Continuous monitoring of stream δ18O and δ2H and stormflow hydrograph separation using laser spectrometry in an agricultural catchment

A portable Wavelength Scanned‐Cavity Ring‐Down Spectrometer (Picarro L2120) fitted with a diffusion sampler (DS‐CRDS) was used for the first time to continuously measure δ¹⁸O and δ²H of stream water. The experiment took place during a storm event in a wet tropical agricultural catchment in north‐eastern Australia. At a temporal resolution of one minute, the DS‐CRDS measured 2160 δ¹⁸O and δ²H values continuously over a period of 36 h with a precision of ±0.08 and 0.5‰ for δ¹⁸O and δ²H, respectively. Four main advantages in using high temporal resolution stream δ¹⁸O and δ²H data during a storm event are highlighted from this study. First, they enabled us to separate components of the hydrograph, which was not possible using high temporal resolution electrical conductivity data that represented changes in solute transfers during the storm event rather than physical hydrological processes. The results from the hydrograph separation confirm fast groundwater contribution to the stream, with the first 5 h of increases in stream discharge comprising over 70% pre‐event water. Second, the high temporal resolution stream δ¹⁸O and δ²H data allowed us to detect a short‐lived reversal in stream isotopic values (δ¹⁸O increase by 0.4‰ over 9 min), which was observed immediately after the heavy rainfall period. Third, δ¹⁸O values were used to calculate a time lag of 20 min between the physical and chemical stream responses during the storm event. Finally, the hydrograph separation highlights the role of event waters in the runoff transfers of herbicides and nutrients from this heavily cultivated catchment to the Great Barrier Reef. Copyright © 2015 John Wiley & Sons, Ltd.     

From groundwater abstraction to vegetative response in fen ecosystems

Hydrological effects of groundwater abstraction near a Danish river valley have been assessed by integrated hydrological modelling. The study site contains groundwater‐dependent terrestrial ecosystems in terms of fen and spring habitats that are highly dependent on regional and local scale hydrology. Fens are rare and threatened worldwide due to pressures from agriculture, to lack of appropriate management and to altered catchment hydrology. A solid foundation for hydrological modelling was established based on intensive monitoring at the site, combined with full‐scale pumping tests in the area. A regional groundwater model was used to describe the dynamics in groundwater recharge and the large‐scale discharge to streams. A local grid refinement approach was then applied in a detailed assessment of damage in order to balance the computational effort and the need for a high spatial resolution. A considerable flow reduction in the natural spring was monitored during a full‐scale pumping test while no significant effects on the water table in the fen habitats were observed. A modelled abstraction scenario predicted a lowering of 2–3 cm in the centre of the main fen area during summer periods. The predicted change in water table conditions in the fen habitat is compared to the variability found in 35 Danish fens, and the ecological response is discussed based on statistical water‐level vegetation relations. The results provide a rare quantitative foundation for decision making in relation to management of groundwater‐dependent terrestrial ecosystems. Copyright © 2013 John Wiley & Sons, Ltd.     

Exotic pollen as an indicator of variable atmospheric circulation over the Labrador Sea region during the mid to late Holocene

Variability in the abundance of exotic (non‐native) pollen in sediment cores has long been considered as a potential proxy for changing atmospheric circulation, but the difficulty of gaining sufficient total exotic pollen and the incomplete understanding of atmospheric pollen transport patterns has hindered its application. In light of recent advances in the study of pollen transport, we present an exotic pollen record from two fjord sediment cores taken from the west (Placentia Bay, Newfoundland) and east (Narsaq Sund, Greenland) Labrador Sea as a basis for studying variations in regional atmospheric circulation. The two cores cover the last ca. 5500 years and indicate a shift in dominant spring/summer air masses at ca. 2000 (southern Greenland) and 3000 cal a BP (Newfoundland) transporting reduced concentrations of pollen from southerly and south‐westerly vegetation zones. This may suggest a shift away from more dominantly zonal atmospheric circulation (a feature of positive North Atlantic Oscillation years) to more frequent meridional circulation. These results support sea ice/sea‐surface temperature proxy reconstructions from Newfoundland, investigated as part of the same project, which also suggest increased winter atmospheric circulation during the early part of the time period studied. In this region, more positive North Atlantic Oscillation years, and therefore more zonal atmospheric circulation, are associated with increased atmospheric circulation in both the winter and the summer seasons. Copyright © 2011 John Wiley & Sons, Ltd.     

Electron density and temperature in the Io plasma torus from Ulysses thermal noise measurements

During the Ulysses flyby of Jupiter, the spacecraft crossed the outer part of the Io plasma torus along a basically North-to-South trajectory at a Jovicentric distance of about 8R_J. The quasi-thermal noise measured by the Unified Radio and Plasma Wave (URAP) experiment is used to deduce the electron density and temperature along the trajectory. The density is deduced from the upper hybrid frequency line and the temperature from the spin modulation of Bernstein waves. These results are used to build a simplified Gaussian model of the torus. The density profile is roughly symmetric with respect to the centrifugal equator, with a scale height of about 0.9R_J. The density at equator crossing is twice as large as that expected from the Divine-Garrett Voyager-based model at the same radial distance. The density scale height is lower than that found by Voyager 1; it is consistent with an ion temperature of about 5 × 10⁵K, assuming an effective mass of about 20 proton masses. The fitting of the pressure distribution, symmetric with respect to the centrifugal equator, yields a cold electron temperature of about 1.4 × 10⁵K at the equator, which is of the same order of magnitude as found by Voyager 1.     

Temperature in lowland Danish streams: contemporary patterns,empirical models and future scenarios

Continuous temperature measurements at 11 stream sites in small lowland streams of North Zealand, Denmark over a year showed much higher summer temperatures and lower winter temperatures along the course of the stream with artificial lakes than in the stream without lakes. The influence of lakes was even more prominent in the comparisons of colder lake inlets and warmer outlets and led to the decline of cold‐water and oxygen‐demanding brown trout. Seasonal and daily temperature variations were, as anticipated, dampened by forest cover, groundwater input, input from sewage plants and high downstream discharges. Seasonal variations in daily water temperature could be predicted with high accuracy at all sites by a linear air‐water regression model (r²: 0·903–0·947). The predictions improved in all instances (r²: 0·927–0·964) by a non‐linear logistic regression according to which water temperatures do not fall below freezing and they increase less steeply than air temperatures at high temperatures because of enhanced heat loss from the stream by evaporation and back radiation. The predictions improved slightly (r²: 0·933–0·969) by a multiple regression model which, in addition to air temperature as the main predictor, included solar radiation at un‐shaded sites, relative humidity, precipitation and discharge. Application of the non‐linear logistic model for a warming scenario of 4–5 °C higher air temperatures in Denmark in 2070‐2100 yielded predictions of temperatures rising 1·6–3·0 °C during winter and summer and 4·4–6·0 °C during spring in un‐shaded streams with low groundwater input. Groundwater‐fed springs are expected to follow the increase of mean air temperatures for the region. Great caution should be exercised in these temperature projections because global and regional climate scenarios remain open to discussion. Copyright © 2006 John Wiley & Sons, Ltd.     

The recession of the Inland Ice margin during the Holocene climatic optimum in the Jakobshavn Isfjord area of West Greenland

Recent subsurface mapping of parts of the Greenland Inland Ice margin in the region of Jakobshavn Isbræ indicates that the fjord system in the period of at least 2700–4700 calendar yr B.P. was more ice free than at present, and that the front of the glacier was at least 15 km behind the present position. The ¹⁴C-dating of subfossils brought to the present ice margin fit with the climatic records from ice cores and confirm the favourable conditions for Greenland's first settlers, the Sarqaq people, who arrived in the region about 400 yr ago to find hunting grounds 10–20% larger than the present.     

Gamma-burst studies using long-duration balloon flights in the Arctic

A new detector for accurate localization of the cosmic gamma-burst sources is presented. The detector is intended for satellite applications, but balloon flights will be used in the development phase. The advantages and limitations of Arctic balloon flights are discussed based on a trial flight in August 1979.Paper presented at the Symposium on Cosmic Gamma-Ray Bursts, held at Toulouse, France, 26–29 November, 1979.     

Oxygen isotope and palaeotemperature records from six Greenland ice‐core stations: Camp Century,Dye‐3, GRIP,GISP2, Renland and NorthGRIP

Oxygen isotope variations spanning the last glacial cycle and the Holocene derived from ice‐core records for six sites in Greenland (Camp Century, Dye‐3, GRIP, GISP2, Renland and NorthGRIP) show strong similarities. This suggests that the dominant influence on oxygen isotope variations reflected in the ice‐sheet records was regional climatic change. Differences in detail between the records probably reflect the effects of basal deformation in the ice as well as geographical gradients in atmospheric isotope ratios. Palaeotemperature estimates have been obtained from the records using three approaches: (i) inferences based on the measured relationship between mean annual δ¹⁸O of snow and of mean annual surface temperature over Greenland; (ii) modelled inversion of the borehole temperature profile constrained either by the dated isotopic profile, or (iii) by using Monte Carlo simulation techniques. The third of these approaches was adopted to reconstruct Holocene temperature variations for the Dye 3 and GRIP temperature profiles, which yields remarkably compatible results. A new record of Holocene isotope variations obtained from the NorthGRIP ice‐core matches the GRIP short‐term isotope record, and also shows similar long‐term trends to the Dye‐3 and GRIP inverted temperature data. The NorthGRIP isotope record reflects: (i) a generally stronger isotopic signal than is found in the GRIP record; (ii) several short‐lived temperature fluctuations during the first 1500 yr of the Holocene; (iii) a marked cold event at ca. 8.2 ka (the ‘8.2 ka event’); (iv) optimum temperatures for the Holocene between ca. 8.6 and 4.3 ka, a signal that is 0.6‰ stronger than for the GRIP profile; (v) a clear signal for the Little Ice Age; and (vi) a clear signal of climate warming during the last century. These data suggest that the NorthGRIP stable isotope record responded in a sensitive manner to temperature fluctuations during the Holocene. Copyright © 2001 John Wiley & Sons, Ltd.     

First incoherent scatter radar observations of ionospheric heating on the second electron gyro-harmonic

We report first results from a unique experiment performed at the HIPAS ionospheric modification facility in conjunction with the Poker Flat incoherent scatter radar in Alaska. High-power radio waves at 2.85 MHz, which corresponds to the second electron gyro-harmonic at ~245 km altitude, were transmitted into the nighttime ionosphere. Clear evidence of F-region ionospheric electron temperature enhancements were found, for the first time at this pump frequency, maximizing when the pump frequency is close to the second gyro-harmonic and double resonance. This is consistent with previous pump-enhanced artificial optical observations. We estimate the plasma heating efficiency to be approximately double that for higher pump frequencies.     

Estrogenicity of xenobiotics in rainbow trout (Oncorhynchus mykiss) using in vivo synthesis of vitellogenin as a biomarker

The estrogenicity of several xenobiotics was evaluated using in vivo vitellogenin (Vtg) synthesis in immature rainbow trout as a biomarker. 17β-estradiol, DES and ethinyl estradiol were tested as positive controls. The xenobiotic compounds tested were technical nonylphenol, bisphenol A, butylbenzylphthalate (BBP) and dibutylphthalate (DBF). Measurements of the Vtg concentration was performed with a direct sandwich ELISA. 17β-estradiol, DES and ethinyl estradiol caused up to 100 000-fold increases in the Vtg-levels. Nonylphenol and bisphenol A had the highest estrogenic potency of the xenobiotics increasing the vitellogenin level approximately 300-fold while BBP was only weakly estrogenic, increasing the concentration about 3 times. DPB did not raise the vitellogenin contration above the detection limit.