Bioremediation and toxicity determination of natural seawater polluted with weathered crude oil by salt-tolerant consortia in a SBR

The aim of this research was to compare the bioremediation treatment of seawater polluted with two different concentrations of weathered crude oil (0.2 for experiment (a) and 1.14% for experiment (b), v/v) by salt-tolerant consortia enriched from the sludge of a refinery wastewater treatment facility, in a SBR. The use of a commercial bioremediation stimulant (S200) was also evaluated as an alternative to the traditional nitrogen and phosphorus supplement.     

Two-dimensional modeling of fine sediment transport with mixed sediment and consolidation: Application to the Gironde Estuary,France

In order to optimize ship navigation in the macrotidal Gironde Estuary, a recent project funded by the port of Bordeaux aims at better understand and forecast hydrodynamic and fine sediment transport within the estuary. In the framework of this project, a two-dimensional hydro-sedimentary model is built. The model includes hydrodynamic forcings, mixed-sediment transport, and consolidation processes. The harmonic analysis of the astronomical tides reveals a strong distortion of the tidal wave inducing the growth of overtide constituents and the non-significant effect of tide-surge interactions in annual-scale prediction. Depending on hydrological conditions, river discharge can considerably alter the model accuracy due to the migration of the turbidity maximum zone modifying the bottom roughness. Comparison with measurements shows the ability of the model to reproduce suspended-sediment concentrations in the central Estuary. Sensitivity of the model to sediment features has also been discussed in regard of suspended-sediment concentrations and fluid mud deposits. The model will be further coupled with ship squat predictions and a morphodynamic model.     

Flow in upper-mantle rocks: Some geophysical and geodynamic consequences

Flow mechanisms effective in the upper mantle and some of the parameters of the creep equation are determined from the study of peridotites from basalt and kimberlite xenoliths and alpine-type massifs. Creep controlled by dislocation climb, as inferred by Weertman, is the dominant mechanism. Evidence for superplastic flow is found in the deepest kimberlite xenoliths. Flow in the alpine-type massifs is ascribed either to intrusion in the crust when continental plates collide (lherzolite massifs) or to sea-floor spreading (harzburgite massifs included in ophiolites). The consideration of textures, crystal substructures and preferred orientations connected with P,T equilibrium conditions derived from pyroxenes, helps in deciphering the large-scale structure and flow of peridotites in the crust and in the mantle down to 200 km. For the first 150 km, the representative structures are those of the basalt xenoliths and the kimberlite xenoliths with a coarsegrained texture. They have many features in common and probably represent a static lithosphere with, in basalt xenoliths, possible evidence for the transition to the shear flowing asthenosphere. The porphyroclastic and mosaic-textured xenoliths, in kimberlites equilibrated at depth between 150 and 200 km and a few more superficial basalt xenoliths, reflect a much larger strain rate and applied stress and might be connected to vertical instabilities also responsible for magma genesis.     

Analysis of rock drainage and cooling experiments for underground cryogenic LNG storage

Hydrogeological monitoring was conducted around a pilot cavern for underground cryogenic LNG (Liquefied Natural Gas) storage. The monitoring was mainly focused on the operation of a drainage and recharge system. After the operation of the drainage system commenced, the drainage rate decreased rapidly in the initial stages and then decreased gradually. Hydrogeological monitoring revealed that the rock drainage system operated effectively. During drainage, the water table was maintained below the cavern roof. The recharge for ice-ring formation was performed in two phases. The first phase involved the cessation of pumping in downward-drainage holes and the second involved the closure of upward boreholes. Since the water table was maintained below the cavern roof, artificial recharge was planned at first. However, it was not implemented due to heavy rainfall in the recharge stage. On the basis of hydrogeological monitoring and hydraulic tests, it was found that the fractures above the roof and on the right wall of the pilot cavern mainly affected seepage into the cavern and thermal variation due to the storage of liquid nitrogen. Thermal variation was examined by the thermometers installed around the pilot cavern. The cooling and thawing processes reveal the characteristics of thermal distribution in the rock and the 0 °C isotherm. The cooling phase lasted for six months, and the 0 °C isotherm progressed in time after the injection of liquid nitrogen into the cavern. The isotherm propagated up to about 4 m from the floor and the sidewall of the cavern and about 3 m from the cavern roof. The cooling rate of the rock mass above the cavern roof was lower than that of the other cavern sides due to the gaseous space in the upper part of the containment. The fractures were analyzed and considered for thermal modeling. A two-dimensional finite element analysis was performed to compare the field monitoring at the pilot cavern. The numerical modeling shows the distance between the ice ring and heat transfer pattern of the fractures around the pilot cavern. The propagation of the measured and calculated 0 °C isotherm reveals that the water-conveying joint on the right wall might affect thermal propagation through a thermal pipe.     

Mass‐dependent fractionation of nickel isotopes in meteoritic metal

Abstract— We measured nickel isotopes via multicollector inductively coupled plasma mass spectrometry (MC‐ICPMS) in the bulk metal from 36 meteorites, including chondrites, pallasites, and irons (magmatic and non‐magmatic). The Ni isotopes in these meteorites are mass fractionated; the fractionation spans an overall range of ～0.4‰ amu^?1. The ranges of Ni isotopic compositions (relative to the SRM 986 Ni isotopic standard) in metal from iron meteorites (～0.0 to ～0.3‰ amu^?1) and chondrites (～0.0 to ～0.2‰ amu^?1) are similar, whereas the range in pallasite metal (～–0.1 to 0.0‰ amu^?1) appears distinct. The fractionation of Ni isotopes within a suite of fourteen IIIAB irons (～0.0 to ～0.3‰ amu^?1) spans the entire range measured in all magmatic irons. However, the degree of Ni isotopic fractionation in these samples does not correlate with their Ni content, suggesting that core crystallization did not fractionate Ni isotopes in a systematic way. We also measured the Ni and Fe isotopes in adjacent kamacite and taenite from the Toluca IAB iron meteorite. Nickel isotopes show clearly resolvable fractionation between these two phases; kamacite is heavier relative to taenite by ～0.4‰ amu^?1. In contrast, the Fe isotopes do not show a resolvable fractionation between kamacite and taenite. The observed isotopic compositions of kamacite and taenite can be understood in terms of kinetic fractionation due to diffusion of Ni during cooling of the Fe‐Ni alloy and the development of the Widmanstätten pattern.     

Sedimentary evidence of deglacial megafloods in the northern Gulf of Mexico (Pigmy Basin)

Cored sediments from the Pigmy Basin, northern Gulf of Mexico, were analyzed in order to better constrain late deglacial and early Holocene paleoenvironmental and sedimentary changes in response to North American climate evolution. Mineralogical and geochemical proxies indicate the succession of two sedimentary regimes: dominantly detrital during the deglaciation (15–12.9 cal ka BP) whereas biogenic contribution relatively increased later on during the Younger Dryas and early Holocene (12.9 and 10 cal ka BP). Geochemical data reveal that the deglacial record mainly reflects variations of terrigenous supply via the Mississippi River rather than modifications of redox conditions in the basin. Specific variations of almost all the parameters measured in this paper are synchronous with the main deglacial meltwater episode (Meltwater Spike) described or modeled in previous marine or continental studies. During this episode, most parameters display “stair-step-like” – pattern variations highlighting three successive steps within the main meltwater flow. Variations in grain-size and clay mineral assemblage recorded in the Pigmy Basin indicate that the erosional regime was very strong on land during the first part of the Meltwater Spike, and then milder, inducing more subtle modifications in the sedimentary regime in this part of the Gulf. Specific geochemical and mineralogical signatures (notably, clay minerals and trace metal geochemistry) pinpoint a dominant origin from NW North America for detrital particles reflecting meltwater outflow from the south-western Laurentide Ice Sheet (LIS) margin during the most intense freshwater discharge. The observed decrease of the sedimentation rate from about 200 to 25 cm/ka at ca 12.9 ka evidenced a drastic decrease of erosional processes during late phase of discharge, consistently with the hypotheses of major reduction of meltwater flow. The major modification at 12.9 cal ka BP is interpreted to result from both modifications of the main Mississippi fluvial regime due to eastward and northward rerouting of meltwater flow at the onset of the Younger Dryas, and the increase of sea-surface temperature linked to insolation. Finally, slight grain-size modifications suggest that some freshwater discharges may have episodically reached the Gulf of Mexico after the Younger Dryas reflecting possible small adjustments of the postglacial hydrological regime.     

Properties and Comparison of Some Kriging Sub-model Aggregation Methods

Mathematical Geosciences - Kriging is a widely employed technique across computer experiments, machine learning and geostatistics. An important challenge for kriging is its high costs when dealing...     

Probing the IRC+10 ° 216 circumstellar envelope using spectroscopic observations of background stars

A unique and novel set of observations has been undertaken to study the circumstellar envelope (CSE) of the nearby (130 pc) carbon star IRC +10° 216 using optical absorption spectroscopy towards twobackground stars lying beyond the envelope.The primary aim of the observations is to search for diffuse band (DIB)carriers in the CSE. The circumstellar H+2H₂column density expected along the line of sight towards the targets islarge compared to that derived from the small interstellar reddening inthis region, E _B-V< 0.03 mag. We summarise our mainfindings, already reported in Kendall et al. (2002): The 6284Å DIB is detected in the VLT/UVES spectrum of one target, but clearly arises inthe foreground ISM. No other DIB is seen. Hence the DIB carriers, if present in the CSE, have a low abundance relative to H in the C-rich envelope of IRC +10°216, in comparison with this ratio in theISM. An important new result, previously unreported, concerns the detectionof circumstellar C₂ via absorption of the Phillips bandnear 8760Å.