Difficulties in determining electrical anisotropy in subsurface investigations

Surface electrical and electromagnetic methods have a limited resolution capability for determining the conductivity structure of the earth. In one-dimensional modelling a collection of many thin layers is frequently considered as one composite layer, which is then macro-anisotropic. Neither galvanic methods nor inductive methods alone can resolve the anisotropy of the ground, but a joint inversion of galvanic and inductive data may do so. The necessity of including the coefficient of anisotropy in the joint inversion of galvanic and inductive sounding data is demonstrated. An analysis is made of the combined use of geoelectrical and transient soundings to resolve the coefficient of anisotropy of a subsurface layer for varying thickness, resistivity and coefficient of anisotropy. It is found that the coefficient of anisotropy is well resolved only for layers that are many times thicker than the overburden and for coefficients of anisotropy that are not too small. The ability of the joint inversion of geoelectrical and transient sounding data to resolve macro-anisotropic layers is tested using realistic earth models determined from electrical logs.     

Globalisation, State Regulation and Industrial Upgrading of the Oil Seed Industries in Malaysia and Brazil

Palm oil from Malaysia and soybean meal from Brazil are of major importance in the world market. State regulation in both countries has played a crucial role in agro-industrial upgrading, i.e. the establishment, consolidation and diversification of manufacturing capacity in the oil seed chains. In particular, sufficient volumes of raw materials for local processing have been secured through systems of differential export taxes. This core set of regulatory mechanisms has been used in both countries, despite structural differences between the two chains related to the properties of the crops (oil palms and soybeans), the previous organisation of agricultural production, and the size and nature of the local markets. Globalisation in its present neoliberal form, institutionalised within the World Trade Organisation, gradually erodes the opportunity for other developing country states to upgrade agro-industries by adapting similar forms of regulatory mechanisms.     

Fate of Point‐Source Pesticide Spill in Clayey Till after 15 Years

This study investigated the development of pesticide pollution two, three, and 17 years after spills of the herbicides dichlorprop, mecoprop (MCPP), MCPA, 2,4‐D (phenoxy acids), simazine, and terbutylazine (triazines) in a former orchard machinery service yard. The spills had occurred over several decades on a 23‐m thick, mainly anaerobic fractured clayey till aquitard. Angled monitoring wells were installed in the aquitard 3 years after the spills ceased in 1989. In 1993, monitoring revealed that high groundwater concentrations of dichlorprop (677 µg/L) and MCPP (139 µg/L) were accumulated as a zone of maximum pollution in anaerobic and largely immobile pore water at 5 to 6 m depth in the aquitard profile. In contrast, 2,4‐D was determined in only one water sample, and MCPA and simazine and terbutylazine were determined only in low concentrations (below10 µg/L), although these pesticides had been handled at the site in greater amounts than dichlorprop and MCPP according to detailed historic information obtained for the site. Repeated monitoring in the same wells after a further 14 years in 2007 revealed that no identifiable degradation of MCPP had occurred, while dichlorprop had degraded by 75% to 80% (estimated half‐life of approximately 5 years). Furthermore, degradation products related to the phenoxy acids had accumulated, especially 4‐CPP with a maximum concentration of 218 µg/L. In the same zone, MCPA and simazine had almost disappeared. As the pollution was mainly accumulated in largely immobile pore water of the aquitard clayey matrix, and the groundwater recharge was low (30 to 60 mm/year), only minor vertical displacement of the zone with maximum pollution zone had occurred during the 15 years of monitoring. However, concentrations of dichlorprop (0.01 to 0.02 µg/L), MCPP (0.1 to 0.2 µg/L), and 4‐CPP (0.6 to 0.7 µg/L) had spread along textural heterogeneities in the aquitard into the underlying sandy aquifer at 23‐m depth.     

Debris entrainment by basal freeze‐on and thrusting during the 1995–1998 surge of Kuannersuit Glacier on Disko Island,west Greenland

Kuannersuit Glacier, a valley glacier on Disko Island in west Greenland, experienced a major surge from 1995 to 1998 where the glacier advanced 10·5 km and produced a ～65 m thick stacked sequence of debris‐rich basal ice and meteoric glacier ice. The aim of this study is to describe the tectonic evolution of large englacial thrusts and the processes of basal ice formation using a multiproxy approach including structural glaciology, stable isotope composition (δ¹⁸O and δD), sedimentology and ground‐penetrating radar. We argue that the major debris layers that can be traced in the terminal zone represent englacial thrusts that were formed early during the surge. Thrust overthrow was at least 200–300 m and this lead to a 30 m thick repetition of basal ice at the ice margin. It is assumed that the englacial thrusting was initiated at the transition between warm ice from the interior and the cold snout. The basal debris‐rich ice was mainly formed after the thrusting phase. Two sub‐facies of stratified basal ice have been identified; a lower massive ice facies (S_M) composed of frozen diamict enriched with heavy stable isotopes overlain by laminated ice facies (S_L) consisting of millimetre thick lamina of alternating debris‐poor and debris‐rich ice. We interpret the stratified basal ice as a continuum formed mainly by freeze‐on processes and localized regelation. First laminated basal ice is formed and as meltwater is depleted more sediment is entrained and finally the glacier freezes to the base and massive diamict is frozen‐on. The increased ability to entrain sediments may partly be associated with higher basal freezing rates enhanced by loss of frictional heat from cessation of fast flow and conductive cooling through a thin heavily crevassed ice during the final phase of the glacier surge. The dispersed basal ice facies (D) was mainly formed by secondary processes where fine‐grained sediment is mobilized in the vein system of ice. Our results have important implications for understanding the significance of basal ice formation and englacial thrusting beneath fast‐flowing glaciers and it provides new information about the development of landforms during a glacier surge. Copyright © 2010 John Wiley & Sons, Ltd.     

Gas-Phase OH Oxidation of Monoterpenes: Gaseous and Particulate Products

Smog chamber experiments have beenconducted in which cyclic monoterpenes were oxidisedin the gas phase by OH. The evolved secondary organicaerosol (SOA) was analysed by LC-MSⁿ and thegas-phase products were analysed by FT-IR. Theconcentrations of the identified compoundscorresponded to carbon mass balances in the range of40%–90%. The identified compounds in the particularphase corresponded to 0.5%–4.2% of the reactedcarbon. The most abundant compounds in SOA fromterpenes with an endocyclic C=C double bond wereC₁₀-keto-aldehydes, C₁₀-keto-carboxylicacids, C₁₀-hydroxy-keto-carboxylic acids, andC₁₀-hydroxy-keto-aldehydes (pinonaldehyde,pinonic acid, hydroxy-pinonic acid isomers, andhydroxy-pinonaldehyde isomers from -pinene;3-caronaldehyde, 3-caronic acid, hydroxy-3-caronicacid isomers, and hydroxy-3-caronaldehyde isomers from3-carene). The most abundant compounds in SOA fromterpenes with an exocyclic C=C double bond wereC₉-ketones, C₉-dicarboxylic acids, andC₁₀-hydroxy-keto-carboxylic acids (nopinone,pinic acid, and hydroxy-pinonic acid isomers from-pinene; sabinaketone, sabinic acid andhydroxy-sabinonic acid isomers from sabinene).Decarboxylated analogues of most of the compounds werepresent in SOA in minor concentrations, such asC₉-keto-carboxylic acids (norpinonic acid,nor-3-caronic acid) and C₈-dicarboxylic acids(norpinic acid, nor-3-caric acid, norsabinic acid). InSOA from limonene, which contains an endocyclic aswell as an exocyclic C=C double bond, the mostabundant compounds were a C₁₀-keto-aldehyde andits oxo-derivative (limononaldehyde and keto-limononaldehyde) together with hydroxy-derivatives of aC₁₀-keto-carboxylic acid (isomers ofhydroxy-limononic acid). Also aC₁₀-keto-carboxylic acid (limononic acid) waspresent together with minor concentrations of aC₉-dicarboxylic acids (limonic acid), itsoxo-derivative (keto-limonic acid), and itsdecarboxylated analogue (norlimonic acid). Mechanisticpathways for the formation of these products, some ofwhich are identified here for the first time, areproposed.     

Oxygen-isotope systematics of a strongly recrystallized granitic rock complex,Grenvillian Belt,SW Sweden

In the eastern, external part of the Grenvillian Belt in SW Sweden, five formations of granitic rocks were found in the basement of the Dalslandian Supracrustal Group. The granitic rocks have been strongly recrystallized but have preserved most of their granitic texture in the process. Most magmatic crystals have been pseudomorphed by metamorphic minerals: quartz, albite, chlorite, biotite, white mica, epidote, titanite, hematite, pyrite and carbonate. Two of the formations have subsequently been affected by a cataclastic deformation and at present consist of mylogneisses. ¹⁸O whole-rock values for the granitic rocks vary from +3.0 to +11.1. Quartz-apatite, quartz-zircon and quartz-titanite pairs show ¹⁸O/¹⁶O fractionations corresponding to equilibrium temperatures of 550–700° C, which are believed to reflect in the main continued closed-system isotopic exchange at high temperatures following solidification. In contrast highly positive ¹⁸O/¹⁶O fractionations for quartz-K-feldspar, quartz-biotite, quartz-chlorite and quartz-sericite pairs in some granitic samples indicate that these rocks have exchanged oxygen with heated, meteoric, H₂O dominated fluids. Other granitic samples, however, show virtually undisturbed magmatic ¹⁸O/¹⁶O fractionation values for the same mineral pairs, even though these rocks are equally altered.It is concluded that all granitic rock units recrystallized under greenschist facies conditions during the infiltration of fluids under the influence of hydrothermal convection systems set up by the intrusion of the granitic plutons. The fluids probably had a range of ¹⁸O values from ca. -14 to ca. +10, indicating the mixing of distinct fluid reservoirs, one of meteoric origin and the others of magmatic and/or metamorphic origin. The temperature of alteration is estimated at 450–500° C.Estimation of pre-alteration ¹⁸O whole rock values for the five granitic units suggests that three units should be assigned a dominantly S-type origin, where as the other two units may partly or wholly have an I-type origin.     

Palaeomagnetic timing of the rotation and translation of Cyprus

The geological evolution of the Mesozoic Troodos Ophiolite Complex in Cyprus, and the tectonic nature and timing of the palaeomagnetically indicated anticlockwise rotation of Cyprus of some 80° and ca. 15° northward translation, have been open for debate for some time. New palaeomagnetic data from 18 sites ( 180samples) in the post-ophiolite sediments, ranging in age from Upper Cretaceous to Upper Miocene, are presented. Most of the sites are of normal geomagnetic polarity, but indications of reversed polarity have been found in an older group of sediments (the Lefkara Formation of Upper Palaeocene age).Six sites from the older group of sediments (Upper Cretaceous to Eocene in age) give a site mean direction of the AF cleaned sediments of (D, I) = (323°, 29°) with α₉₅ = 18°, while 5 sites from a younger group of sediments (Oligocene to Miocene in age) give a cleaned site mean direction of (D, I) = (334°, 58°) with α₉₅ = 9°. These and published data suggest that an anticlockwise rotation of Cyprus of 60 ± 10° occurred early during the post-igneous evolution of the Cyprus oceanic crust between 90 and 50Ma, leaving only a minor anticlockwise rotation of 20 ± 10° to occur during the last 50 Ma. It is furthermore concluded that the northward translation of Cyprus of 15° mostly took place during the last 30Ma.It thus appears that a fairly rapid rotation of the Cyprus microplate first took place in the Late Cretaceous and Early Tertiary time with an average angular velocity of 1–2°/Ma, during which the northward translation was minor or negligible. In the latter half of the Tertiary, the sense of movement appears to have radically changed, the northward translation now being dominant with an average velocity of 5–6cm/yr. This temporal evolution is found to be in good agreement with the Mesozoic and Tertiary movements of the African lithospheric plate relative to Europe, as evidenced from the Atlantic sea-floor magnetic anomaly spreading history.     

The effectiveness of communicative tools in addressing barriers to municipal climate change adaptation: lessons from the Netherlands

Little research has been done on the effectiveness of communicative tools for climate change adaptation. Filling this knowledge gap is relevant, as many national governments rely on communicative tools to raise the awareness and understanding of climate impacts, and to stimulate adaptation action by local governments. To address this knowledge gap, this study focuses on the effectiveness of communicative tools in addressing key municipal barriers to climate change adaptation, by conducting a large N-size empirical study in the Netherlands. This study explores the effectiveness of these tools in theory, by checking whether their goals match the perceived barriers to municipal climate change adaptation, and the effectiveness in practice by analysing whether they are used and perceived as useful. Document analyses have clarified the assumptions underlying the tools. By conducting semi-structured interviews with 84 municipalities the key barriers to climate change adaptation and the use and usefulness of the tools in practice were analysed. The research revealed that the key barriers experienced by municipalities are a lack of urgency, a lack of knowledge of risks and measures, and limited capacity, the first being the primary one. Communicative tools, while being effective in theory, are not sufficiently effective in practice in addressing the key barriers. Municipalities that are not experiencing a sense of urgency to take on adaptation planning are not likely to be activated by the tools. Advanced municipalities need more sophisticated tools. This article concludes with some suggestions to improve the effectiveness of communicative tools.

Key policy insights

• Although effective in theory in addressing key barriers to municipal adaptation planning, the effectiveness in practice of communicative tools is limited.

• To increase their effectiveness in practice, municipalities’ awareness of the existence of the communicative tools needs to be raised.

• Advanced municipalities need more sophisticated tools that are context-specific and address a wide range of climate risks.

• The effectiveness of communicative tools can be improved by embedding them in a wider mix of policy instruments.