Molecular weight distribution,analytical and spectroscopic characterization of humic fractions sequentially isolated by organic solvents from a brown coal humic acid

A sequential fractionation procedure employing a series of selected mild organic solvents of different polarity has been applied for the isolation of chemically different organic fractions from a brown coal humic acid. Elemental composition, molecular weight distribution, i.r. and electron spin resonance analysis were carried out on the isolated humic fractions. They were characterized by: (a) a low polydispersity, (b) a decreasing aliphatic and increasing aromatic character along the series, (c) very different molecular weight which significantly correlated with E₄/E₆ ratios (particle aggregation and molecular association) and free radical concentrations (chemical and biochemical activity). Significant correlations were found between physico-chemical parameters of the isolated humic fractions, i.e. M_n, M_w, E₄/E₆ ratios, spins/g contents and the dielectric constants of the solvents used. This suggested the efficiency of the applied procedure in isolating chemically different organic fractions from the bulk, original humic acid.     

Shark interactions in pelagic longline fisheries

Substantial ecological, economic and social problems result from shark interactions in pelagic longline fisheries. Improved understanding of industry attitudes and practices towards shark interactions assists with managing these problems. Information on fisher knowledge and new strategies for shark avoidance may benefit sharks and fishers. A study of 12 pelagic longline fisheries from eight countries shows that incentives to avoid sharks vary along a continuum, based on whether sharks represent an economic disadvantage or advantage. Shark avoidance practices are limited, including avoiding certain areas, moving when shark interaction rates are high, using fish instead of squid for bait and deeper setting. Some conventionally employed fishing gear and methods used to target non-shark species contribute to shark avoidance. Shark repellents hold promise; more research and development is needed. Development of specifically designed equipment to discard sharks could improve shark post release survival prospects, reduce gear loss and improve crew safety. With expanding exploitation of sharks for fins and meat, improved data collection, monitoring and precautionary shark management measures are needed to ensure that shark fishing mortality levels are sustainable.     

The potential origins and palaeoenvironmental implications of high temporal resolution δO heterogeneity in coral skeletons

δ¹⁸O was determined at high spatial resolution (beam diameter ∼30 μm) by secondary ion mass spectrometry (SIMS) across 1-2 year sections of 2 modern Porites lobata coral skeletons from Hawaii. We observe large (>2‰) cyclical δ¹⁸O variations that typically cover skeletal distances equivalent to periods of ∼20-30 days. These variations do not reflect seawater temperature or composition and we conclude that skeletal δ¹⁸O is principally controlled by other processes. Calcification site pH in one coral record was estimated from previous SIMS measurements of skeletal δ¹¹B. We model predicted skeletal δ¹⁸O as a function of calcification site pH, DIC residence time at the site and DIC source (reflecting the inputs of seawater and molecular CO₂ to the site). We assume that oxygen isotopic equilibration proceeds at the rates observed in seawater and that only the aqueous carbonate ion is incorporated into the precipitating aragonite. We reproduce successfully the observed skeletal δ¹⁸O range by assuming that DIC is rapidly utilised at the calcification site (within 1 h) and that ∼80% of the skeletal carbonate is derived from seawater. If carbonic anhydrase catalyses the reversible hydration of CO₂ at the calcification site, then oxygen isotopic equilibration times may be substantially reduced and a larger proportion of the skeletal carbonate could be derived from molecular CO₂. Seasonal skeletal δ¹⁸O variations are most pronounced in the skeleton deposited from late autumn to winter (and coincide with the high density skeletal bands) and are dampened in skeleton deposited from spring to summer. We observed no annual pattern in sea surface temperature or photosynthetically active radiation variability which could potentially correlate with the coral δ¹⁸O. At present we are unable to resolve an environmental cue to drive seasonal patterns of short term skeletal δ¹⁸O heterogeneity.     

Fragmentation during Rock Falls: Two Italian Case Studies of Hard and Soft Rocks

In recent years, rock fall phenomena in Italy have received considerable attention for risk mitigation through in situ observations and experimental data. This paper reports the study conducted at Camaldoli Hill, in the urban area of Naples, and at Monte Pellegrino, Palermo, Italy. The rocks involved are volcanic Neapolitan yellow tuff (NYT) in the former area and dolomitic limestone in the latter. Both rocks, even though with different strength characteristics, have shown a significant tendency towards rock fragmentation during run out. This behavior was first investigated by comparing the volumes of removable blocks on the cliff faces (V ₀) and fallen blocks on the slopes (V _f). It was assumed that the ratio V _f/V ₀ decreases with the distance (x _f) from the detachment area by an empirical law, which depends on a coefficient α, correlated with the geotechnical properties of the materials involved in the rock fall. Finally, this law was validated by observation of well-documented natural rock falls (Palermo) and by in situ full-scale tests (Naples). From the engineering perspective, consideration of fragmentation processes in rock fall modeling provides a means for designing low-cost mitigation measures.     

On the prediction of the Toce alpine basin floods with distributed hydrologic models

With the objective of improving flood predictions, in recent years sophisticated continuous hydrologic models that include complex land‐surface sub‐models have been developed. This has produced a significant increase in parameterization; consequently, applications of distributed models to ungauged basins lacking specific data from field campaigns may become redundant. The objective of this paper is to produce a parsimonious and robust distributed hydrologic model for flood predictions in Italian alpine basins. Application is made to the Toce basin (area 1534 km²). The Toce basin was a case study of the RAPHAEL European Union research project, during which a comprehensive set of hydrologic, meteorological and physiographic data were collected, including the hydrologic analysis of the 1996–1997 period. Two major floods occurred during this period. We compare the FEST04 event model (which computes rainfall abstraction and antecedent soil moisture conditions through the simple Soil Conservation Service curve number method) and two continuous hydrologic models, SDM and TDM (which differ in soil water balance scheme, and base flow and runoff generation computations). The simple FEST04 event model demonstrated good performance in the prediction of the 1997 flood, but shows limits in the prediction of the long and moderate 1996 flood. More robust predictions are obtained with the parsimonious SDM continuous hydrologic model, which uses a simple one‐layer soil water balance model and an infiltration excess mechanism for runoff generation, and demonstrates good performance in both long‐term runoff modelling and flood predictions. Instead, the use of a more sophisticated continuous hydrologic model, the TDM, that simulates soil moisture dynamics in two layers of soil, and computes runoff and base flow using some TOPMODEL concepts, does not seem to be advantageous for this alpine basin. Copyright © 2006 John Wiley & Sons, Ltd.     

Middle and late Pleistocene glaciations in the Campo Felice Basin (central Apennines, Italy)

The present paper refers to research conducted in the tectonic-karst depression of Campo Felice in the central Apennines (Italy), in which glacial, alluvial and lacustrine sediments have been preserved. Stratigraphic interpretations of sediments underlying the Campo Felice Plain are based on evidence obtained from nine continuous-core boreholes. The boreholes reach a depth of 120 m and provide evidence of five sedimentation cycles separated by erosion surfaces. Each cycle is interpreted as an initial response to a mainly warm stage, characterized by low-energy alluvial and colluvial deposition, pedogenesis, and limited episodes of marsh formation. In turn, a mainly cold stage follows during which a lake formed, and glaciers developed and expanded, leading to deposition of glacial and fluvioglacial deposits. The chronological framework is established by eleven accelerator mass spectrometer ¹⁴C ages and three ³⁹Ar-⁴⁰Ar ages on leucites from interbedded tephra layers. These age determinations indicate five glacial advances that respectively occurred during marine oxygen isotope stages 2, 3-4, 6, 10 and 14.     

Examining the difficulties in letting social housing within England

This paper provides an overview of the current literature on why difficulties are being experienced in letting social housing within England. The first part of the paper focuses on whether the management of the social housing stock, and in particular the current allocation system, has contributed to the growing number of difficult to let (DTL) properties in the social sector. Drawing on findings from in-depth interviews with twenty local authorities, the paper provides evidence to support this argument and also highlights a number of initiatives which authorities have adopted to fill DTL properties. However, the paper argues that these initiatives are likely to have limited value in the long run in stemming the fall in demand for social housing, particularly in the North of England. The second part of the paper focuses on the changing aspirations of tenants and the way that social housing is in competition with alternative forms to housing provision, such as private rented housing. It concludes by advocating that an appropriate response to difficulties in letting social housing has to go beyond internal housing management initiatives. Instead a more strategic approach needs to be adopted which builds up an understanding of the operation of the local housing market and the complex interaction of neighbourhoods.     

Landslide HotSpot Mapping by means of Persistent Scatterer Interferometry

Landslide detection and mapping represent fundamental requirements for every hazard and risk evaluation and consequent improvement of the management strategies for such natural hazards. Optical and radar remote sensing can be used to observe landslide-induced ground deformation, ranging from regional to local scales. This work presents a methodology called Landslide HotSpot Mapping; this approach integrates cartographic, thematic and optical data with Persistent Scatterer Interferometry for the identification of extremely slow to very slow moving landslides, and for the evaluation of their state of activity and intensity. This methodology scans wide areas to detect hotspots, which are narrow unstable zones characterized by higher landslide hazard. To these hotspots, priority has to be given when planning field surveys and in situ validation campaigns, so that field work time and effort can be optimized and significantly reduced. The approach is tested in Central Calabria, over a 4,470?km² area located in southern Italy. ENVISAT ascending images acquired between 2003 and 2009 and processed with the Persistent Scatterer Pairs (PSP) technique are used to analyse deformation patterns. Combining conventional photo-interpretation with the analysis of PSP data, 64 new landslides are identified and the spatial (boundaries) and temporal (activity) information of 980 pre-mapped phenomena (23.6% of updated inventory) are updated. 1,012 active (continuous or reactivated) landslides are identified and 4 hotspot areas selected: San Fili, Rende, Lago, Catanzaro. Urgent field checks have to be organized for these hotspots to validate the satellite-based observations and to design appropriate mitigation measures to reduce impacts on the elements at risk.