铁同位素的MC-ICP-MS测定方法与地质标准物质的铁同位素组成

详细报道了在低分辨和高分辨模式下运用MC-ICP-MS进行Fe同位素比值高精度测试的方法,对Fe同位素测定过程中谱峰干扰、基质效应、浓度效应、仪器测试的长期重现性等问题进行了评估,并对两种运行模式的测试结果进行了对比.在95%的可信度范围内,所建方法的外部精度优于0.5ε/ainu,达到国际同类实验室的先进水平,并且低分辨和高分辨两种模式下获得的Fe同位素测试结果是一致的.在此基础上对国家地质标准物质GBW07105(玄武岩)和GBW 07111(花岗闪长岩)进行了Fe同位素测定.相对于Fe同位素国际标样IRMM-014,GBW07105的Fe同位素成分为:ε57Fe=1.9±0.3(20),ε56Fe=1.3±0.2(2σ),ε57/56Fe=0.6±0.1(2σ);GBW 07111的Fe同位素成分为:ε57Fe=1.8±0.4(2σ),ε56Fe=1.2±0.2(2σ),ε57/56Fe=0.6±0.1(2σ).     

Neoglacial (<3000 years) till and flutes at Saskatchewan Glacier,Canadian Rocky Mountains,formed by subglacial deformation of a soft bed

Understanding the processes that deposit till below modern glaciers provides fundamental information for interpreting ancient subglacial deposits. A process‐deposit‐landform model is developed for the till bed of Saskatchewan Glacier in the Canadian Rocky Mountains. The glacier is predominantly hard bedded in its upper reaches and flows through a deep valley carved into resistant Palaeozoic carbonates but the ice margin rests on a thick (<6 m) soft bed of silt‐rich deformation till that has been exposed as the glacier retreats from its Little Ice Age limit reached in 1854. In situ tree stumps rooted in a palaeosol under the till are dated between ca 2900 and 2700 yr bp and record initial glacier expansion during the Neoglacial. Sedimentological and stratigraphic observations underscore the importance of subglacial deformation of glaciofluvial outwash deposited in front of the advancing glacier and mixing with glaciolacustrine carbonate‐rich silt to form a soft bed. The exposed till plain has a rolling drumlinoid topography inherited from overridden end moraines and is corrugated by more than 400 longitudinal flute ridges which record deformation of the soft bed and fall into three genetically related types: those developed in propagating incipient cavities in the lee of large subglacial boulders embedded in deformation till, and those lacking any originating boulder and formed by pressing of wet till up into radial crevasses under stagnant ice. A third type consists of U‐shaped flutes akin to barchan dunes; these wrap around large boulders at the downglacier ends of longitudinal scours formed by the bulldozing of boulders by the ice front during brief winter readvances across soft till. Pervasive subglacial deformation during glacier expansion was probably facilitated by large boulders rotating within the soft bed (‘glacioturbation’).     

新疆西天山高硫化型京希-伊尔曼德金矿床的识别标志及其找矿意义

经过详细的野外地质勘查、热液蚀变及蚀变矿物学研究，流体包裹体和同位素研究，首次将西天山京希－伊尔曼德金矿床确定为高硫化型浅成低温热液金矿床。该矿床的主要识别标志为：发育以多孔状石英为特征的硅化蚀变带和高级泥化蚀变带；成矿流体性质为低盐度[W(NaCl)为0.3-4.2%]、低pH值（3－4）和高氧化态；氧同位素δ（^18O)为1.7 ‰-4.3‰,δ(D)为－60‰--80‰。金主要富集在高级泥化带和中心硅化蚀变带内。系统研究和总结了成矿地质－地球化学制约因素以及区域、靶区和勘探区尺度的找矿标志。     

The Seasonal Prediction of the Exceptional Yangtze River Rainfall in Summer 2020

During June and July of 2020, the Yangtze River basin suffered from extreme mei-yu rainfall and catastrophic flooding. This study explores the seasonal predictability and associated dynamical causes for this extreme Yangtze River rainfall event, based on forecasts from the Met Office GloSea5 operational forecast system. The forecasts successfully predicted above-average rainfall over the Yangtze River basin, which arose from the successful reproduction of the anomalous western North Pacific subtropical high (WNPSH). Our results indicate that both the Indian Ocean warm sea surface temperature (SST) and local WNP SST gradient were responsible for the westward extension of the WNPSH, and the forecasts captured these tropical signals well. We explore extratropical drivers but find a large model spread among the forecast members regarding the meridional displacements of the East Asian mid-latitude westerly jet (EAJ). The forecast members with an evident southward displacement of the EAJ favored more extreme Yangtze River rainfall. However, the forecast Yangtze River rainfall anomaly was weaker compared to that was observed and no member showed such strong rainfall. In observations, the EAJ displayed an evident acceleration in summer 2020, which could lead to a significant wind convergence in the lower troposphere around the Yangtze River basin, and favor more mei-yu rainfall. The model forecast failed to satisfactorily reproduce these processes. This difference implies that the observed enhancement of the EAJ intensity gave a large boost to the Yangtze River rainfall, hindering a better forecast of the intensity of the event and disaster mitigation.     

Predicting June Mean Rainfall in the Middle/Lower Yangtze River Basin

We demonstrate that there is significant skill in the GloSea5 operational seasonal forecasting system for predicting June mean rainfall in the middle/lower Yangtze River basin up to four months in advance. Much of the rainfall in this region during June is contributed by the mei-yu rain band. We find that similar skill exists for predicting the East Asian summer monsoon index(EASMI) on monthly time scales, and that the latter could be used as a proxy to predict the regional rainfall. However, th...     

Understanding historical coastal spit evolution: A case study from Spurn,East Yorkshire,UK

Globally sandy coastlines are threatened by erosion driven by climatic changes and increased storminess. Understanding how they have responded to past storms is key to help manage future coastal changes. Coastal spits around the world are particularly dynamic and therefore potentially vulnerable coastal features. Therefore, how they have evolved over the last few centuries is of great importance. To illustrate this, this study focuses on the historical evolution of a spit at Spurn on the east coast of the UK, which currently provides critical protection to settlements within the Humber estuary. Through the combination of digitized historical mapping and luminescence dating, this study shows that Spurn has been a consistent coastal feature over at least the past 440 years. No significant westward migration was observed for the last 200 years. Results show a long-term extension of the spit and a decrease in its overall area, particularly in the last 50 years. Breaches of the neck cause temporary sediment pathway changes enabling westward extension of the head. Use of digitized historical maps in GIS combined with OSL dating has allowed a more complete understanding of long-term spit evolution and sediment transport modes at Spurn. In doing so it helps inform future possible changes linked to pressures, such as increases in storm events and sea-level rise. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Regional magma plumbing and emplacement mechanisms of the Faroe‐Shetland Sill Complex: implications for magma transport and petroleum systems within sedimentary basins

The movement of magma through the shallow crust and the impact of subsurface sill complexes on the hydrocarbon systems of prospective sedimentary basins has long been an area of interest and debate. Based on 3D seismic reflection and well data, we present a regional analysis of the emplacement and magmatic plumbing system of the Palaeogene Faroe‐Shetland Sill Complex (FSSC), which is intruded into the Mesozoic and Cenozoic sequences of the Faroe‐Shetland Basin (FSB). Identification of magma flow directions through detailed seismic interpretation of approximately 100 sills indicates that the main magma input zones into the FSB were controlled primarily by the NE–SW basin structure that compartmentalise the FSB into its constituent sub‐basins. An analysis of well data shows that potentially up to 88% of sills in the FSSC are <40 m in thickness, and thus below the vertical resolution limit of seismic data at depths at which most sills occur. This resolution limitation suggests that caution needs to be exercised when interpreting magmatic systems from seismic data alone, as a large amount of intrusive material could potentially be missed. The interaction of the FSSC with the petroleum systems of the FSB is not well understood. Given the close association between the FSSC and potential petroleum migration routes into some of the oil/gas fields (e.g. Tormore), the role the intrusions may have played in compartmentalisation of basin fill needs to be taken fully into account to further unlock the future petroleum potential of the FSB.     

Application of infrared thermography for temperature distributions in fluid-saturated porous media

Infrared thermography has increasingly gained importance because of environmental and technological advancements of this method and is applied in a variety of disciplines related to non-isothermal flow. However, it has not been used so far for quantitative thermal analysis in saturated porous media. This article suggests infrared thermographic approach to obtain the entire surface temperature distribution(s) in water-saturated porous media. For this purpose, infrared thermal analysis is applied with in situ calibration for a better understanding of the heat transfer processes in porous media. Calibration is achieved with a combination of invasive sensors which are inserted into the medium and non-invasive thermal sensors in which sensors are not inserted to measure temperatures but it works through the detection of infrared radiation emitted from the surface. Thermocouples of relatively thin diameter are used to minimize the disturbance for flow. Thermocouples give the temperature values at specified positions inside the porous medium, and these values are compared with the values suggested by the infrared thermographic device at the same positions, in the calibration exercise. The calibration process was repeated for different temperatures and flow rates to get the temperature distributions of the whole material inside the system. This technique enables us to measure accurate two-dimensional temperature distributions, which is not possible by using thermocouples only. Continuous point heat sources at different flow rates and temperatures are studied experimentally. Additionally, it offers numerical simulations of the experiments utilizing a finite element-based model. A two-dimensional density and viscosity-dependent flow and transport model accounting for thermal dispersion is utilized to simulate the experimental results. Possible small heat losses from the surface are incorporated in the model according to the properties and thickness of the Plexiglass material used for the construction of the experiment tank. The numerical results agree well with the experimental observations.     

Tectonic significance of syn-rift sediment packages across the Gabon-Cabinda continental margin

The tectonic development of a continental margin is recorded in the stratigraphic successions preserved along and across the margin in terms of stratal relationships (e.g., onlap, downlap, truncation), lithofacies, biostratigraphy, and paleo-water depths. By using these observations coupled to a kinematic and flexural model for the deformation of the lithosphere, we have elucidated the tectonic significance of the preserved stratigraphy that comprises the Gabon-Cabinda margin of west Africa. Two hinge zones, an Eastern and Atlantic, formed along the Gabon-Cabinda margin in response to three discrete extensional events occuring from Berriasian to Aptian time. The Eastern hinge zone demarcates the eastern limit of a broadly distributed Berriasian extension that resulted in the formation of deep anoxic, lacustrine systems as evidenced by the silts and shales of the Sialivakou and lower Djeno Formations and the regressive packages of the upper Djeno Formation. Approximately 1.5 to 2 km of asymmetric footwall uplift was induced across the Eastern hinge zone in response to the mechanical unloading of the lithosphere during this first phase of rifting. In contrast, the Atlantic hinge, located approximately 90 km west of the Eastern hinge, marks the eastern limit of a second phase of extension that began in the Hauterivian. Footwall uplift and rotation exposed earlier syn-rift and pre-rift sediments to at least wavebase causing varying amounts of erosional truncation across the Atlantic hinge zone along much of the Gabon-Cabinda margins. We interpret the thickness variations of reworked clastic sediment of this age (e.g. the Melania Formation) between the hinge zones as indicative of variations in the degree of uplift and erosional truncation of the Atlantic hinge. For example, the absence of Melania Formation across the Congo margin implies that uplift of the Atlantic hinge was relatively minor compared to that across the Cabinda and Gabon margins, the latter being characterized by significant thicknesses of Melania Formation (or equivalent). Material eroded from the Cabinda and Gabon Atlantic hinge zone may in part account for the thick wedge of sediment deposited seaward of the Gabon-Cabinda Atlantic hinge (the Erva Formation). Our modelling suggests that this wedge of reworked elastics represents deposition by along-axis gravity flows within a deep water (≈2 km) environment. A third and final phase of extension in the late Barremian-early Aptian was responsible for breaching the continental lithosphere to form the ocean/continent boundary and thus the installation of open marine conditions. Elsewhere, the environments will tend to be marginal marine to brackish, depending on the efficiency of the Atlantic hinge zone to act as a barrier to marine enchroachment. This third rift phase reactivated both the Eastern and Atlantic hinge0zones thereby creating accomodation for the Marnes Noires Formation (and equivalent) source rock deposition between the hinges and the Falcão source rock equivalent seaward of the Atlantic hinge. Two possible scenarios exist for the lateral distribution of the Marnes Noires Formation. If the reactivated rift flank topography across the Atlantic hinge was significant, then sedimentation would be restricted between the hinge zones within discrete lacustrine settings (e.g., Congo margin). Alternatively, if hinge zone uplift was relatively minor, then a coral-rimmed archipelago may have developed parallel to the margin with restricted communication across the Atlantic hinge zone (e.g., Cabinda margin). In this latter scenario, dilution of the Marnes Noires source rocks by terrigenous input from the eroding Atlantic hinge zone should be relatively minor thereby enhancing source rock quality. Furthermore, potential marine upwelling outboard of the Atlantic hinge zone is likely the cause for the production and accumulation of organic-rich material associated with the Falcão source rock of the Kwanza basin. By late Aptian time, the remaining accomodation between the hinge zones was partially filled by across- and along-axis prograding deltaic systems of the Argilles Vertes and Tchibota Formations. The progradation and interaction of the Argilles Vertes depositional lobes resulted in the formation of residual paleo-relief. Subsequent marine incursions and flooding of this paleo-relief led to the development of basal conglomerates (the Chela ‘lag’ unconformity) grading upward into fine-grained sands and evaporites. Consequently, an inverse relationship should exist betweeb evaporite thickness (in particular, the lower members) and the thickness of the underlying Argilles Vertes and Tchibota Formations. Variations in Loeme evaporite thickness is a consequence of stratigraphic and structural control with salt instability influencing local variability.Our modelling suggests the occurrence of two distinct evaporite sequences on the Congo margin, an earlier evaporite deposited seaward (west) of the Atlantic hinge during the second and third rift phases and the late Aptian Loeme Formation deposited between the hinge zones. An evaporite sequence seaward of the Atlantic hinge is inferred on the basis of extensive diapirs and salt tectonic structures observed in seismic data. In order to match the distribution and thickness of the observed post-salt stratigraphy across the basin, however, we require large paleowater depths west of the Atlantic hinge during the later Aptian. The existence of large paleowater depths precludes the formation of thick evaporite sequences within the outer basin. Consequently, we propose that the evaporites seaward of the Atlantic hinge were formed during the syn-rift development of the margin and are not contemporaneous with the post-rift Loeme salts deposited between the hinge zones. This double salt hypothesis is consistent with observations from the conjugate Brazilian margin.