Nephelines from the Somma-Vesuvius volcanic complex (Southern Italy): crystal-chemical,structural and genetic investigations

Sixteen nephelines from different geological occurrences were sampled at the type-locality, the Somma-Vesuvius volcanic complex (southern Italy), and investigated for their chemistry and crystal structure obtained by both single-crystal and powder X-ray diffraction. Nepheline-bearing samples are metamorphic or from magmatic ejecta and pumice deposits. The lower K contents characterize the pumice- and some metamorphic-derived nephelines, whereas the higher ones are found in some samples from magmatic nodules. The amount of the anorthite molecule, quite low on average, can be more variable in the metamorphic nephelines. The crystal-structure investigations on Somma-Vesuvius samples compare well with previous studies of natural nephelines. All 16 nepheline samples adopt space group P6₃. The observed lattice parameters vary between 9.9768–9.9946 Å (for a) and 8.3614–8.3777 Å (for c), respectively. Furthermore, chemical analysis revealed that all specimens exhibit an excess of Si relative the ideal Si:Al ratio of 1:1. The analysis of the T-O distances in our samples clearly indicates a distinct ordering process of aluminium and silicon on the tetrahedral sites which is an agreement with Loewenstein’s rule. A linear correlation between the distance of symmetry equivalent split atoms O(1)-O(1)’ and the T(1)-O(1)-T(2) tilt angle was observed. The average <B-O> (B = Na) distances of all crystals are very similar which is consistent with the outcome of the site population refinement indicating full occupancy with sodium. Oriented precession-type sections of reciprocal space indicated the presence of at least the most intense family of satellite peaks, demonstrating that this group of satellite reflections can occur not only in nephelines from pegmatites and ijolites but also in rocks from completely different petrological settings.     

Terrestrial laser scanner and geomechanical surveys for the rapid evaluation of rock fall susceptibility scenarios

The primary objective of this paper is to present a semiautomatic procedure that, integrated with traditional methods, can be useful for a rapid definition of rock fall susceptibility scenarios with the purpose of civil protection. Due to its morphology (steep slopes and narrow valleys), regional seismicity, and rock mass characteristics, the Nera Valley (Valnerina, Umbria Region, Italy) is characterized by high rock fall risk. With the aim of covering a wide range of features and investigating the main advantages and drawbacks of the proposed approach, data collection (terrestrial laser scanning (TLS) and geomechanical surveys) was carried out at three different slopes. Detailed three-dimensional (3D) models were created to reconstruct the shape and volume of the most unstable blocks, to define the position of the main rock fall source areas, and to precisely distinguish the outcropping materials and the position of the elements at risk for reliable runout analyses. The proposed approach can be useful in supporting proper maintenance and land management programs both in ordinary and in emergency circumstances.     

Predictive modeling for preventive Archaeology: overview and case study

The use of GIS and Spatial Analysis for predictive models is an important topic in preventive archaeology. Both of these tools play an important role in the Support Decision System (SDS) for archaeological research and for providing information useful to reduce archaeological risk. Over the years, a number of predictive models in the GIS environment have been developed and proposed. The existing models substantially differ from each other in methodological approaches and parameters used for performing the analysis. Until now, only few works consider spatial autocorrelation, which can provide more effective results. This paper provides a brief review of the existing predictive models, and then proposes a new methodological approach, applied to the neolithic sites in the Apulian Tavoliere (Southern Italy), that combines traditional techniques with methods that allow us to include spatial autocorrelation analysis to take into account the spatial relationships among the diverse sites.     

GNSS software receiver for the MAGIA (Missione Altimetrica Geofisica GeochImica lunAre) mission

In recent years a number of missions have been conceived to acquire and track signals from GPS satellites at altitudes higher than the GPS constellation itself. The main purpose of SDR is to reduce the number of hardware components, projected for specific unmodifiable uses, and utilize general purpose units: on board CPU, DSP or FPGA. In this paper he study and design of a GNSS Software Receiver for space application, applied to a Lunar Mission, is presented with particular attention on Space Segment device and on Ground Facilities.     

Cenomanian–Turonian transition in a shallow water sequence of the Sinai, Egypt

Environmental and depositional changes across the Late Cenomanian oceanic anoxic event (OAE2) in the Sinai, Egypt, are examined based on biostratigraphy, mineralogy, δ¹³C values and phosphorus analyses. Comparison with the Pueblo, Colorado, stratotype section reveals the Whadi El Ghaib section as stratigraphically complete across the late Cenomanian–early Turonian. Foraminifera are dominated by high-stress planktic and benthic assemblages characterized by low diversity, low-oxygen and low-salinity tolerant species, which mark shallow-water oceanic dysoxic conditions during OAE2. Oyster biostromes suggest deposition occurred in less than 50 m depths in low-oxygen, brackish, and nutrient-rich waters. Their demise prior to the peak δ¹³C excursion is likely due to a rising sea-level. Characteristic OAE2 anoxic conditions reached this coastal region only at the end of the δ¹³C plateau in deeper waters near the end of the Cenomanian. Increased phosphorus accumulations before and after the δ¹³C excursion suggest higher oxic conditions and increased detrital input. Bulk-rock and clay mineralogy indicate humid climate conditions, increased continental runoff and a rising sea up to the first δ¹³C peak. Above this interval, a dryer and seasonally well-contrasted climate with intermittently dry conditions prevailed. These results reveal the globally synchronous δ¹³C shift, but delayed effects of OAE2 dependent on water depth.