Occurrence and fate of polycyclic aromatic hydrocarbons in the coastal surface microlayer

Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air-sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3+/-9.1 vs. 13.1+/-10.0 ng L(-1) in the dissolved phase; 709+/-207 vs. 158+/-111 ng g(-1) in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.     

A detailed study of the duality relation for the least squares adjustment in euclidean spaces

The Euclidean spaces with their inner products are used to describe methods of least squares adjustment as orthogonal projections on finite-dimensional subspaces. A unified Euclidean space approach to the least squares adjustment methods “observation equations” and “condition equations” is suggested. Hence not only the two adjustment solutions are treated from the view-point of Euclidean space theory in a unified frame but also the existing duality relation between the methods of “observation equations” and “condition equations” is discussed in full detail. Another purpose of this paper is to contribute to the development of some familiarity with Euclidean and Hilbert space concepts. We are convinced that Euclidean and Hilbert space techniques in least squares adjustment are elegant and powerful geodetic methods.     

Integrating lysimeter drainage and eddy covariance flux measurements in a groundwater recharge model

Abstract

Field-scale water balance is difficult to characterize because controls exerted by soils and vegetation are mostly inferred from local-scale measurements with relatively small support volumes. Eddy covariance flux and lysimeters have been used to infer and evaluate field-scale water balances because they have larger footprint areas than local soil moisture measurements. This study quantifies heterogeneity of soil deep drainage (D) in four 12.5-m² repacked lysimeters, compares evapotranspiration from eddy covariance (ET_EC) and mass balance residuals of lysimeters (ETwb_Lys), and models D to estimate groundwater recharge. Variation in measured D was attributed to redirection of snowmelt infiltration and differences in lysimeter hydraulic properties caused by surface soil treatment. During the growing seasons of 2010, 2011 and 2012, ETwb_Lys (278, 289 and 269 mm, respectively) was in good agreement with ET_EC (298, 301 and 335 mm). Annual recharge estimated from modelled D was 486, 624 and 613 mm for three calendar years 2010, 2011 and 2012, respectively. In summary, lysimeter D and ET_EC can be integrated to estimate and model groundwater recharge.

Editor D. Koutsoyiannis     

The Alleret maar (Massif Central, France): A new lacustrine sequence of the early Middle Pleistocene in western Europe

The Alleret maar (Massif Central, France) provides a long lacustrine sequence (40.6 m) attributed to the early Middle Pleistocene. Sediment, pollen and diatoms analysis of its upper part (AL2 core, 14.6 m) indicates two temperate phases marked by high lake levels, forest development and vegetation expansion. They are separated by a cold period during which lake level drops, coarse sediment input increases and steppic and xerophilous plants develop. Pollen data suggests that this sequence belongs to the upper part of the Cromerian complex. These results are in agreement with the 557 ± 3 ka (±12 ka, including all errors) ⁴⁰Ar/³⁹Ar age obtained from an interbedded tephra layer emitted by the Mont-Dore/Sancy strato-volcano and establish that this sequence probably covers the MIS 15 substages.     

Historical Climatology In Europe – The State Of The Art

This paper discusses the state of European research in historical climatology. This field of science and an overview of its development are described in detail. Special attention is given to the documentary evidence used for data sources, including its drawbacks and advantages. Further, methods and significant results of historical-climatological research, mainly achieved since 1990, are presented. The main focus concentrates on data, methods, definitions of the “Medieval Warm Period” and the “Little Ice Age”, synoptic interpretation of past climates, climatic anomalies and natural disasters, and the vulnerability of economies and societies to climate as well as images and social representations of past weather and climate. The potential of historical climatology for climate modelling research is discussed briefly. Research perspectives in historical climatology are formulated with reference to data, methods, interdisciplinarity and impacts.     

Olivine in ultramafic lamprophyres: chemistry,crystallisation, and melt sources of Siberian Pre- and post-trap aillikites

We studied olivines from the Devonian pre-trap (the Ilbokich occurrence) and the Triassic post-trap (the Chadobets occurrence) carbonate-rich ultramafic lamprophyres (UMLs) in the southwestern portion of the Siberian craton. On the basis of detailed investigations of major, minor, and trace-element distributions, we have reconstructed the main processes that control the origins of these olivines. These include fractional crystallisation from melt, assimilation, and fractional crystallisation processes with orthopyroxene assimilation, melt-reaction diffusive re-equilibration, alkali enrichment, and CO₂ degassing of the melt. Furthermore, we inferred the composition of the sources of the primary UML melt and their possible correlations with proto-kimberlitic melts, as well as the influence of the Triassic Siberian plume on the composition of the lithospheric mantle. The main differences between olivines from the Ilbokich and the Chadobets aillikites were that the olivines from the former had more magnesium-rich cores (Mg# = 89.2?±?0.2), had Mg- and Cr-rich transition zones (Mg# = 89.7?±?0.2 and 300–500 ppm Cr), had lower Ni (up to 3100 ppm) and Li (1.4–1.5 ppm), and had higher B (0.8–2.6 ppm) contents, all at higher Fo values (90–86), relative to the olivines from the latter (Mg# = 88–75; 200–300 ppm Cr; up to 3400 ppm Ni; 1.4–2.4 ppm Li; 0.4–2.2 ppm B). The Siberian aillikite sources contained a significant amount of metasomatic material. Phlogopite-rich MARID-type veins provided the likely metasomatic component in the pre-trap Devonian Ilbokich aillikite source, whereas the Triassic Chadobets aillikitic post-trap melts were derived from a source with a significant carbonate component. A comparison of UML olivines with olivines from the pre-trap and post-trap Siberian kimberlites shows a striking similarity. This suggests that the carbonate component in the aillikitic source could have been produced by evolved kimberlite melts. The differences in the lithospheric metasomatic component that contributed to pre-trap and post-trap aillikitic melts can be interpreted as reflections of the thermal impact of the Siberian Traps, which reduced phlogopite-bearing metasomes within the southwestern Siberian sub-continental lithospheric mantle.     

Stable Atmospheric Boundary-Layer Experiment in Spain (SABLES 98): A Report

This paper describes the Stable AtmosphericBoundary Layer Experiment in Spain (SABLES 98),which took place over the northern Spanish plateaucomprising relatively flat grassland,in September 1998. The main objectives of the campaign were to study the properties of themid-latitude stable boundary layer (SBL).Instrumentation deployed on two meteorologicalmasts (of heights 10 m and 100 m)included five sonic anemometers, 15 thermocouples,five cup anemometers and three propeller anemometers,humidity sensors and radiometers.A Sensitron mini-sodar and a tetheredballoon were also operated continuously. Atriangular array of cup anemometers wasinstalled to allow the detection ofwave events. Two nocturnal periods analysedon 14–15 and 20–21 September are used toillustrate the wide-ranging characteristics of the SBL.     

A combined study of macroseismic data and focal mechanisms applied to the West-Bohemian earthquake,Czechoslovakia

The main shock of the West-Bohemian earthquake swarm, Czechoslovakia, (magnitudem=4.5, depthh=10 km) exhibits an irregular areal distribution of macroseismic intensities 6° to 7° MSK-64. Four lobes of the 6° isoseismal are found and the maximum observed intensity is located at a distance of 8 km from the instrumentally determined epicentre. This distribution can be explained by the energy flux of the directS wave generated by a circular source, the hypocentral location and focal mechanism of which are taken from independent instrumental studies. The theoretical intensity, which is assumed to be logarithmically proportional to the integrated squared ground-motion velocity (i.e.,I=const+log v ² (t)dt), fits the observed intensity with an overall root-mean-square error less than 0.5°. It is important that the present intensity data can also be equally well explained by the isotropic source. The fit was attained by means of a horizontally layered model though large fault zones and an extended sedimentary basin suggest a significant lateral heterogeneity of the epicentral region. The results encourage a broader application of the simple modelling technique used.     

Bringing globalization to the countryside: Special Economic Zones in India

Special Economic Zones (SEZs) are important vectors of neoliberal globalization in India. Despite facing widespread resistance against the proposed land acquisition for these zones, they are still being promoted across the country. We argue that the wealth redistribution to the country's elites and the fractured resistance movements enable neoliberalism and its practices to grow in the countryside. Using a private sector SEZ in Gurgaon as a case study, this article explores how special economic zoning, as a neoliberal policy, has been implicated in the spatialized production of poverty. We also show that the main actors who promote neoliberalism in India (the state and the large‐scale urban private sector) have found a seemingly unlikely ally in rural India in the form of farmers with large landholdings, rural elites who are willing to let go of their land under certain conditions. The data for the article was collected in India in 2009–10.