Phosphate amendment of metalliferous tailings, Cannington Ag–Pb–Zn mine, Australia: implications for the capping of tailings storage facilities

This study appraised the use of phosphate fertilisers in immobilising metals in mine tailings to prevent their uptake into Curly Mitchell grass (Astrebla lappacea), when grown on capped, phosphate-amended tailings. Leaching experiments showed that Pb mobility was reduced by both bone meal and superphosphate amendment. Bone meal amendment also reduced Cd mobility. By contrast, Cd, Mn and Zn mobility increased in superphosphate-amended tailings due to increased acid production and, Cu was mobilised in bone meal-amended tailings possibly through the formation of soluble metal-complexing organic compounds. Arsenic and Sb were mobilised in both treatments due to phosphate ligand exchange. Greenhouse trials used Curly Mitchell grass grown on 1-m-high columns stacked with waste materials and different amendments overlain by clean topsoil. Curly Mitchell grass showed substantial uptake of Cd, Mn, Pb and Zn from unamended tailings and waste rock, where these were penetrated by the plant’s root system. Addition of phosphate fertilisers to the surface of tailings did not result in reduced metal uptake by Curly Mitchell grass. In tailings capped with limestone, the limestone layer formed an effective physical barrier preventing root penetration into the tailings and led to substantially reduced metal uptake in grass. The study demonstrates that thorough mixing of waste materials and fertilisers as well as irrigation may be required for successful phosphate immobilisation of metals in base metal tailings. Alternatively, the placement of a thin layer of crushed limestone on top of the tailings pile prior to capping may lead to the formation of a chemical and physical barrier and prevent the transfer of environmentally significant elements into the above-ground biomass of Mitchell grasses.     

A demonstration of the importance of bedload transport for fluvial bedrock erosion and knickpoint propagation

We provide field evidence for the role of bedload in driving fluvial incision and knickpoint propagation. Using aerial photographs, field surveys, and hydrological data, we constrain the incision history of a bedrock gorge 1200 m long and up to 20 m deep cut by Da'an River in western Taiwan. This reach of the river experienced 10 m of uplift during the 1999 Chi‐Chi earthquake. For five years following the earthquake, bedload was prevented from entering the uplift zone, the knickpoint was static and little incision took place. Bedload transport across the uplift zone resumed in 2004, initiating extremely rapid incision, with 620 m of knickpoint propagation and up to 20 m of downcutting by 2008. This change highlights the relative inefficiency of suspended sediment and the dominant role of bedload as a tool for fluvial erosion and knickpoint propagation. Once bedload tools became available, knickpoint propagation was influenced by geological structure, lithology, and drainage organization. In particular, a change in dip of the sandstone beds at the site caused a decrease of knickpoint propagation velocity. Copyright © 2012 John Wiley & Sons, Ltd.     

The use of salinity contrast for density difference compensation to improve the thermal recovery efficiency in high-temperature aquifer thermal energy storage systems

The efficiency of heat recovery in high-temperature (>60 °C) aquifer thermal energy storage (HT-ATES) systems is limited due to the buoyancy of the injected hot water. This study investigates the potential to improve the efficiency through compensation of the density difference by increased salinity of the injected hot water for a single injection-recovery well scheme. The proposed method was tested through numerical modeling with SEAWATv4, considering seasonal HT-ATES with four consecutive injection-storage-recovery cycles. Recovery efficiencies for the consecutive cycles were investigated for six cases with three simulated scenarios: (a) regular HT-ATES, (b) HT-ATES with density difference compensation using saline water, and (c) theoretical regular HT-ATES without free thermal convection. For the reference case, in which 80 °C water was injected into a high-permeability aquifer, regular HT-ATES had an efficiency of 0.40 after four consecutive recovery cycles. The density difference compensation method resulted in an efficiency of 0.69, approximating the theoretical case (0.76). Sensitivity analysis showed that the net efficiency increase by using the density difference compensation method instead of regular HT-ATES is greater for higher aquifer hydraulic conductivity, larger temperature difference between injection water and ambient groundwater, smaller injection volume, and larger aquifer thickness. This means that density difference compensation allows the application of HT-ATES in thicker, more permeable aquifers and with larger temperatures than would be considered for regular HT-ATES systems.     

The geography of urban greenhouse gas emissions in Asia: A regional analysis

This paper aims to advance two objectives: (1) identify and explore greenhouse gas emissions from urban areas in Asia at the regional level; and (2) explore covariates of urban greenhouse gas emissions. We use the Emissions Database for Global Atmospheric Research estimates for carbon dioxide, methane, nitrous oxide, and sulfur hexafluoride from 14 source activities for the year 2000, which are allocated on a 1/10° global grid. We extract emissions for 3535 urban extents all with populations over 50,000, accounting for approximately 91% of the region's urban population. We use regression analysis to associate emissions with urban area and growth, economic, and biophysical characteristics. Our findings suggest that urban areas account for between 30 and 38% of total anthropogenic greenhouse gas emissions for the region and that emission per capita averages from urban areas are lower than those at the national level. Important covariates for total urban greenhouse gas emissions include population size, density and growth rate, income per capita, development status and elevation. This is a first and preliminary assessment of regional baseline trends using these data and this top-down analysis.     

Mobility and potential bioavailability of traffic-derived trace metals in a ‘wet–dry’ tropical region,Northern Australia

The aqueous mobility and potential bioavailability of metals and metalloids in road runoff in a ‘wet–dry’ tropical location were assessed by analysing metal and metalloid concentrations in particulate, total dissolved and labile dissolved phases in runoff waters. Road-derived Al, Cu, Pb, Sb and Zn concentrations were substantially elevated in runoff when compared to receiving creek waters. Median dissolved concentrations in road runoff exceeded those in creek waters by up to an order of magnitude. Leaching experiments of road sediments confirmed that several metals and metalloids were released in high concentrations from road sediments. Labile Zn and Cu concentrations measured by diffusion gradients in thin films (DGT) showed that almost all dissolved Zn and up to half of dissolved Cu in runoff waters and in road sediment leachate were potentially bioavailable. Comparisons of dissolved metal concentrations in receiving waters affected by road runoff with ecosystem guideline levels, indicated a risk of reaching toxic levels of Cu and Zn in the receiving waters in the absence of adequate treatment or dilution. Low dilution rates of road runoff are likely to occur during late ‘dry’ season/early ‘wet’ season storms which have the potential to produce high metal concentrations derived from long periods of accumulation of road sediment at a time when creek flow rates are at their annual minimum.     

南极中山站至Dome A剖面表面雪样氧同位素组成

运用质谱技术 ,测定了南极中山站至 Dome A剖面 1 998/1 999年度表面雪样氧同位素组成。结果表明 ,表面雪样氧同位素组成变化范围相当大 (- 2 2 .5 1‰ - - 5 0 .6 7‰ ) ,且具有随距中山站距离逐渐增大、海拔高度逐渐增加而逐渐减小的趋势。线性回归分析显示表面雪样氧同位素组成与距中山站距离、海拔高度和纬度存在着很好的相关性 ,这实际上反映出稳定同位素组成和温度之间的密切联系     

Palaeomagnetism of the Proterozoic Zig-Zag Dal Basalt and the Midsommersø Dolerites, eastern North Greenland

Summary. Palaeomagnetic investigations are reported from 24 sites in the Proterozoic Zig-Zag Dal Basalt Formation and 12 sites in the Midsominersø Dolerites of eastern North Greenland. The Zig-Zag Dal Basalt is a typical tholeiitic flood basalt sequence, and dolerite intrusions in the underlying sandstones are thought to be genetically related to the basalts.
After a detailed AF demagnetization programme 19 sites in the basalts and 10 sites in the dolerites reveal one stable component of magnetization, probably of TRM and/or CRM origin residing in small single domain titano-magnetite grains. The degree of anisotropy has not affected the direction of the remanent magnetization. The maximum axis of the anisotropy ellipsoid is parallel to the flow direction of the magma, whereas the minimum axis is perpendicular to the flow plane.
Only one polarity of the geomagnetic field was found. The mean palaeomagnetic pole positions for the two rock types are not significantly different (basalt: 12.2°S, 62.8°E with A ₉₅= 3.8°; dolerites: 6.9°S, 62.0°E with A ₉₅ = 5.1°). After correction for Phanerozoic drift of Greenland the two mean poles compare closely to a relevant North American APW-curve for 1250–1350 Ma, in good agreement with Rb-Sr isochron ages of 1250 Ma obtained for the intrusives. The palaeogeographical position of Greenland was near equator with the major geographical axis orientated E-W.