mass spectrometry oxygen isotope analyses, and U–Pb and Sm–Nd geochronology are used to reconstruct their thermal, temporal and fluid evolution. These techniques reveal a detailed sequence of garnet growth, re‐equilibration and dissolution during intracontinental reworking associated with the Ordovician–Carboniferous (450–300 Ma) Alice Springs Orogeny. A euhedral garnet porphyroblast displays bell‐shaped major element profiles diagnostic of prograde growth zoning during shear zone burial. Coexisting granulitic garnet porphyroclasts inherited from precursor wall rocks show extensive cation re‐equilibration assisted by fracturing and fragmentation. Oxygen isotope variations in the former are inversely correlated with the molar proportion of grossular, suggesting that isotopic fractionation is linked to Ca substitution. The latter generally show close correspondence to the isotopic composition of their precursor, indicating slow intergranular diffusion of O relative to Fe²⁺, Mg and Mn. Peak metamorphism associated with shearing (～550 °C; 5.0–6.5 kbar) occurred at c. 360 Ma, followed by rapid exhumation and cooling. Progressive Mn enrichment in rim domains indicates that the retrograde evolution caused partial garnet dissolution. Accompanying intra‐mineral porosity production then stimulated limited oxygen isotope exchange between relict granulitic garnet grains and adjacent metasomatic biotite, resulting in increased garnet δ¹⁸O values over length scales <200 μm. Spatially restricted oxygen interdiffusion was thus facilitated by increased fluid access to reaction interfaces. The concentration of Ca in channelled fracture networks suggests that its mobility was enhanced by a similar mechanism. In contrast, the intergranular diffusion of Fe²⁺, Mg and Mn was rock‐wide under the same P–T regime, as demonstrated by a lack of local spatial variations in the re‐equilibration of these components. The extraction of detailed reaction histories from garnet must therefore take into account the variable length‐ and time‐scales of elemental and isotopic exchange, particularly where the involvement of a fluid phase enhances the possibility of measureable resetting profiles being generated for slowly diffusing components such as Ca and O, even at low ambient temperatures and relatively fast cooling rates.     

Total waterborne carbon export and DOC composition from ten nested subarctic peatland catchments—importance of peatland cover,groundwater influence,and inter‐annual variability of precipitation patterns

Waterborne carbon (C) export from terrestrial ecosystems is a potentially important flux for the net catchment C balance and links the biogeochemical C cycling of terrestrial ecosystems to their downstream aquatic ecosystems. We have monitored hydrology and stream chemistry over 3 years in ten nested catchments (0.6–15.1 km²) with variable peatland cover (0%–22%) and groundwater influence in subarctic Sweden. Total waterborne C export, including dissolved and particulate organic carbon (DOC and POC) and dissolved inorganic carbon (DIC), ranged between 2.8 and 7.3 g m^–2 year^–1, representing ~10%–30% of catchment net ecosystem exchange of CO₂. Several characteristics of catchment waterborne C export were affected by interacting effects of peatland cover and groundwater influence, including magnitude and timing, partitioning into DOC, POC, and DIC and chemical composition of the exported DOC. Waterborne C export was greater during the wetter years, equivalent to an average change in export of ~2 g m^–2 year^–1 per 100 mm of precipitation. Wetter years led to a greater relative increase in DIC export than DOC export due to an inferred relative shift in dominance from shallow organic flow pathways to groundwater sources. Indices of DOC composition (SUVA₂₅₄ and a₂₅₀/a₃₆₅) indicated that DOC aromaticity and average molecular weight increased with catchment peatland cover and decreased with increased groundwater influence. Our results provide examples on how waterborne C export and DOC composition might be affected by climate change. Copyright © 2012 John Wiley & Sons, Ltd.     

Controls on the morphology of braided rivers and braid bars: An empirical characterization of numerical models

Braided rivers exhibit highly variable morphologies, morphodynamic behaviours and resulting depositional records. To evaluate relationships between characteristics of braided-river channel belts and river depth, water discharge and streambed gradient, 39 numerical modelling experiments were conducted with the software Delft3D to simulate braided-river evolution under a broad range of boundary conditions. Data from model outputs were integrated with observations from 63 natural braided rivers differing with respect to river depth and streambed gradient. The modelled rivers each underwent similar evolutions, yet each culminated in markedly different final river morphologies, dependent on discharge and riverbed gradient. The rivers underwent evolutionary stages of: (i) formation of transverse unit bars with limited relief from an initially featureless bed; (ii) channel development around bars and in some cases dissecting transverse unit bars; (iii) formation of relatively simpler compound bars; and (iv) amalgamation of these simpler compound bars into more complex compound bars. Quantitative relationships relating to braided-river channel-belt morphology and organization are established, and the following results are noted: (i) bar elongation (length-to-width ratio) is correlated positively with riverbed gradient; (ii) bar height and area are correlated positively with discharge, and negatively with riverbed gradient; (iii) the river depth is the main predictor of mean braid-bar area; and (iv) the degree of braiding is primarily associated with river width-to-depth ratio and riverbed gradient. Results arising from this research improve our understanding of controls on the morphology and architectures of braided fluvial channel belts; they provide a novel empirical characterization that can be applied for predicting channel depth, bar morphology, streambed gradient, and degree of braiding of modern fluvial systems and of the formative rivers of ancient preserved successions.     

Post-Marquette discharge from Glacial Lake Agassiz into the Superior basin

Glacial Lake Agassiz, the largest of the North American glacial lakes, discharged through several different outlets during its history, although the timing and location of discharge remain controversial. However, one discharge event is well established based on extensive onshore observations: drainage through the Nipigon Lake area into the Superior basin about 10,700 years ago, following retreat of ice of the Marquette advance from the basin. High-resolution, single-channel seismic-reflection data collected with a small airgun were acquired to test the hypothesis that the Post-Marquette drainage event left diagnostic stratigraphic and geomorphic signatures beneath Lake Superior. The unique bathymetry of northwestern Lake Superior, where water depth plunges off Nipigon and Black Bays, makes this location ideal for the characterization of the post-Marquette depositional and erosional features. According to our hypothesis, the initial, sudden discharge of high-velocity water would have eroded channels through the bays. The steep and sudden drop-off into the Superior basin would have caused the flow to slow and drop much of the sediment it was carrying. Our results confirm the existence of both erosional features and depositional sediment packages related to Lake Agassiz discharge at this time. The erosional features include deeply incised bedrock channels in the bays. The depositional features comprise subaqueous fans that are thickest in the deep water areas adjacent to the outlets and thin lakeward and laterally away from the channels. The seismic character of the basal units of the fans, proximal to the channels, is chaotic and only very weakly stratified, suggesting that these deposits represent coarse sediment laid down during the initial, high-energy stages of the flood. These sediments are overlain by a stratified package which is interpreted as the fine grained sediment associated with the later, low-energy stages of the flood. The combination of channels and subaqueous fans is inferred to be diagnostic of high-energy Lake Agassiz discharge into the Superior basin, and they serve as analogs for hypothesized discharge at other times.     

Patterns of development in tourist accommodation enterprises on farms in England and Wales

The spatial distribution of UK farm-based tourist accommodation is not known in detail, although this type of facility has been an important element in the growth of rural tourism and the most common option for farm diversification. A database of farms in England and Wales offering tourist accommodation has been prepared and the individual entries georeferenced to enable their locations to be determined with respect to selected Scenic Areas (Areas of Outstanding Natural Beauty, Heritage Coasts and National Parks). Exploratory analysis of this database indicates a possible ‘neighbourhood effect’ in which the provision of farm-based accommodation within buffer zones immediately surrounding these designated areas has a higher level of penetration in the farming community than in more distant areas. Further research is outlined to examine the interaction between actors in farming and planning communities using the geographical framework presented here.     

ENGLISH AS INTERNATIONAL LANGUAGE IN GEOGRAPHY: DEVELOPMENT AND LIMITATIONS

ABSTRACT. The rise and spread of English as a language of international communication is discussed through an analysis of two bodies of data: languages used in twenty‐nine International Geographical Congresses (1871–2000); and utilization of supplementary abstracts or text in international languages in geographical periodicals and serials, from initial use of English in 1882 to widespread use of it in 2002. Five stages in the use of English are recognized: 1) no use of English; 2) provision of abstracts in English; 3) occasional inclusion of articles in English; 4) publication of special issues in English, particularly for international meetings; and 5) a shift to English as the basic language of the text. English provides a window into the geographical literature; but it is only a window, not the full panorama of the richly diverse geographical literature in the six main languages that have been used in International Geographical Congresses and in the fifty‐five languages that have been used in geographical serials.     

Reef Fabrics, biotic crusts and syndepositional cements of the Latemar reef margin (Middle Triassic), northern Italy

The Latemar reef buildup of the central Dolomites (northern Italy) provides a rare opportunity to examine an in-place Middle Triassic (Upper Anisian to Lower Ladinian) platform margin that is not strongly deformed or dolomitized. The margin lies between the flat lying platform interior and steeply dipping foreslope clinoforms. Across this transition, the depositional profile relates directly to a consistent lateral facies pattern: (1) restricted-biota grainstone of the platform interior, (2) ‘Tubiphytes’-rich boundstone and (3) diverse-biota grainstone that grades into (4) foreslope breccia beds. The boundstone and diverse-biota grainstone facies comprise the platform margin. The boundstone facies consists of a framework of small (< 10 cm) skeletal remains (< 10% by volume) with associated biotic crusts, internal sediments and syndepositional cements. Crusts and cements constitute most of the rock volume and created the boundstone fabric. Biotic crusts exhibit gravity-defying geometries and range from a light grey, ‘structure grumeleuse’ rind to dark grey, micritic laminae. Both cements and biotic crusts occur as redeposited talus in the foreslope talus deposits, indicating a syndepositional origin. The diverse-biota grainstone facies primarily consists of skeletal-peloidal grainstone with a diverse open marine biotic assemblage, in contrast to the restricted biota grainstones of the platform interior that have a low diversity, restricted marine biota. Metre scale hexacoral boundstone and centimetre-scale sponge boundstone and microbial boundstone occur as isolated patches (tens to hundreds of metres apart) within the diverse-biota grainstone facies. The depositional profile, facies zonation and biotic constituents all indicate that the Latemar buildup had a shallow water reef margin, in contrast to previous interpretations that these were upper slope reefs. The syndepositional biotic crusts and inorganic cementation played key roles in stabilizing the boundstone fabric to form a wave-resistant reef fabric.     

A simple method to reduce discharge of sewage microorganisms from an Antarctic research station

The majority of coastal Antarctic stations release untreated sewage into the near-shore marine environment. This study examined bacterial reproduction within the temporary sewage-holding tanks of Rothera Research Station (Adelaide Island, Antarctic Peninsula) and monitored sewage pollution in the local marine environment. By continuously flushing the sewage-holding tanks with cold seawater we inhibited microbial reproduction and decreased the numbers of bacteria subsequently released into the sea by >90%. The widespread use of this simple method could significantly reduce the numbers of faecal coliform and other non-native microorganisms introduced into the Antarctic marine environment.