Trace and minor elements in sphalerite from metamorphosed sulphide deposits

Sphalerite is a common sulphide and is the dominant ore mineral in Zn-Pb sulphide deposits. Precise determination of minor and trace element concentrations in sulphides, including sphalerite, by Laser-Ablation Inductively-Coupled-Plasma Mass-Spectrometry (LA-ICP-MS) is a potentially valuable petrogenetic tool. In this study, LA-ICP-MS is used to analyse 19 sphalerite samples from metamorphosed, sphalerite-bearing volcanic-associated and sedimentary exhalative massive sulphide deposits in Norway and Australia. The distributions of Mn, Fe, Co, Cu, Ga, Se, Ag, Cd, In, Sn, Sb, Hg, Tl, Pb and Bi are addressed with emphasis on how concentrations of these elements vary with metamorphic grade of the deposit and the extent of sulphide recrystallization. Results show that the concentrations of a group of trace elements which are believed to be present in sphalerite as micro- to nano-scale inclusions (Pb, Bi, and to some degree Cu and Ag) diminish with increasing metamorphic grade. This is interpreted as due to release of these elements during sphalerite recrystallization and subsequent remobilization to form discrete minerals elsewhere. The concentrations of lattice-bound elements (Mn, Fe, Cd, In and Hg) show no correlation with metamorphic grade. Primary metal sources, physico-chemical conditions during initial deposition, and element partitioning between sphalerite and co-existing sulphides are dominant in defining the concentrations of these elements and they appear to be readily re-incorporated into recrystallized sphalerite, offering potential insights into ore genesis. Given that sphalerite accommodates a variety of trace elements that can be precisely determined by contemporary microanalytical techniques, the mineral has considerable potential as a geothermometer, providing that element partitioning between sphalerite and coexisting minerals (galena, chalcopyrite etc.) can be quantified in samples for which the crystallization temperature can be independently constrained.     

Parametrization of peatland hydraulic properties for the Canadian land surface scheme

Abstract

A hydraulic parametrization is developed for peatland environments in the Canadian Land Surface Scheme (CLASS). Three ‐wetland soil classes account for the typical variation in the hydraulic characteristics of the uppermost 0.5 m of organic soils. Review of the literature reveals that saturated hydraulic conductivity varies from a median of 1.0 × 10^?7m/s in deeply humified sapric peat to 2.8 × 10^?4 m/s in relatively undecomposed fibric peat. Average pore volume fraction ranges from 0.83 to 0.93. Parameters have been designed for the soil moisture characteristic curves for fibric, hemic and sapric peat using the Campbell (1974) equation employed in CLASS, and the van Genuchten (1980) formulation. There is little difference in modelled soil moisture between the two formulations within the range of conditions normally found in peatlands. Validation of modelled water table depth and peat temperature is performed for a fen in northern Québec and a bog in north‐central Minnesota. The new parametrization results in a more realistic simulation of these variables in peatlands than the previous version of CLASS, in which unrealistic mineral soil “equivalents “ were used for wetland soil climate modelling.     

http://www.sciencedirect.com/science/article/pii/S1674987111001113

The Rheic Ocean was one of the most important oceans of the Paleozoic Era.It lay between Laurentia and Gondwana from the Early Ordovician and closed to produce the vast Ouachita-Alleghanian -Variscan orogen during the assembly of Pangea.Rifting began in the Cambrian as a continuation of Neoproterozoic orogenic activity and the ocean opened in the Early Ordovician with the separation of several Neoproterozoic arc terranes from the continental margin of northern Gondwana along the line of a former suture.The rapid rate of ocean opening suggests it was driven by slab pull in the outboard lapetus Ocean.The ocean reached its greatest width with the closure of lapetus and the accretion of the periGondwanan arc terranes to Laurentia in the Silurian.Ocean closure began in the Devonian and continued through the Mississippian as Gondwana sutured to Laurussia to form Pangea.The ocean consequently plays a dominant role in the Appalachian-Ouachita orogeny of North America,in the basement geology of southern Europe,and in the Paleozoic sedimentary,structural and tectonothermal record from Middle America to the Middle East.Its closure brought the Paleozoic Era to an end.