Applications of computer modeling to the study of the genesis of stratiform sulfide deposits

Stratiform sulfide deposits are considered to have formed at or near the discharge vents of submarine hydrothermal systems. Such deposits constitute an important source of zinc, lead, copper, silver, and gold. They are often divided on the basis of the dominant host-rock lithology into volcanogenic and sediment-hosted types. In terms of their economic base metal contents, volcanogenic deposits contain either Cu and Zn or Zn, Pb, and Cu, whereas sediment-hosted deposits usually contain predominantly Zn and Pb. Mathematical models of the chemical characteristics of stratiform sulfide deposits are based on a program (B)which allows the calculation of the equilibrium distribution of aqueous species in a hydrothermal solution. Program B is front-ended by Program A, which defines the components of the chemical system, and back-ended by Program C, which controls the mode of output of the calculated results. Programs A and C are tailored to the specific problem under investigation. Results of chemical modeling of the two chemically active zones of the hydrothermal system (1. the hydrothermal reservoir in which the ore-forming solutions are generated and, 2. the site of ore deposition)suggest explanations of various characteristics of stratiform sulfide deposits, and include

1. The consistency of the metal associations and metal ratios suggest that ore-forming hydrothermal solutions are saturated with respect to the major metals in the reservoir zone. The chemistry of the solutions is determined mainly by temperature and chemical equilibrium between the hydrothermal solution and the rock-forming minerals of the reservoir.
2. Metal associations and metal ratios corroborate isotopic and other evidence that volcanogenic deposits were formed from hotter hydrothermal systems (> 200°Capprox.)than sediment-hosted (< 200°Capprox.)Metal ratios suggest that the hydrothermal reservoirs were contained in mafic rocks (ferromagnesian-feldspar mineral assemblages)for the Cu-Zn association; in felsic rocks and/or sediments (feldspar-mica; clay mineral assemblages)for the Zn-Pb-Cu association: and in sediments (dominated by clay mineral assemblages)for the Zn-Pb association.
3. Chemical zonation patterns and ore textures characteristics of volcanogenic deposits are explained by rapid cooling of the hydrothermal solution immediately above its discharge vent.
4. Chemical zonation patterns and the fine laminations of sediment-hosted deposits are explained by the comparatively slow degeneration of hydrothermal solutions that have collected as a brine pool on the ocean floor.

     

Seed biology of Australian arid zone species: Germination of 18 species used for rehabilitation

Revegetation of disturbed land, particularly in arid environments, is often hindered by low seedling establishment. Information on seed biology and germination cues of keystone species is lacking, particularly in arid Australia; a major zone for mining developments. This study investigated seed characteristics and germination of 18 common species required for rehabilitation of disturbed areas at Shark Bay Salt in the Shark Bay World Heritage Area, Western Australia. Untreated seeds of seven species (Aphanopetalum clematideum, Atriplex bunburyana, Austrostipa elegantissima, Melaleuca cardiophylla, Pembertonia latisquamea, Rhagodia baccata, Salsola tragus) exhibited high germination percentages. Seeds of two species (Acacia tetragonophylla, Stylobasium spathulatum) had low imbibition, which increased with hot-water treatment, hence require scarification for germination. Gibberellic acid, smoke water and karrikinolide (a butenolide isolated from smoke) substantially increased germination percentages of three species (Anthocercis littorea, Diplolaena grandiflora, Solanum orbiculatum). Seeds of the remaining six species (Dioscorea hastifolia, Eremophila oldfieldii, Nitraria billardierei, Ptilotus exaltatus, Thryptomene baeckeacea, Zygophyllum fruticulosum) had low germination percentages regardless of treatment. Most species germinated equally well at 26/13 °C and 33/18 °C, however seven species had improved performance at 26/13 °C. This study is significant to land managers and conservation agencies with an interest in optimising germination of arid zone seeds for restoration.     

Localised coherent response of the La Molina basin (Lima,Peru) to earthquakes,and future approaches suggested by Parkway basin (New Zealand) experience

Earthquake records from a 1984 temporary seismograph array set up in La Molina, Lima, Peru, are re-analysed. The array comprised eight three-component geophones; seven soil based and one rock based. Values of horizontal-to-vertical spectral ratio (HVSR) for two small earthquakes peaked at around 1.3 Hz. In one distant earthquake, four of the seven soil-based stations showed a peak at 1.25 Hz in soil-to-rock spectral ratio (SSR), the same dominant frequency observed during an aftershock of a damaging earthquake. Because this frequency is not compatible with the shear wave velocity profile attributed to La Molina, and because the spectral peak is confined to a small ground area, it is concluded that the peak is caused by a localised deposit of soft soil. Because the area associated with the spectral peak includes the area of great damage in 1974, it is concluded that coherent monochromatic behaviour is responsible for the damage.     

Modelling Seismic Waves Around Underground Openings in Fractured Rock

—?The potential for large excavation-induced seismic events may be recognised, even if the timing of an event may be inherently unpredictable. In this case, modelling the wave propagation from a potential event could allow the dynamic motions around an excavation to be projected, and for areas of danger to be anticipated. However, the above and other potential applications require accurate models of wave interaction with the openings, as well as with the fractured rock which surrounds such excavations. This paper considers real recorded waveforms and how well these waveforms are modelled by explicit mechanical models of the source, the medium and the excavation. Models of experiments at three different scales of the problem are presented: small and large amplitude waveforms recorded around a deep-level mining tunnel in a synthetic rockburst experiment; waveforms from laboratory experiments of waves through plates of steel representing fractures; waveforms from active pulses in an acoustic emission experiment in a small volume of fractured rock at the surface of an underground excavation. The results show that elastic wave propagation around an excavation was a first approximation for small amplitude waves, but was less successful for modelling large amplitude waves and more fractured rock. Fractures in the models were represented explicitly with displacement discontinuities. Waveforms through known fracture geometries were particularly well-reproduced, and indicate the importance of fracture stiffness, the in situ stress state, and stress-dependence of the fractures in such models. Overall, the models are sufficiently successful at representing recorded behaviour, to be encouraging for the goal of representing accurate wave motions around excavations.     

Stratification and bottom-water hypoxia in the Pamlico River estuary

Relationships among bottom-water dissolved oxygen (DO), vertical stratification, and the factors responsible for stratification-destratification in this shallow, low tidal-energy estuary were studied using a 15-yr set of biweekly measurements, along with some recent continuous-monitoring data. Hypoxia develops only when there is both vertical water-column stratification and warm water temperature (>15°C). In July, 75% of the DO readings were <5 mg 1^?1, and one-third were <1 mg 1^?1. Severe hypoxia occurs more frequently in the upper half of the estuary than near the mouth. Both the time series data and correlation analysis results indicate that stratification events and DO levels are tightly coupled with variations in freshwater discharge and wind stress. Stratification can form or disappear in a matter of hours, and episodes lasting from one to several days seem to be common. Estimated summertime respiration rates in the water and sediments are sufficient to produce hypoxia if the water is mixed only every 6–12 d. There has been no trend toward lower bottom water DO in the Pamlico River Estuary over the past 15 yr. *** DIRECT SUPPORT *** A01BY059 00002     

Generalizations of reaction rate integrals with applications to nuclear synthesis in astrophysics and some corrections to published literature

Under the Maxwell-Boltzmann approach, the study of nuclear reactions in dense astrophysical plasmas under various cases (such as resonant, non-resonant, modified non-resonant, non-resonant under electron screening, and so on) leads to a class of complicated reaction rate integrals. It is shown that this general class of integrals can be identified with an integral involving the product of twoH-functions. This latter integral is evaluated in this article, and following Buschman (1979), several similar results in the published literature are shown to be incorrect.