铁同位素的MC-ICP-MS测定方法与地质标准物质的铁同位素组成

详细报道了在低分辨和高分辨模式下运用MC-ICP-MS进行Fe同位素比值高精度测试的方法,对Fe同位素测定过程中谱峰干扰、基质效应、浓度效应、仪器测试的长期重现性等问题进行了评估,并对两种运行模式的测试结果进行了对比.在95%的可信度范围内,所建方法的外部精度优于0.5ε/ainu,达到国际同类实验室的先进水平,并且低分辨和高分辨两种模式下获得的Fe同位素测试结果是一致的.在此基础上对国家地质标准物质GBW07105(玄武岩)和GBW 07111(花岗闪长岩)进行了Fe同位素测定.相对于Fe同位素国际标样IRMM-014,GBW07105的Fe同位素成分为:ε57Fe=1.9±0.3(20),ε56Fe=1.3±0.2(2σ),ε57/56Fe=0.6±0.1(2σ);GBW 07111的Fe同位素成分为:ε57Fe=1.8±0.4(2σ),ε56Fe=1.2±0.2(2σ),ε57/56Fe=0.6±0.1(2σ).     

Radar Backscatter from Underdense Meteors and Diffusion Rates

Many meteoroids burn up between about 120 km and 70 km, deposit metals and dust and form ionized trails which are detected by radars. Model studies about the influence of neutral or positively charged background dust on the ambipolar diffusion indicate that significant smaller decay times should be observed for weak meteor echoes compared to strong meteor echoes which can affect the estimation of temperatures. The variation of meteor decay times in dependence on echo strength, height, and season was studied using radar observations at 69° N, 22° S, and 67° S. Significantly reduced decay times were found for weak echoes below about 88 km at low latitudes throughout the year, and at high latitudes with the exception of summer. In summer at high latitudes, decreasing decay times of weak and strong meteors are observed at altitudes below about 85 km during the appearance of noctilucent clouds. The impact of reduced decay times on the estimation of neutral temperatures from decay times is discussed.     

Interactions between river flows and colonizing vegetation on a braided river: exploring spatial and temporal dynamics in riparian vegetation cover using satellite data

Field, laboratory, and numerical modelling research are increasingly demonstrating the potential of riparian tree colonization and growth to influence fluvial dynamics and the evolution of fluvial landforms. This paper jointly analyses multi‐temporal, multispectral ASTER data, continuous river stage and discharge data, and field observations of the growth rates of the dominant riparian tree species (Populus nigra) along a 21 km reach of the Tagliamento River, Italy. Research focuses on the period 2004–2009, during which there was a bankfull flood on 24 October 2004, followed by 2 years with low water levels, nearly 2 years with only modest flow pulses, and then a final period from 15 August 2008 that included several intermediate to bankfull flow events. This study period of increasing flow disturbance allows the exploration of vegetation dynamics within the river's active corridor under changing flow conditions. The analysis demonstrates the utility of ASTER data for investigating vegetation dynamics along large fluvial corridors and reveals both spatial and temporal variations in the expansion, coalescence, and erosion of vegetated patches within the study reach. Changes in the extent of the vegetated area and its dynamics vary along the study reach. In sub‐reaches where riparian tree growth is vigorous, the vegetated area expands rapidly during time periods without channel‐shaping flows, and is subsequently able to resist erosion by bankfull floods. In contrast, in sub‐reaches where tree growth is less vigorous, the vegetated area expands at a slower rate and is more readily re‐set by bankfull flood events. This illustrates that the rate of growth of riparian trees is crucial to their ability to contribute actively to river corridor dynamics. Copyright © 2011 John Wiley & Sons, Ltd.     

Archean to Recent aeolian sand systems and their sedimentary record: Current understanding and future prospects

The sedimentary record of aeolian sand systems extends from the Archean to the Quaternary, yet current understanding of aeolian sedimentary processes and product remains limited. Most preserved aeolian successions represent inland sand‐sea or dunefield (erg) deposits, whereas coastal systems are primarily known from the Cenozoic. The complexity of aeolian sedimentary processes and facies variability are under‐represented and excessively simplified in current facies models, which are not sufficiently refined to reliably account for the complexity inherent in bedform morphology and migratory behaviour, and therefore cannot be used to consistently account for and predict the nature of the preserved sedimentary record in terms of formative processes. Archean and Neoproterozoic aeolian successions remain poorly constrained. Palaeozoic ergs developed and accumulated in relation to the palaeogeographical location of land masses and desert belts. During the Triassic, widespread desert conditions prevailed across much of Europe. During the Jurassic, extensive ergs developed in North America and gave rise to anomalously thick aeolian successions. Cretaceous aeolian successions are widespread in South America, Africa, Asia, and locally in Europe (Spain) and the USA. Several Eocene to Pliocene successions represent the direct precursors to the present‐day systems. Quaternary systems include major sand seas (ergs) in low‐lattitude and mid‐latitude arid regions, Pleistocene carbonate and Holocene–Modern siliciclastic coastal systems. The sedimentary record of most modern aeolian systems remains largely unknown. The majority of palaeoenvironmental reconstructions of aeolian systems envisage transverse dunes, whereas successions representing linear and star dunes remain under‐recognized. Research questions that remain to be answered include: (i) what factors control the preservation potential of different types of aeolian bedforms and what are the characteristics of the deposits of different bedform types that can be used for effective reconstruction of original bedform morphology; (ii) what specific set of controlling conditions allow for sustained bedform climb versus episodic sequence accumulation and preservation; (iii) can sophisticated four‐dimensional models be developed for complex patterns of spatial and temporal transition between different mechanisms of accumulation and preservation; and (iv) is it reasonable to assume that the deposits of preserved aeolian successions necessarily represent an unbiased record of the conditions that prevailed during episodes of Earth history when large‐scale aeolian systems were active, or has the evidence to support the existence of other major desert basins been lost for many periods throughout Earth history?     

A visibility-based assessment of tsunami evacuation signs in Seaside,Oregon

Tsunami risk mitigation programs often include iconic evacuation signage to direct locals and visitors to safety during a tsunami event. This paper examines sign placement in Seaside, Oregon, from a visibility perspective. It leverages existing visibility analysis methodologies characterize the visibility of the community’s evacuation signage and reveals patterns in the viewable landscape. Additionally, we develop a topologically 3D approach to visibility analysis using raw LiDAR datasets. This applied work situates a discussion on existing patterns of visibility, how to improve existing signage placement, 2D and 3D representation of landscape, and the importance of visibility analysis. This work aims to stimulate discussion and development of hazard research that incorporates a visibility perspective.     

Middle Paleolithic occupation on a Marine Isotope Stage 5 lakeshore in the Nefud Desert,Saudi Arabia

Major hydrological variations associated with glacial and interglacial climates in North Africa and the Levant have been related to Middle Paleolithic occupations and dispersals, but suitable archaeological sites to explore such relationships are rare on the Arabian Peninsula. Here we report the discovery of Middle Paleolithic assemblages in the Nefud Desert of northern Arabia associated with stratified deposits dated to 75,000 years ago. The site is located in close proximity to a substantial relict lake and indicates that Middle Paleolithic hominins penetrated deeply into the Arabian Peninsula to inhabit landscapes vegetated by grasses and some trees. Our discovery supports the hypothesis of range expansion by Middle Paleolithic populations into Arabia during the final humid phase of Marine Isotope Stage 5, when environmental conditions were still favorable.     

Some exact solutions for the flow of fluid through tubes with uniformly porous walls

Summary This paper considers an incompressible fluid flowing through a straight, circular tube whose walls are uniformly porous. The flow is steady and one dimensional. The loss of fluid through the wall is proportional to the mean static pressure in the tube. Several formulations of the wall shear stress are considered; these formulations were motivated by the results from Hamel's radial flow problem, boundary layer flows/and boundary layer suction profiles. For each of these formulations exact solutions for the mean axial velocity and the mean static pressure of the fluid are obtained. Sample results are plotted on graphs. For the constant wall shear stress problem, the theoretical solutions compare favorably with some experimental results.Notations A, B, D, E constant parameters - a, b constant parameters - Ai(z), Bi(z) Airy functions - Ai, Bi derivatives of Airy functions - k constant of proportionality betweenV andp - L length of pores - p,p mean static pressure - p ₀ static pressure outside the tube - p ₀ value ofp atx=0 - Q constant exponent - R inside radius of the tube - T wall shear stress - T ₀ shear parameter - t wall thickness - U free stream velocity - ,u mean axial velocity - u ₀ value ofu atx=0 - V,V mean seepage velocity through the wall - v ₀ mean seepage velocity - x,x axial distance along the tube - z transformed axial distance - z ₀ value ofz atx=0 - mean outflow angle through the wall - cos - density of the fluid - wall shear stress - dynamic viscosity of the fluid - over-bar dimensional terms - no bar nondimensional terms The National Center for Atmospheric Research is sponsored by the National Science Foundation     

Bioassessment Techniques for Monitoring of Eutrophication and Nutrient Limitation in Coastal Ecosystems

Bioassesment by the use of the macroalga, Ulva lactuca L., was carried out in the Limfjord, Denmark, to assess the significance of nitrogen and phosphorus as limiting factors for primary production during 1985, 1993, 1994 and 1995 and for the detection of changes in eutrophication levels.

Minimum and critical tissue concentrations for nitrogen and phosphorus in macroalgae were identified. The concentrations of nitrogen were generally below the critical concentration level in June–October in 1985, 1993, and 1995 but in 1994 nitrogen was only limiting for primary production in short periods. Only in early spring in 1985 and 1993 were the tissue concentrations of phosphorus below the critical concentration level, whereas in 1994 up to 3–4 months showed phosphorus limited growth, indicating that significant changes in limitation patterns can occur between different years.

It was concluded that the use of biomonitoring techniques is well suited as a bioassessment method for direct detection and for providing a time-integrated measure of nutrient availability in coastal waters, and thus for assessing ecosystem health with regard to eutrophication. It is recommended that biomonitors and the concept of critical tissue concentrations should be used in environmental management and incorporated in future monitoring programmes.     

Geochemistry of tin, tungsten and molybdenum in Swedish proterozoic granitoids: Their potential use in regional mineral exploration

The primary aim of this broad regional study is to statistically determine the Li-Sn-W-Mo-bearing potential of various granitoids using geochemical criteria. Computer based, univariate and multivariate statistical methods are applied to major- and trace-element data from about 660 granitic rock samples and over 800 major element analyses, selected from the Swedish geological literature. The granitoids are subdivided following earlier geotectonic chronologic and newer geochemical-statistical principles.Most granite types occurring in known Sn-W mineralized areas, except the granites around the W deposit of Baggetorp, were identified as potentially W-Sn-bearing. That is, they show significantly high mean and variance values for W and/or Sn as well as promising values of the probability parameters for these elements, compared to corresponding statistics for a calculated Swedish average granitoid (SAG).Evidence of very high total variability of Li, Sn and W within the individual granite types suggests the need for further tests, to control the variability errors due to sampling and preparation and errors of chemical analysis. These sources of error may obscure natural elemental heterogeneity of the granite type that is of interest in geochemical prospecting.Interpretations of Sn, W and Li frequency distribution patterns, petrochemical trends and multivariate similarity tests suggest that the primary chemistry of the granitoids is overprinted by (a) postmagmatic processes of broad regional nature, which have similarly affected the individual granite types, and (b) a wide variety of secondary alterations of local character. These conclusions imply that potential Sn and W deposits may be sought within all Swedish Proterozoic granitoids and their within all Swedish Proterozoic granitoids and their immediate sorroundings, where susch processes have redistributed and concentrated these where such processes have redistributed and concentrated these elements. However, the granites which are highly differentiated, Sn-W-Li-U-Th-F-enriched, and strongly and strongly magnetic are particularly promising target areas for further, extensive rock-geochemical prospecting and other exploration surveys. rock-geochemical prospecting and other exploration surveys.     

New friends in new places: Network formation during the migration process among Poles in the UK

This paper contributes to on-going work that seeks to understand the dynamic nature of immigrant social network formation. We explore three propositions, derived from the literature, that might be expected to characterise the ways in which migrant associational ties evolve during and immediately after arrival in their destination country. Evidence is drawn from 42 interviews conducted between January and December 2008 with predominantly Polish migrants to the UK (28) as well as domestic service providers (14). In agreement with the existing literature on immigrant social network formation we find that weak associational ties between migrants are locally dense and rapidly formed. More surprisingly, we also find that the Poles in our sample from lower socio-economic groups tended to rely heavily upon weak associational ties while higher socio-economic group Poles tended to rely on associations made through their employing institutions. This illustrates the importance of socio-economic status in framing co-ethnic migrant network formation. This is significant because we also find that weak associational ties are not unambiguously beneficial to lower socio-economic group migrants who tend to (have to be) more compromising about, and therefore more compromised by, the social ‘friendships’ that result.