Organotemplate silica deposition in Neoproterozoic deep-marine environments: evidence from the Penganga Group, Adilabad, India

Silica in bedded cherts interstratified with manganese carbonates in a deep‐water carbonate ramp succession of the Neoproterozoic Penganga Group, India, displays film‐like, spherical to rod‐shaped, and tubular branching microstructures. The microstructures resemble mineralized extracellular polysaccharides, biofilms and bacterial morphologies. The microstructures suggest silicification by nucleation of silica on organic‐templates or indirectly as sorbed species accumulating on organic templates. Given that similar microstructures have also been documented in Archean cherts it is proposed that organotemplates might have been an important sink for the deposition of silica in Precambrian deep‐water marine environments.     

Coupling mechanisms in double sandbar systems. Part 2: impact on alongshore variability of inner‐bar rip channels

Double sandbar systems are common morphological features along sandy, wave‐dominated, micro‐ to meso‐tidal coastlines. In the companion paper, we demonstrated how various alongshore inner‐bar rip‐channel patterns can develop through morphological coupling to an alongshore‐variable outer bar. The simulated coupling patterns are, however, scarcely observed in the field. Instead, inner‐bar rip channels more often possess remarkably smaller and more variable alongshore length scales, suggesting that coupling mechanisms do not play a substantial role in the overall double‐sandbar dynamics. Here we use a numerical model to show that the relative importance of self‐organization and morphological coupling changes in favour of the latter with an increase in waterdepth variability along the outer‐bar crest. Furthermore, we find that the typical alongshore variability in inner‐bar rip‐channel scale is indicative of a mixture of self‐organization and morphological coupling rather than self‐organization alone. Morphological coupling may thus be more important to understanding and predicting the evolution of inner‐bar rip channels than previously envisaged. Copyright © 2010 John Wiley and Sons, Ltd.     

Das Problem des Fazieswechsels in der Mitteltrias der Südtiroler Dolomiten

Ohne ZusammenfassungVortrag, gehalten in der Hauptversammlung der Geologischen Vereinigung in Frankfurt a. M., am 7. I. 1928. Ausführlichere Mitteilungen über dieses Thema werden im Rahmen einer größeren Abhandlung über die südalpine Mitteltrias an anderer Stelle veröffentlicht werden.     

Evidence for delayed poleward expansion of North Atlantic surface waters during the last interglacial (MIS 5e)

The Last Interglacial (Marine Isotopic Stage or MIS 5e) surface ocean heat flux from the Rockall Basin (NE Atlantic) towards the Arctic Ocean was reconstructed by analysing dinoflagellate cyst (dinocyst) assemblages in four sediment cores. Together with records of stable isotopes and ice-rafted detritus, the assemblage data reflect the northward retreat of ice(berg)-laden waters and the gradual development towards interglacial conditions at the transition from the Saalian deglaciation (Termination II) into MIS 5e. At the Rockall Basin, this onset of the Last Interglacial is soon followed by the appearance of the thermophilic dinocyst species Spiniferites mirabilis, with relative abundances higher than those observed at present in the area. North of the Iceland-Scotland Ridge, however, S. mirabilis only appears in significant numbers during late MIS 5e, between ～118 and 116.5 ka. Hence, fully marine Last Interglacial conditions with most intense Atlantic surface water influence occurred during late MIS 5e in the Nordic seas, and consequently also farther north in the Arctic Ocean, and at times when northern hemisphere summer insolation was already significantly decreased. The stratigraphic position of this Late Interglacial optimum is supported by planktic foraminifers and contrasts with the timing of the early Holocene climatic optimum in this area. We interpret the delayed northward expansion of Atlantic waters towards the polar latitudes as a result of the Saalian ice sheet deglaciation and its specific impact on the subsequent water mass evolution in this region.     

Earthquakes in Switzerland and surrounding regions during 2006

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2006. During this period, 572 earthquakes and 91 quarry blasts were detected and located in the region under consideration. Of these earthquakes, two occurred in conjunction with the construction of the new Gotthard railway tunnel and 165 were induced artificially by the stimulation of a proposed geothermal reservoir beneath the city of Basel. With 20 events with M _L ≥ 2.5, five of which were artificially induced, the seismic activity in the year 2006 was far below the average over the previous 31 years. Nevertheless, six events were felt by the public, most prominently the strongest of the induced Basel events (M _L 3.4), which caused some non-structural building damage. Noteworthy are also the two earthquakes near Cortaillod (M _L 3.2), on the shore of Lake Neuchatel, and in Val Mora (M _L 3.5), between the Engadin and Val Müstair, as well as the 42 aftershocks of the M _L 4.9 Vallorcine earthquake, between Martigny and Chamonix, of September 2005. Editorial handling: Stefan Bucher     

Micro- and nano-textural evidence of Ti(–Ca–Fe) mobility during fluid–rock interactions in carbonaceous lawsonite-bearing rocks from New Zealand

Understanding the mobility of chemical elements during fluid–rock interactions is critical to assess the geochemical evolution of a rock undergoing burial and metamorphism and, more generally, to constrain the geochemical budget of the subduction factory. In particular, determining the behavior and mobility of Ti in aqueous fluids constitutes a great challenge that is still under scrutiny. Here, we study plant fossils preserved in blueschist metasedimentary rocks from the Marybank Formation (New Zealand). Using scanning and transmission electron microscopies (SEM and TEM), we show that the carbonaceous material (CM) composing the fossils contains abundant nano-inclusions of Ti- and Fe-oxides. These nanocrystals are mainly anatase, rutile, and Fe–Ti oxides. The mineral composition observed within the fossils is significantly different from that detected in the surrounding rock matrix. We propose that Ti and Fe might have been mobilized by the alteration of a detrital Ti–Fe-rich protolith during an early diagenetic event under acidic and reducing conditions. Aqueous fluids rich in organic ligands released by the degradation of organic matter may have been involved. Moreover, using mass balance and petrological observations, we show that the contrasted mineralogy between the rock matrix and the fossil CM might be the consequence of the chemical isolation of fossil CM during the prograde path of the rock. Such an isolation results from the early formation of quartz and Fe-rich phyllosilicate layers enclosing the fossil as characterized by SEM and TEM investigations. Overall, this study shows that investigating minerals associated with CM down to the nanometer scale in metamorphic rocks can provide a precious record of early prograde geochemical conditions.     

Solar abundance of praseodymium

16 lines of Pr ii possibly present in the solar photospheric spectrum have been studied. When including hyperfine structure in synthetic calculations, investigations of 9 lines result in an abundance A _Pr = 0.71 ± 0.08 in the log A _H = 12.00 scale.     

CO2-H2O mixtures in the geological sequestration of CO2. II. Partitioning in chloride brines at 12-100°C and up to 600 bar

Correlations presented by Spycher et al. (2003) to compute the mutual solubilities of CO₂ and H₂O are extended to include the effect of chloride salts in the aqueous phase. This is accomplished by including, in the original formulation, activity coefficients for aqueous CO₂ derived from several literature sources, primarily for NaCl solutions. Best results are obtained when combining the solubility correlations of Spycher et al. (2003) with the activity coefficient formulation of Rumpf et al. (1994) and Duan and Sun (2003), which can be extended to chloride solutions other than NaCl. This approach allows computing mutual solubilities in a noniterative manner with an accuracy typically within experimental uncertainty for solutions up to 6 molal NaCl and 4 molal CaCl₂.     

Development and validation of a regional coupled atmosphere lake model for the Caspian Sea Basin

We present a validation analysis of a regional climate model coupled to a distributed one dimensional (1D) lake model for the Caspian Sea Basin. Two model grid spacings are tested, 50 and 20 km, the simulation period is 1989–2008 and the lateral boundary conditions are from the ERA-Interim reanalysis of observations. The model is validated against atmospheric as well as lake variables. The model performance in reproducing precipitation and temperature mean seasonal climatology, seasonal cycles and interannual variability is generally good, with the model results being mostly within the observational uncertainty range. The model appears to overestimate cloudiness and underestimate surface radiation, although a large observational uncertainty is found in these variables. The 1D distributed lake model (run at each grid point of the lake area) reproduces the observed lake-average sea surface temperature (SST), although differences compared to observations are found in the spatial structure of the SST, most likely as a result of the absence of 3 dimensional lake water circulations. The evolution of lake ice cover and near surface wind over the lake area is also reproduced by the model reasonably well. Improvements resulting from the increase of resolution from 50 to 20 km are most significant in the lake model. Overall the performance of the coupled regional climate—1D lake model system appears to be of sufficient quality for application to climate change scenario simulations over the Caspian Sea Basin.     

Options to overcome the barriers to pricing European agricultural emissions

Although agriculture could contribute substantially to European emission reductions, its mitigation potential lies untapped and dormant. Market-based instruments could be pivotal in incentivizing cost-effective abatement. However, sector specificities in transaction costs, leakage risks and distributional impacts impede its implementation. The significance of such barriers critically hinges on the dimensions of policy design. This article synthesizes the work on emissions pricing in agriculture together with the literature on the design of market-based instruments. To structure the discussion, an options space is suggested to map policy options, focusing on three key dimensions of policy design. More specifically, it examines the role of policy coverage, instruments and transfers to farmers in overcoming the barriers. First, the results show that a significant proportion of agricultural emissions and mitigation potential could be covered by a policy targeting large farms and few emission sources, thereby reducing transaction costs. Second, whether an instrument is voluntary or mandatory influences distributional outcomes and leakage. Voluntary instruments can mitigate distributional concerns and leakage risks but can lead to subsidy lock-in and carbon price distortion. Third, the impact on transfers resulting from the interaction of the Common Agricultural Policy (CAP) with emissions pricing will play a key role in shaping political feasibility and has so far been underappreciated.

POLICY RELEVANCE

Following the 2015 Paris Agreement, European climate policy is at a crossroads. Achieving cost-effectively the 2030 and 2050 European targets requires all sectors to reduce their emissions. Yet, the cornerstone of European climate policy, the European Union Emissions Trading System (EU ETS), covers only about half of European emissions. Major sectors have been so far largely exempted from carbon pricing, in particular transport and agriculture. While transport has been increasingly under the spotlight as a possible candidate for an EU ETS sectoral expansion, policy discussions on pricing agricultural emissions have been virtually absent. This article attempts to fill this gap by investigating options for market-based instruments to reduce agricultural emissions while taking barriers to implementation into account.