Acta Geochimica - In this paper, the Jurassic granitoid dike that intrudes into Permian diabase was reported in Luokun, Luodian County, south Guizhou. Zircon LA-ICP-MS U–Pb dating of the... 相似文献
The newly discovered Baogudi gold district is located in the southwestern Guizhou Province, China, where there are numerous Carlin-type gold deposits. To better understand the geological and geochemical characteristics of the Baogudi gold district, we carried out petrographic observations, elemental analyses, and fluid inclusion and isotopic composition studies. We also compared the results with those of typical Carlin-type gold deposits in southwestern Guizhou. Three mineralization stages, namely, the sedimentation diagenesis, hydrothermal (main-ore and late-ore substages), and supergene stages, were identified based on field and petrographic observations. The main-ore and late-ore stages correspond to Au and Sb mineralization, respectively, which are similar to typical Carlin-type mineralization. The mass transfer associated with alteration and mineralization shows that a significant amount of Au, As, Sb, Hg, Tl, Mo, and S were added to mineralized rocks during the main-ore stage. Remarkably, arsenic, Sb, and S were added to the mineralized rocks during the late-ore stage. Element migration indicates that the sulfidation process was responsible for ore formation. Four types of fluid inclusions were identified in ore-related quartz and fluorite. The main-ore stage fluids are characterized by an H2O–NaCl–CO2–CH4 ± N2 system, with medium to low temperatures (180–260 °C) and low salinity (0–9.08% NaCl equivalent). The late-ore stage fluids featured H2O–NaCl ± CO2 ± CH4, with low temperature (120–200 °C) and low salinity (0–7.48% NaCl equivalent). The temperature, salinity, and CO2 and CH4 concentrations of ore-forming fluids decreased from the main-ore stage to the late-ore stage. The calculated δ13C, δD, and δ18O values of the ore-forming fluids range from − 14.3 to − 7.0‰, −76 to −55.7‰, and 4.5–15.0‰, respectively. Late-ore-stage stibnite had δ34S values ranging from − 0.6 to 1.9‰. These stable isotopic compositions indicate that the ore-forming fluids originated mainly from deep magmatic hydrothermal fluids, with minor contributions from strata. Collectively, the Baogudi metallogenic district has geological and geochemical characteristics that are typical of Carlin-type gold deposits in southwest Guizhou. It is likely that the Baogudi gold district, together with other Carlin-type gold deposits in southwestern Guizhou, was formed in response to a single widespread metallogenic event.
Satellite records show that the extent and thickness of sea ice in the Arctic Ocean have significantly decreased since the early 1970s. The prediction of sea ice is highly important, but accurate simulation of sea ice variations remains highly challenging. For improving model performance, sensitivity experiments were conducted using the coupled ocean and sea ice model (NEMO-LIM), and the simulation results were compared against satellite observations. Moreover, the contribution ratios of dynamic and thermodynamic processes to sea ice variations were analyzed. The results show that the performance of the model in reconstructing the spatial distribution of Arctic sea ice is highly sensitive to ice strength decay constant (Crhg). By reducing the Crhg constant, the sea ice compressive strength increases, leading to improved simulated sea ice states. The contribution of thermodynamic processes to sea ice melting was reduced due to less deformation and fracture of sea ice with increased compressive strength. Meanwhile, dynamic processes constrained more sea ice to the central Arctic Ocean and contributed to the increases in ice concentration, reducing the simulation bias in the central Arctic Ocean in summer. The root mean square error (RMSE) between modeled and the CryoSat-2/SMOS satellite observed ice thickness was reduced in the compressive strength-enhanced model solution. The ice thickness, especially of multiyear thick ice, was also reduced and matched with the satellite observation better in the freezing season. These provide an essential foundation on exploring the response of the marine ecosystem and biogeochemical cycling to sea ice changes.