Coherent integration time limit of a mobile receiver for indoor GNSS applications

There is an emerging requirement for processing global navigation satellite system (GNSS) signals indoor where the signal is very weak and subjected to spatial fading. Typically, longer coherent integration intervals provide the additional processing gain required for the detection and processing of such weak signals. However, the arbitrary physical motion of the handset imputed by the user limits the effectiveness of longer coherent integration intervals due to the spatial decorrelation of the multipath-faded GNSS signal. In this paper, limits of coherent integration due to spatial decorrelation are derived and corroborated with experimental verification. A general result is that the processing gain resulting from direct coherent integration saturates after the antenna has moved through a certain distance, which for typical indoor propagation, is about half a carrier wavelength. However, a refined Doppler search coupled with a prolonged coherent integration interval extends this limit, which is effectively a manifestation of selective diversity.     

Qualitative satellite image analysis: Mapping spatial distribution of farming types in Ethiopia

Satellite images have enormous potential for qualitative land use analysis. This paper presents empirical results that demonstrate how normally invisible dimensions produced by land use can be identified by enriching satellite data with qualitative information from field studies.Land use can be defined as the intentional use of a specific piece of land resulting in patterns of ecological responses that are visible in the land cover and landscape. Responses to land use often result in a heterogeneous combination of reflectance in satellite images. Statistical methods used in the classification of satellite imagery are limited in their capacity to handle categories consisting of heterogeneous combinations of spectral values. To overcome this limitation, a contextual post-classification method has been used to map land cover configurations as related to different agricultural practices in the district of Sodo, Ethiopia.The results show that it is possible to map socio-spatial distribution of different agricultural and socioeconomic practices on a regional level by combining field observations and spatial contextual information. The empirical findings show local agricultural activity variations in cash crop production and subsistence agriculture in the Sodo district of Ethiopia.     

On the homeostasis and bistability on a Gaian planet

Geochemical disequilibrium of Earth's atmosphere is a sign of life. The fact that Earth's atmosphere is just right for life led Lovelock to propose the Gaia hypothesis: life itself regulates the environment on planetary scale in order to maintain habitability. This hypothesis is supported by the so-called Daisyworld parable, which illustrates a possible mechanism for such a self regulation. Here we revisit Daisyworld and challenge some of its conclusions from a closer examination of the model. We find that even within this simple, conceptual model of a Gaian planet there are regimes where climate is less homeostatic than on a dead planet. Furthermore, in other regimes, bistability between two climate states is found to exist due to the presence of life. This indicates that even if the Gaian stability might describe life in some planetary conditions, it need not be generic to all inhabited planets.     

Equilibrium H/H fractionations in organic molecules: I. Experimental calibration of ab initio calculations

Carbon-bound hydrogen in sedimentary organic matter can undergo exchange over geologic timescales, altering its isotopic composition. Studies investigating the natural abundance distribution of ¹H and ²H in such molecules must account for this exchange, which in turn requires quantitative knowledge regarding the endpoint of exchange, i.e., the equilibrium isotopic fractionation factor (α_eq). To date, relevant data have been lacking for molecules larger than methane. Here we describe an experimental method to measure α_eq for C-bound H positions adjacent to carbonyl group (H_α) in ketones. H at these positions equilibrates on a timescale of days as a result of keto-enol tautomerism, allowing equilibrium ²H/¹H distributions to be indirectly measured. Molecular vibrations for the same ketone molecules are then computed using Density Functional Theory at the B3LYP/6-311G** level and used to calculate α_eq values for H_α. Comparison of experimental and computational results for six different straight and branched ketones yields a temperature-dependent linear calibration curve with slope = 1.081−0.00376T and intercept = 8.404−0.387T, where T is temperature in degrees Celsius. Since the dominant systematic error in the calculation (omission of anharmonicity) is of the same size for ketones and C-bound H in most other linear compounds, we propose that this calibration can be applied to analogous calculations for a wide variety of organic molecules with linear carbon skeletons for temperatures below 100 °C. In a companion paper (Wang et al., 2009) we use this new calibration dataset to calculate the temperature-dependent equilibrium isotopic fractionation factors for a range of linear hydrocarbons, alcohols, ethers, ketones, esters and acids.     

Thallium isotopes as a potential tracer for the origin of cratonic eclogites

Cratonic eclogites are inferred to originate either from subducted ocean crust or mantle melts accreted onto the roots of continents. These models have different implications for the growth of continents, but it is currently difficult to determine the origin of individual eclogite suites.Upper ocean crust altered at low temperatures and marine sediments both display high thallium (Tl) concentrations and strongly fractionated Tl isotope signatures relative to the ambient upper mantle. In this study we carry out the first examination of the suitability of Tl isotopes as a tracer for an ocean-crust origin of cratonic eclogites. We have analysed the Tl isotope composition of clinopyroxene and garnet in six eclogites from the Kaalvallei and Bellsbank kimberlite pipes in South Africa. Minerals were pre-cleaned with an HCl leaching technique and the leachates display variably light Tl isotope ratios. These most likely reflect low-temperature hydrothermal alteration occurring after eruption of the kimberlite that carried the eclogites to the surface.The leached mineral pairs all display identical Tl isotope ratios, strongly suggesting that the source of the analysed Tl is identical for each mineral pair. It is, however, not possible to exclude the possibility that the analysed Tl originates from kimberlitic material that was not removed by the cleaning procedure.Only one of the six samples exhibits a Tl isotope composition different from ambient mantle. Assuming that the Tl isotope signatures indeed represent the eclogite minerals and not any form of contamination, the Tl isotope composition in this sample is consistent with containing a minor component (<3%) of ocean crust altered at low temperatures.Thallium isotopes may become one of the most sensitive indicators for the presence of low-T altered ocean crust because of the stark contrast in Tl concentration and isotopic composition between the mantle and altered ocean crust. In fact, no other chemical or isotopic tracer could have provided an indication that any of the samples studied here had a subduction origin. However, much work is still required before it becomes clear if Tl isotope measurements are a viable means to establish the origin of cratonic eclogites.     

Subduction Influence on Oxygen Fugacity and Trace and Volatile Elements in Basalts Across the Cascade Volcanic Arc

Fluids or melts derived from a subducting plate are often citedas a mechanism for the oxidation of arc magmas. What remainsunclear is the link between the fluid, oxygen fugacity, andother major and trace components, as well as the spatial distributionof the impact of those fluids. To test the potential effectsof addition of a subduction-derived fluid or melt to the sub-arcmantle, olivine-hosted melt inclusions from primitive basalticlavas sampled from across the central Oregon Cascades (43°–45°N)have been analyzed for major, trace and volatile elements andfO₂. Oxygen fugacity was determined in melt inclusions fromsulfur speciation determined by electron microprobe and fromolivine–chromite oxygen geobarometry. The overall rangein fO₂ based on sulfur speciation measurements is from <–0·25log units to + 1·9 log units (FMQ, where FMQ is fayalite–magnetite–quartzbuffer). Oxygen fugacity is positively correlated with fluid-mobiletrace element and light rare earth element contents in basaltsgenerated by relatively low-degree partial melting. Establishinga further correlation between fO₂ and fluid-mobile trace elementabundances with position along the arc requires the basaltsto be subdivided into shoshonitic, calc-alkaline, low-K tholeiiteand enriched intraplate basalt groups. Melt inclusions fromenriched intraplate and shoshonitic lavas show increasing fO₂and trace element abundances closer to the trench, whereas calc-alkalinemelt inclusions exhibit no significant across-arc variations.Low-K tholeiitic melt inclusions record an increase in incompatibletrace elements closer to the trench; however, there is no correlatedincrease in fO₂. The correlation observed in enriched intraplateand shoshonitic melt inclusions is interpreted to reflect aprogressively greater proportion of a fluid-rich, oxidized subductioncomponent in magmas generated nearer the subduction zone. Significantly,calc-alkaline melt inclusions with high ratios of large ionlithophile elements to high field strength elements, characteristicof ‘typical’ arc magmas, have oxidation states indistinguishablefrom low-K tholeiite and enriched intraplate basalt melt inclusions.The lack of across-arc geochemical variation in calc-alkalinemelt inclusions may suggest that these basalts are not necessarilythe most appropriate magmas for examining recent addition ofa subduction component to the sub-arc mantle. Flux and batchmelt model results produce a wide range of predicted amountsof melting and subduction component added to the mantle source;however, general trends characterized by increased melting andproportion of the subduction component from enriched intraplate,to low-K tholeiite, to calc-alkaline are robust. The model resultsdo not require enriched intraplate, low-K tholeiite and calc-alkalinemagmas to be produced from the same more fertile mantle source.However, enriched intraplate magmas, in contrast to calc-alkalineand low-K tholeiite magmas, cannot be generated from a depletedmantle source. Flux or batch melting of either the more fertileor depleted mantle sources used to generate the low-K tholeiite,calc-alkaline, and enriched intraplate magmas cannot reproduceshoshonitic compositions, which require a significantly depletedmantle source strongly metasomatized by a subduction component.The potential mantle source for shoshonitic basalts has a predictedfO₂ (after oxidation) from + 0·3 to + 2·4 logunits (FMQ) whereas the mantle source for low-K tholeiite, calc-alkaline,and enriched intraplate magmas may range from –1·1to + 0·7 log units (FMQ). KEY WORDS: basalt; Cascades; melt inclusions; oxidation state; volatiles     

Objectives of fisheries management: case studies from the UK, France, Spain and Denmark

The main objectives of fisheries management are generally similar throughout the world. These are often stated in policy documents such as the Common Fisheries Policy and the Magnuson–Stevens Fishery Conservation and Management Act. However, at the local level often the key objectives of management are more detailed, characterised by both the overriding management structure and the status and type of fishery concerned. In this paper, we consider case study fisheries from the UK, France, Spain and Denmark to compare some of the various types of fisheries and fisheries management systems that exist in the European Union. From this, we define the key objectives for each management system.     

Comparison of abstraction scenarios simulated by SWAT and SWAT-MODFLOW

In hydrological modelling of catchments, wherein streams are groundwater-fed, an accurate representation of groundwater processes and their interaction with surface water is crucial. With this purpose, a coupled model was recently developed linking SWAT (Soil and Water Assessment Tool) with the fully-distributed groundwater model MODFLOW (Modular Groundwater Flow). In this study, SWAT and SWAT-MODFLOW were applied to a Danish groundwater-dominant catchment, simulating groundwater abstraction scenarios and assessing the benefits and drawbacks of SWAT-MODFLOW. Both models demonstrated good performance. However, SWAT-MODFLOW provided more realistic outputs when simulating abstraction: the decrease in streamflow was similar to the volume of water abstracted, while in SWAT the impact was negligible. SWAT also showed impacts on streamflow only when abstractions were taken from the shallow aquifer, not from the deep aquifer. Overall, SWAT-MODFLOW demonstrated wider possibilities for groundwater analysis, providing more insights than SWAT in supporting decision making in relation to environmental assessment.