Canadian Shield brine from the Con Mine, Yellowknife, NT, Canada: Noble gas evidence for an evaporated Palaeozoic seawater origin mixed with glacial meltwater and Holocene recharge

Dissolved noble gas concentrations were measured in high salinity (270 g/L) Ca(Na)-Cl groundwaters from the Con Mine, Yellowknife, Canada in an effort to discriminate between two possible origins, as either a brine generated by evaporative enrichment in a Paleozoic inland sea, or marine water concentrated by freezing during glacial times. Major ion and isotope geochemistry indicate that brines from the deepest level remain relatively undisturbed by mixing with modern water introduced by mining. Mixing calculations are used to quantify fractions of brine, glacial meltwater and modern water. From this, noble gas concentrations were corrected for excess air with Ne and normalized to 100% brine solution. Over-pressuring of helium and argon in the brine provide age constraints based on the accumulation of geogenic ⁴He and ⁴⁰Ar. Radiogenic age calculations together with the local geological history suggest brine emplacement during early Palaeozoic time, likely during the Devonian when evaporitic inland seas existed in this region. The concentrations of the atmospherically derived noble gases in the brine fraction (Kr = 1.4E-8, Xe = 8.5E-10 cc_STP/cc_H2O) are close to atmospheric equilibrium for brine at 25 °C (Kr = 7.3E-9, Xe = 8.0E-10 cc_STP/cc_H2O), but are far lower than would be expected for closed-system concentration of seawater by freezing (Kr = 2.8E-6, Xe = 4.2E-7 cc_STP/cc_H2O). Thus, despite the complicated mixing history of the brine, the atmospheric and geogenic noble gases provide strong evidence for an origin as air-equilibrated brine from evaporated Paleozoic seawater, which infiltrated via density displacement through existing fractures and faults into the Canadian Shield.     

Slowing things down: Lessons from the GM controversy

This paper stages an encounter between one strand of the controversy around genetically modified food crops and some conceptual resources from the field of science and technology studies, with the aim of illuminating the relationship between science and politics. Contrary to some suggestions, it is argued that the spatial, temporal and material imagination encapsulated in the figure of Progress remains central to their contemporary articulation. Best described as an ‘anti-political’ strategy, Progress does not leave room for anything else but one story of the world. Through following the attempts of both scientists in the field and protestors on the streets to make public some of the trajectories which this story leaves out, what emerges is the possibility of an alternative to Progress that is not based simply on its rejection. Instead, such efforts offer resources for inventing another way of collectively going forward which chime with some more theoretical attempts to elaborate how things might be productively ‘slowed down’. An example of how government was forced to construct a way of dealing with things that is more adequate and appropriate to life in a full world is compared with Bruno Latour’s model of due process for nonhumans, before some conclusions are drawn about whether we should be depressed or hopeful about our ability to move on in the lights of such attempts.     

Seasonal Forecasts of the Summer 2016 Yangtze River Basin Rainfall

The Yangtze River has been subject to heavy flooding throughout history,and in recent times severe floods such as those in 1998 have resulted in heavy loss of life and livelihoods.Dams along the river help to manage flood waters,and are important sources of electricity for the region.Being able to forecast high-impact events at long lead times therefore has enormous potential benefit.Recent improvements in seasonal forecasting mean that dynamical climate models can start to be used directly for operational services.The teleconnection from El Ni ?no to Yangtze River basin rainfall meant that the strong El Ni ?no in winter 2015/16 provided a valuable opportunity to test the application of a dynamical forecast system.This paper therefore presents a case study of a real-time seasonal forecast for the Yangtze River basin,building on previous work demonstrating the retrospective skill of such a forecast.A simple forecasting methodology is presented,in which the forecast probabilities are derived from the historical relationship between hindcast and observations.Its performance for2016 is discussed.The heavy rainfall in the May–June–July period was correctly forecast well in advance.August saw anomalously low rainfall,and the forecasts for the June–July–August period correctly showed closer to average levels.The forecasts contributed to the confidence of decision-makers across the Yangtze River basin.Trials of climate services such as this help to promote appropriate use of seasonal forecasts,and highlight areas for future improvements.     

The market(able) place of school geography scholarship, 2007–2016

This report analyses a decade of geography scholarship student entry and achievement data (n = 10,205) to reveal patterns and trends of high‐achieving school students. The study is an exploratory analysis, the aim of which is to describe where the greatest scholarship success has occurred, as well as attendant demographic characteristics of New Zealand's most capable geography students and their schools. Emerging from the regions is a localised story of students from an extremely narrow number of schools achieving disproportionate scholarship success. This raises questions in the wider geography teaching community about the possibility of a broader constituency achieving scholarship awards.     

The skeleton of a straight-tusked elephant,Palaeoloxodon antiquus (Falconer and Cautley, 1847) from Selsey,England, and growth and variation in Palaeoloxodon of the European Pleistocene

A partial skeleton of straight-tusked elephant (Palaeoloxodon antiquus) excavated at Selsey beach (Sussex, UK) in 1961 is one of very few from Marine Isotope Stage 7 (MIS 7), ca. 240–200 ka, in Europe. Dental morphometrics, including X-ray micro-computed tomography, confirms the species identification. Age determination through dental wear and skeletal morphology, sex determination through pelvic anatomy, and body-size measurements, together identify the individual as a female of approximately 30 years old with a live shoulder height of ca. 3 m and a body mass of ca. 5 t. Dental mesowear indicates mixed feeding with a significant proportion of grass, indicating selective feeding in a predominately forested environment. Although taphonomic conclusions are limited by the nature of the excavation, identification of 107 recovered skeletal elements indicates predominant preservation of the right side of the animal, suggesting death or burial on the right side in a shallow, slow-moving freshwater environment, with possible removal of other elements by scavenging or decay. Combining the Selsey data with 29 comparative skeletons from across Europe, we demonstrate the validity of pelvic proportions for determining sex and provide a graphical representation of variation and growth rate in males and females of this species.     

Timing of the first drainage of the Baltic Ice Lake synchronous with the onset of Greenland Stadial 1

Glacial varves can give significant insights into recession and melting rates of decaying ice sheets. Moreover, varve chronologies can provide an independent means of comparison to other annually resolved climatic archives, which ultimately help to assess the timing and response of an ice sheet to changes across rapid climate transitions. Here we report a composite 1257‐year‐long varve chronology from southeastern Sweden spanning the regional late Allerød–late Younger Dryas pollen zone. The chronology was correlated to the Greenland Ice‐Core Chronology 2005 using the time‐synchronous Vedde Ash volcanic marker, which can be found in both successions. For the first time, this enables secure placement of the Lateglacial Swedish varve chronology in absolute time. Geochemical analysis from new varve successions indicate a marked change in sedimentation regime accompanied by an interruption of ice‐rafted debris deposition synchronous with the onset of Greenland Stadial 1 (GS‐1; 12 846 years before AD 1950). With the support of a simple ice‐flow/calving model, we suggest that slowdown of sediment transfer can be explained by ice‐sheet margin stabilization/advance in response to a significant drop of the Baltic Ice Lake level. A reassessment of chronological evidence from central‐western and southern Sweden further supports the hypothesis of synchronicity between the first (penultimate) catastrophic drainage of the Baltic Ice Lake and the start of GS‐1 in Greenland ice‐cores. Our results may therefore provide the first chronologically robust evidence linking continental meltwater forcing to rapid atmosphere–ocean circulation changes in the North Atlantic.     

The space environment of Mercury at the times of the second and third MESSENGER flybys

The second and third flybys of Mercury by the MESSENGER spacecraft occurred, respectively, on 6 October 2008 and on 29 September 2009. In order to provide contextual information about the solar wind properties and the interplanetary magnetic field (IMF) near the planet at those times, we have used an empirical modeling technique combined with a numerical physics-based solar wind model. The Wang–Sheeley–Arge (WSA) method uses solar photospheric magnetic field observations (from Earth-based instruments) in order to estimate the inner heliospheric radial flow speed and radial magnetic field out to 21.5 solar radii from the Sun. This information is then used as input to the global numerical magnetohydrodynamic model, ENLIL, which calculates solar wind velocity, density, temperature, and magnetic field strength and polarity throughout the inner heliosphere. WSA-ENLIL calculations are presented for the several-week period encompassing the second and third flybys. This information, in conjunction with available MESSENGER data, aid in understanding the Mercury flyby observations and provide a basis for global magnetospheric modeling. We find that during both flybys, the solar wind conditions were very quiescent and would have provided only modest dynamic driving forces for Mercury's magnetospheric system.     

Investigation of iron sulfide impact crater residues: A combined analysis by scanning and transmission electron microscopy

Abstract– Samples returned from comet 81P/Wild 2 by the Stardust mission provided an unequaled opportunity to compare previously available extraterrestrial samples against those from a known comet. Iron sulfides are a major constituent of cometary grains commonly identified within cometary interplanetary dust particles (IDPs) and Wild 2 samples. Chemical analyses indicate Wild 2 sulfides are fundamentally different from those in IDPs. However, as Wild 2 dust was collected via impact into capture media at approximately 6.1 km s^?1, it is unclear whether this is due to variation in preaccretional/parent body processes experienced by these materials or due to heating and alteration during collection. We investigated alteration in pyrrhotite and pentlandite impacted into Stardust flight spare Al foils under encounter conditions by comparing scanning and transmission electron microscope (SEM, TEM) analyses of preimpact and postimpact samples and calculating estimates of various impact parameters. SEM is the primary method of analysis during initial in situ examination of Stardust foils, and therefore, we also sought to evaluate the data obtained by SEM using insights provided by TEM. We find iron sulfides experience heating, melting, separation, and loss of S, and mixing with molten Al. These results are consistent with estimated peak pressures and temperatures experienced (approximately 85 GPa, approximately 2600 K) and relative melting temperatures. Unambiguous identification of preserved iron sulfides may be possible by TEM through the location of Al‐free regions. In most cases, the Ni:Fe ratio is preserved in both SEM and TEM analyses and may therefore also be used to predict original chemistry and estimate mineralogy.     

Vertical abundance profiles of hydrocarbons in Titan's atmosphere at 15° S and 80° N retrieved from Cassini/CIRS spectra

Limb spectra recorded by the Composite InfraRed Spectrometer (CIRS) on Cassini provide information on abundance vertical profiles of C₂H₂, C₂H₄, C₂H₆, CH₃C₂H, C₃H₈, C₄H₂, C₆H₆ and HCN, along with the temperature profiles in Titan's atmosphere. We analyzed two sets of spectra, one at 15° S (Tb flyby) and the other one at 80° N (T3 flyby). The spectral range 600-1400 cm⁻¹, recorded at a resolution of 0.5 cm⁻¹, was used to determine molecular abundances and temperatures in the stratosphere in the altitude range 100-460 km for Tb and 170-495 km for T3. Both temperature profiles show a well defined stratopause, at around 310 km (0.07 mbar) and 183 K at 13° S, and 380 km (0.01 mbar) with 207 K at 80° N. Near the north pole, stratospheric temperatures are colder and mesospheric temperatures are warmer than near the equator. C₂H₂, C₂H₆, C₃H₈ and HCN display vertical mixing ratio profiles that increase with height at 15° S and 80° N, consistent with their formation in the upper atmosphere, diffusion downwards and condensation in the lower stratosphere, as expected from photochemical models. The CH₃C₂H and C₄H₂ mixing ratios also increase with height at 15° S. But near the north pole, their profiles present an unexpected minimum around 300 km, observed for the first time thanks to the high vertical resolution of the CIRS limb data. C₂H₄ is the only molecule having a vertical abundance profile that decreases with height at 15° S. At 80° N, it also displays a minimum of its mixing ratio around the 0.1-mbar level. For C₆H₆, an upper limit of 1.1 ppb (in the 0.3-10 mbar range) is derived at 15° S, whereas a constant mixing ratio profile of is inferred near the north pole. At 15° S, the vertical profile of HCN exhibits a steeper gradient than other molecules, which suggests that a sink for this molecule exists in the stratosphere, possibly due to haze formation. All molecules display a more or less pronounced enrichment towards the north pole, probably due, in part, to subsidence of air at the north (winter) pole that brings air enriched in photochemical compounds from the upper atmosphere to lower levels.