Evidence for Holocene climate variability from the sediments of a Scottish remote mountain lake

High resolution sampling of sediment cores covering approximately the last 4000 yr from Lochan Uaine, a small corrie loch in the Scottish Cairngorm Mountains, show quasi‐periodic cycles in organic matter (measured as percentage loss on ignition). Analysis of these cycles show correspondences between loss on ignition, δ¹³C values and chironomid head capsule abundance. We interpret the changes as reflecting changes in lake productivity and hypothesise that they are driven by climate variability. However, it is not yet clear whether the periods of relatively high organic matter production and preservation are associated with colder or with warmer conditions. Nevertheless the results indicate the value of using sediments from remote, undisturbed mountain lakes as recorders of Holocene climate variability. Copyright © 2001 John Wiley & Sons, Ltd.     

An integrated approach to determine three‐dimensional accretion geometries of tidal point bars: Examples from the Venice Lagoon (Italy)

Low rates of lateral migration (centimetres to decimetres per year) combined with relatively high rates of vertical accretion (millimetres to centimetres per year) recorded in microtidal channels of the Venice Lagoon (Italy) give rise to point‐bar geometries and internal facies arrangements that differ substantially from widely accepted models of point‐bar sedimentary architecture. In this study, field data from the Venice Lagoon are combined with a three‐dimensional forward stratigraphic model, the ‘Point‐Bar Sedimentary Architecture Numerical Deduction’ (PB‐SAND), to predict the stratal geometries of point bars formed in aggradational settings. The PB‐SAND uses a combined geometric and stochastic modelling approach that can be constrained by field evidence. The model applied determines the geometry of four point bars generated by 9 to 11 m wide channels cutting through salt marshes. An iterative best‐fit modelling approach has been used to obtain multiple simulations for each case study, each of which fits the observations derived from the analysis of time‐series historical aerial photographs and 44 sedimentary cores. Results demonstrate how the geometry of the bars is determined by the development of two key stratal surfaces: the point‐bar brink and channel‐thalweg surfaces. These surfaces are defined by the progressive translation and vertical shift of the point‐bar brink (i.e. break of slope between bar top and bar slope) and the channel thalweg (i.e. deepest part of the channel) during bar evolution. The approach is used to: (i) reconstruct three‐dimensional point‐bar geometries; (ii) propose alternative reconstructions; (iii) provide insight to drive the acquisition of additional data to better constrain the proposed models; and (iv) provide insight into the mechanism of bar growth for slowly migrating channels in settings subject to relatively high rates of aggradation. This study highlights how interaction between styles of planform transformation and latero‐vertical shifts of meandering channels can determine the geometry of related sedimentary bodies.     

An Unusual, Three-Dimensionally Preserved, Large Hadrosauriform Pes Track from “Mid”-Cretaceous Jiaguan Formation of Chongqing, China

Three-dimensional tracks provide unique insights into the locomotor mechanics of their track makers. An isolated, large hadrosauriform print attributable to Caririchnium lotus from the “mid”-Cretaceous Lotus track site (Jiaguan Formation) in China permits reconstruction of the footfall, weight-bearing, and kick-off phases of the step cycle. Large-scale modifications of the pes during the step cycle indicate C. lotus trackmakers were capable of locomotory modifications in response to substrate consistency beyond the “expected” shift between bipedal and quadrupedal postures. An unusual curvature to the trace of one of the outer digits indicates substantial transverse mobility. The remaining digits demonstrate lesser degrees of transverse movement accompanied by extension of the digits during footfall. The absence of overprinted scale-scratch marks and toe drags are consistent with a vertical kick-off of the pes and concomitant flexion of the digits. This track suggests that pedal mobility in C. lotus track makers was greater than previously suspected and has implications for reconstructions of hadrosauriform locomotion.     

白垩纪四足动物足印的生物地层学、生物年代学与遗迹相

从全球范围来看,白垩纪四足动物的足印多数是非鸟恐龙与鸟类留下的痕迹;少量足印来自翼龙、鳄鱼、龟、哺乳动物和其他四足动物。白垩纪的足迹化石以东亚(尤其是中国和朝鲜)和北美西部的最为人所知。南美(主要是阿根廷和巴西)也有一定数量广泛分布的足迹化石,欧洲、非洲与澳大利亚的白垩纪足迹组合则鲜为人知。以白垩纪四足动物的足印记录为基础,我们对两个全球足印生物年代重新进行了检查。早白垩世生物年代以蜥脚类与鸟脚类的足迹为特征。晚白垩世生物年代中的蜥脚类足迹较少,但是鸭嘴龙、暴龙和角龙的足迹增多了。另外,白垩纪足印化石的记录中记载了许多重要的生物地层学信息,如北美白垩纪中期蜥脚类恐龙的消失,以及白垩纪末恐龙的绝灭。越来越多来自东亚的白垩纪足印记录使我们对更精细的地方性白垩纪足印生物年代学有了初步印象。因此,以地方性四足恐龙(包括鸟类)遗迹属的地层分布为基础,可以识别出三个或四个足印生物年代。种类丰富并具有地方性特色的东亚的白垩纪鸟类动物的遗迹群,可能指示白垩纪时东亚存在着一个独特而繁盛的鸟类动物群。以足印化石为基础的这一假说有待进一步的验证。     

Climatic versus halokinetic control on sedimentation in a dryland fluvial succession

Fluvial systems and their preserved stratigraphic expression as the fill of evolving basins are controlled by multiple factors, which can vary both spatially and temporally, including prevailing climate, sediment provenance, localized changes in the rates of creation and infill of accommodation in response to subsidence, and diversion by surface topographic features. In basins that develop in response to halokinesis, mobilized salt tends to be displaced by sediment loading to create a series of rapidly subsiding mini‐basins, each separated by growing salt walls. The style and pattern of fluvial sedimentation governs the rate at which accommodation becomes filled, whereas the rate of growth of basin‐bounding salt walls governs whether an emergent surface topography will develop that has the potential to divert and modify fluvial drainage pathways and thereby dictate the resultant fluvial stratigraphic architecture. Discerning the relative roles played by halokinesis and other factors, such as climate‐driven variations in the rate and style of sediment supply, is far from straightforward. Diverse stratigraphic architectures present in temporally equivalent, neighbouring salt‐walled mini‐basins demonstrate the effectiveness of topographically elevated salt walls as agents that partition and guide fluvial pathways, and thereby control the loci of accumulation of fluvial successions in evolving mini‐basins: drainage pathways can be focused into a single mini‐basin to preserve a sand‐prone fill style, whilst leaving adjoining basins relatively sand‐starved. By contrast, over the evolutionary history of a suite of salt‐walled mini‐basins, region‐wide changes in fluvial style can be shown to have been driven by changes in palaeoclimate and sediment‐delivery style. The Triassic Moenkopi Formation of the south‐western USA represents the preserved expression of a dryland fluvial system that accumulated across a broad, low‐relief alluvial plain, in a regressive continental to paralic setting. Within south‐eastern Utah, the Moenkopi Formation accumulated in a series of actively subsiding salt‐walled mini‐basins, ongoing evolution of which exerted a significant control on the style of drainage and resultant pattern of stratigraphic accumulation. Drainage pathways developed axial (parallel) to salt walls, resulting in compartmentalized accumulation of strata whereby neighbouring mini‐basins record significant variations in sedimentary style at the same stratigraphic level. Despite the complexities created by halokinetic controls, the signature of climate‐driven sediment delivery can be deciphered from the preserved succession by comparison with the stratigraphic expression of part of the system that accumulated beyond the influence of halokinesis, and this approach can be used to demonstrate regional variations in climate‐controlled styles of sediment delivery.     

The significance of Cenozoic magmatism from the western margin of the eastern syntaxis, southeast Tibet

The major and trace-element geochemistry, Sr–Nd bulk-rock isotopes, U–Pb zircon chronology and Lu–Hf isotopic compositions are described for three granitic bodies which intrude the Nyingchi gneisses (Lhasa terrane) along the western margin of the eastern Himalayan syntaxis. The Bayi two-mica granite and Lunan granite–granodiorite were intruded at 22 ± 1 and 25.4 ± 0.3 Ma, respectively, whereas the Confluence biotite granite was emplaced at 49.1 ± 0.4 Ma. All share strong depletions in Y and HREE requiring a garnet-bearing source both during and following the Eocene collision of the Indian plate with the Lhasa terrane. The isotope geochemistry of these intrusives (ε _Nd(t) = −3 to −5, ⁸⁷Sr/⁸⁶Sr_(t) = 0.706–0.707) indicates a crustal source within the Lhasa terrane. Sr–Nd systematics of the garnet-bearing Nyingchi gneisses together with the U–Pb and Lu–Hf isotopic ratios of detrital zircons recovered from this unit identifies it as a potential melt source. The combined element and isotope geochemistry of the plutons indicate a mixed source; the gneisses provide the older component whereas the Gangdese batholith provides a younger, siliceous component. The involvement of garnet-bearing crustal material in melt sources from the Cretaceous (80 Ma) to the Miocene (20 Ma) is consistent with the presence of a thicker continental crust in the eastern Lhasa terrane, as is the presence of magmatic epidote in several plutons which indicates a regional deepening level of exposure eastwards. Post-collision crustal melting is synchronous with proposed slab break-off during the early Miocene, suggesting advective heating by rising asthenospheric melts.     

Post-collision, Shoshonitic Volcanism on the Tibetan Plateau: Implications for Convective Thinning of the Lithosphere and the Source of Ocean Island Basalts

Potassic volcanism has been widespread and semi-continuous onthe Tibetan plateau since 13 Ma, post-dating the orogenic thickeningof the India-Asia collision. Volcanism may have commenced slightlyearlier (16–20 Ma) in the southern portion of the plateauand then ceased around 10 Ma. The dominant lavas are pyroxen-and plagioclase-phyric shoshonites with subordinate occurrencesof dacites and rhyolites. Their mineralogy reflects crystallizationfrom high-temperature (1100C) magmas which had elevated oxygenand water fugacities. Geochemically, they are characterizedby relatively low TiO², Al²O³ and Fe²O³, and high Na²O, coupledwith variable abundances of compatible trace elements and veryhigh contents of incompatible trace elements. Normalized incompatibleelement patterns have marked negative Nb, Ta and Ti anomalieswhereas K²O appears to be buffered at 4% over a wide range ofSiO². Isotope data show a relatively broad and enriched rangeof ⁸⁷Sr/⁸⁶ Sr (0.7076–0.7106) at more restricted ENd (–5.2to –8.1). Pb isotopes are characterized by a range of²⁰⁷Pb/²⁰⁴ Pb (15.51–15.72) and ²⁰⁸ Pb/²⁰⁴Pb (38.67–39.30) at very uniform ²⁰⁶Pb/²⁰⁴ Pb (18.39–18.83), leadingto vertical arrays. Volcanics from the southern parts of theplateau have more primitive isotopic compositions: ⁸⁷Sr/⁸⁶ Sr0.7048–0.7080, _Nd 1.4 to –3.3, ²⁰⁶Pb/²⁰⁴ Pb 18.48–18.67,²⁰⁷Pb/²⁰⁴ Pb 15.59–15.68 and ²⁰⁸Pb/²⁰⁴ Pb 38. 73–38.98. In general, the geochemical and isotopic data most closely approximatepartial melting arrays, although fractionation processes haveclearly operated. The isotopic ratios and the enrichment ofincompatible elements and LREE/HREE cannot be derived from adepleted mantle source via a single-stage melting process. Instead,a metasomatized, garnet peridotite source containing 6% phlogopiteis required and this is inferred to lie within the lithosphericmantle. The enrichment in incompatible elements in this sourcemust have been sufficiently ancient to generate the observedisotopic ratios, and Nd depleted mantle model ages suggest thiswas Proterozoic in age (1.2 Ga), whereas Pb model ages recordan Archaean event, suggesting the source had a multi-stage enrichmenthistory. The negative Ta, Nb and Ti anomalies and low Rb/Basuggest that metasomatism may have occurred during an ancientsubduction episode. The high ²⁰⁸Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴ Pb and lowNb/U, Ce/Pb of the Tibetan shoshonites are distinct from oceanisland basalts. Thus, if convectively removed lithospheric mantleprovides a source for ocean island basalts, it must differ significantlyfrom the source of the Tibetan shoshonites. A lithospheric mantle source for the volcanism places importantconstraints on geodynamic models for the evolution of the Tibetanplateau and the India-Asia collision. For likely thermal structuresbeneath the plateau, the temperatures required to trigger meltingwithin the lithospheric mantle can only be plausibly obtainedif the lower parts of the lithospheric mantle were removed byconvective thinning. This is consistent with recent models whichinvoke the same process to explain the current elevation andextensional deformation of the plateau. The age data suggestthis occurred at 13 Ma and the duration of volcanism may beexplained by continued conductive heating since that time. Poorlysampled but slightly older volcanics from the southern portionsof the plateau may indicate that convective thinning began inthe south and migrated northwards. Rapid uplift of the plateaumay have resulted in increased rates of chemical weathering,which led to global cooling, as indicated by oxygen isotopedata from Atlantic sediments. KEY WORDS: Climate; lithospheric mantle; OIB; Tibet; volcanism ^*Corresponding author.     

Do S-type granites commonly sample infracrustal sources? New results from an integrated O, U–Pb and Hf isotope study of zircon

In contrast to I-type granites, which commonly comprise infracrustal and supracrustal sources, S-type granites typically incorporate predominantly supracrustal sources. The initial aim of this study was to identify the sources of three Scottish Caledonian (~460 Ma) S-type granites (Kemnay, Cove and Nigg Bay) by conducting oxygen, U–Pb and Hf isotope analyses in zircon in order to characterise one potential end-member magma involved in the genesis of the voluminous late Caledonian (~430–400 Ma) I-type granites. Field, whole-rock geochemical and isotopic data are consistent with the generation of the S-type granites by melting their Dalradian Supergroup country rocks. While Hf isotope compositions of magmatic zircon, U–Pb data of inherited zircons, and high mean zircon δ¹⁸O values of 9.0 ± 2.7‰ (2SD) and 9.8 ± 2.0‰ for the Kemnay and Cove granites support this model, the Nigg Bay Granite contains zircons with much lower δ¹⁸O values (6.8 ± 2.1‰), similar to those found in Scottish I-type granites. This suggests that the Nigg Bay Granite contains low-δ¹⁸O material representing either altered supracrustal material, or more likely, an infracrustal source component with mantle-like δ¹⁸O. Mixing trends in plots of δ¹⁸O vs. εHf for S-type granite zircons indicate involvement of at least two sources in all three granites. This pilot study of Scottish Caledonian S-type granites demonstrates that, while field and whole-rock geochemical data are consistent with local melting of only supracrustal sources, the oxygen isotopic record stored in zircon reveals a much more complex petrogenetic evolution involving two or more magma sources.     

‘Invisible gold’ in bismuth chalcogenides

Gold concentrations have been determined by LA-ICPMS in bismuth chalcogenides (tellurides and sulfosalts, minerals with modular structures; chalcogen X = Te, Se, and S) from 27 occurrences. Deposit types include epithermal, skarn, intrusion-related and orogenic gold. The samples comprised minerals of the tetradymite group, aleksite series, bismuth sulfosalts (cosalite, lillianite, hodrushite, bismuthinite, and aikinite), and accompanying altaite. Gold concentrations in phases of the tetradymite group range from <0.1 to 2527 ppm. Phases in which Bi > X tend to contain lower gold concentrations than Bi₂X₃ minerals (tellurobismuthite and tetradymite). Cosalite and lillianite contain Au concentrations ranging up to 574 and 3115 ppm, respectively. Bismuthinite derivatives have lower Au concentrations: <2 ppm in bismuthinite and up to 542 ppm in aikinite. In our samples, Au concentrations in altaite range from <0.2 to 1662 ppm.Smoother parts of the LA-ICPMS profiles suggest lattice-bound gold, whereas irregularities on the profiles are best explained by the presence of gold particles (?1 μm in diameter). Plotting Au vs. Ag for the entire dataset gives a wedge-shaped distribution, suggesting that Ag underpins Au uptake in both bismuth tellurides and sulfosalts. In the tellurides, correlation trends suggest statistical substitution of Ag(Au), together with Pb, into the octahedral site in the layers. In sulfosalts, Au follows coupled substitutions in which M¹⁺ (Ag, Cu) enters the structure. In tellurides, the presence of van der Waals gaps at chalcogen-chalcogen contacts provides for p-type semi-conductive properties critical for gold scavenging from fluids. Such weak bonds may also act as sites for nucleation of Au (nano)particles. In sulfosalts, contacts between different species that replace one another are also highly predictable to act as traps for (nano)particulate gold.Invisible gold in Bi-chalcogenides is useful to (i) identify trends of orefield zonation, (ii) discriminate between ‘melt’ and ‘fluid-driven’ scavenging, and (iii) interpret replacement and remobilisation processes. Bismuth chalcogenides have the potential to be significant Au carriers in sulfide-poor Au systems, e.g., intrusion-related gold, with impact on the overall Au budget if mean Au concentrations are high enough and the minerals are sufficiently abundant.