9: Processes of tectonism, magmatism and mineralization: Lessons from Europe

Metallogenic provinces in Europe range in age from the Archaean to the Neogene. Deposit types include porphyry copper and epithermal Cu–Au, volcanic-hosted massive sulphide (VMS), orogenic gold, Fe-oxide–Cu–Au, anorthosite Fe–Ti-oxide and sediment-hosted base-metal deposits. Most of them formed during short-lived magmatic events in a wide range of tectonic settings; many can be related to specific tectonic processes such as subduction, hinge retreat, accretion of island arcs, continental collision, lithosphere delamination or slab tear. In contrast, most sediment-hosted deposits in Europe evolved in extensional, continental settings over significant periods of time. In Europe, as elsewhere, ore formation is an integral part of the geodynamic evolution of the Earth's crust and mantle. Many tectonic settings create conditions conducive to the generation of water-rich magma, but the generation of ore deposits appears to be restricted to locations and short periods of change in temperature and stress, imposed by transitory plate motions. Crustal influence is evident in the strong structural controls on the location and morphology of many ore deposits in Europe. Crustal-scale fault–fracture systems, many involving strike-slip elements, have provided the fabric for major plumbing systems. Rapid uplift, as in metamorphic core complexes, and hydraulic fracturing can generate or focus magmatic–hydrothermal fluid flow that may be active for time spans significantly less than a million years. Once a hydrologically stable flow is established, ore formation is strongly dependent on the steep temperature and pressure gradients experienced by the fluid, particularly within the upper crust. In Europe, significant fracture porosity deep in the crystalline basement (1%) is not only important for magmatic–hydrothermal systems, but allows brines to circulate down through sedimentary basins and then episodically upward, expelled seismically to produce sediment-hosted base-metal deposits and Kupferschiefer copper deposits. Emerging research, stimulated by GEODE, can improve the predicting power of numerical simulations of ore-forming processes and help discover the presence of orebodies beneath barren overburden.     

Evaluation of a simple,inexpensive, in situ sampler for measuring time‐weighted average concentrations of suspended sediment in rivers and streams

The accurate measurement of suspended sediment (<200 μm) in aquatic environments is essential to understand and effectively manage changes to sediment, nutrient, and contaminant concentrations on both temporal and spatial scales. Commonly used sampling techniques for suspended sediment either lack the ability to accurately measure sediment concentration (e.g., passive sediment samplers) or are too expensive to deploy in sufficient number to provide landscape‐scale information (e.g., automated discrete samplers). Here, we evaluate a time‐integrated suspended sediment sampling technique, the pumped active suspended sediment (PASS) sampler, which collects a sample that can be used for the accurate measurement of time‐weighted average (TWA) suspended sediment concentration and sediment particle size distribution. The sampler was evaluated against an established passive time‐integrated suspended sediment sampling technique (i.e., Phillips sampler) and the standard discrete sampling method (i.e., manual discrete sampling). The PASS sampler collected a sample representative of TWA suspended sediment concentration and particle size distribution of a control sediment under laboratory conditions. Field application of the PASS sampler showed that it collected a representative TWA suspended sediment concentration and particle size distribution during high flow events in an urban stream. The particle size distribution of sediment collected by the PASS and Phillips samplers were comparable and the TWA suspended sediment concentration of the samples collected using the PASS and discrete sampling techniques agreed well, differing by only 4% and 6% for two different high flow events. We should note that the current configuration of the PASS sampler does not provide a flow‐weighted measurement and, therefore, is not suitable for the determination of sediment loads. The PASS sampler is a simple, inexpensive, and robust in situ sampling technique for the accurate measurement of TWA suspended sediment concentration and particle size distribution.     

On the iron interpretation of the 6.4 keV emission line from SGR 1900+14

A 6.4 keV emission line was discovered in an unusual burst from the soft gamma repeater SGR 1900+14 with the Rossi X-ray Timing Explorer (RXTE). The line was detected in part of a complex multipeak precursor that preceded the unusual burst of 1998 August 29, i.e. two days after the giant flare of August 27 from the source. The origin of the line was not firmly identified and two possible interpretations were equally plausible including (a) Kα fluorescence from a small iron rich material that was ejected to the magnetosphere during the August 27 flare, and (b) proton or α-particle cyclotron resonance. If the iron scenario was correct, we expect to find evidence for the line during the intervening interval between the flare and the August 29 burst, i.e. on August 28. Here we present the results of the August 28 burst observation, taken with RXTE. We detect a total of seven bursts whose individual and joint spectra do not show evidence for spectral lines. We also investigated a sample of nine bursts before and after the August 29 burst (from 1998 June to December) that do not reveal evidence for a spectral line near 6.4 keV or elsewhere. These results disfavor the iron scenario and make the proton/α-particle cyclotron resonance interpretation more plausible. The appearance of the emission line in part of a complex burst and its absence from the studied sample indicate that the line is likely due to a transient phenomenon that may depend on the burst morphology, energetics and the properties of the emission region.      

Computer-composite mapping for geologists

A computer program for overlaying maps has been tested and evaluated as a means for producing geologic derivative maps. Four maps of the Sugar House Quadrangle, Utah, were combined, using the Multi-Scale Data Analysis and Mapping Program, in a single composite map that shows the relative stability of the land surface during earthquakes. Computer-composite mapping can provide geologists with a powerful analytical tool and a flexible graphic display technique. Digitized map units can be shown singly, grouped with different units from the same map, or combined with units from other source maps to produce composite maps. The mapping program permits the user to assign various values to the map units and to specify symbology for the final map. Because of its flexible storage, easy manipulation, and capabilities of graphic output, the composite-mapping technique can readily be applied to mapping projects in sedimentary and crystalline terranes, as well as to maps showing mineral resource potential.     

Quantifying multiple Permian–Recent exhumation events during the break‐up of eastern Gondwana: sonic transit time analysis of the central and southern Perth Basin

The central and southern Perth Basin in southwestern Australia has a geological history involving multiple regional unconformity‐forming events from the Permian to Recent. This study uses sonic transit time analysis to quantify the magnitudes of net and gross exhumation for four stratigraphic periods from 43 wells. Most importantly, we quantify gross exhumation of the Permian–Triassic, Triassic–Jurassic, Valanginian break‐up and post‐Early Cretaceous events. Post‐Early Cretaceous gross exhumation averages 900‐m offshore and 600‐m onshore. Up to 200 m of this exhumation may be attributed to localized fault block rotation during extension in the Late Cretaceous and/or reverse fault re‐activation due to the compressive stresses in Australia in the last 50 Ma. The remainder is attributed to regional exhumation caused by epeirogenic processes either during the Cenozoic or at the Aptian–Albian boundary. Maximum burial depths prior to the Valanginian unconformity‐forming event were less than those reached subsequently, so that the magnitude of Valanginian break‐up exhumation cannot be accurately quantified. Gross exhumation prior to the break‐up of Gondwana was defined by large magnitude differences (up to 2500 m) between adjoining sub‐basins. At the end of Triassic, exhumation is primarily attributed to reverse re‐activation of faults that were driven by short‐wavelength inversion and exhumation at the end Permian is likely caused by uplift of rotated fault blocks during extension. The evidence from quantitative exhumation analysis indicates a switch in regime, from locally heterogeneous before break‐up to more regionally homogeneous after break‐up.     

Seismic electric signals in seismic prone areas

The Varotsos-Alexopoulos-Nomicos(VAN) method of short-term earthquake prediction was introduced in the 1980s. The VAN method enables estimation of the epicenter, magnitude and occurrence time of an impending earthquake by observing transient changes of the electric field of the Earth termed seismic electric signals(SES). Here, we present a few examples of SES observed in various earthquake prone areas worldwide.     

Mineralogical and chemical evolution of the Ernest Henry Fe oxide–Cu–Au ore system, Cloncurry district, northwest Queensland, Australia

The Ernest Henry Cu–Au deposit was formed within a zoned, post-peak metamorphic hydrothermal system that overprinted metamorphosed dacite, andesite and diorite (ca 1740–1660 Ma). The Ernest Henry hydrothermal system was formed by two cycles of sodic and potassic alteration where biotite–magnetite alteration produced in the first cycle formed ca 1514±24 Ma, whereas paragenetically later Na–Ca veining formed ca 1529 +11/−8 Ma. These new U–Pb_titanite age dates support textural evidence for incursion of hydrothermal fluids after the metamorphic peak, and overlap with earlier estimates for the timing of Cu–Au mineralization (ca 1540–1500 Ma). A distal to proximal potassic alteration zone correlates with a large (up to 1.5 km) K–Fe–Mn–Ba enriched alteration zone that overprints earlier sodic alteration. Mass balance analysis indicates that K–Fe–Mn–Ba alteration—largely produced during pre-ore biotite- and magnetite-rich alteration—is associated with K–Rb–Cl–Ba–Fe–Mn and As enrichment and Na, Ca and Sr depletion. The aforementioned chemical exchange almost precisely counterbalances the mass changes associated with regional Na–Ca alteration. This initial transition from sodic to potassic alteration may have been formed during the evolution of a single fluid that evolved via alkali exchange during progressive fluid-rock interaction. Cu–Au ore, dominated by co-precipitated magnetite, minor specular hematite, and chalcopyrite as breccia matrix, forms a pipe-like body at the core of a proximal alteration zone dominated by K-feldspar alteration. Both the core and K-feldspar alteration overprint Na–Ca alteration and biotite–magnetite (K–Fe) alteration. Ore was associated with the concentration of a diverse range of elements (e.g. Cu, Au, Fe, Mo, U, Sb, W, Sn, Bi, Ag, F, REE, K, S, As, Co, Ba and Ca). Mineralization also involved the deposition of significant barite, K(–Ba)–feldspar, calcite, fluorite and complexly zoned pyrite. The complexly zoned pyrite and variable K–(Ba)–feldspar versus barite associations are interpreted to indicate fluctuating sulphur and/or barium supply. Together with the alteration zonation geochemistry and overprinting criteria, these data are interpreted to indicate that Cu–Au mineralization occurred as a result of fluid mixing during dilation and brecciation, in the location of the most intense initial potassic alteration. A link between early alteration (Na–Ca and K–Fe) and the later K-feldspathization and the Cu–Au ore is possible. However, the ore-related enrichments in particular elements (especially Ba, Mn, As, Mo, Ag, U, Sb and Bi) are so extreme compared with earlier alteration that another fluid, possibly magmatic in origin, contributed the diverse element suite geochemically independently of the earlier stages. Structural focussing of successive stages produced the distinctive alteration zoning, providing a basis both for exploration for similar deposits, and for an understanding of ore genesis.     

Investigation of spatially distributed braided river flows using a two‐dimensional hydraulic model

This paper reports the application of a two‐dimensional hydraulic model to a braided reach of the Avoca River, New Zealand. Field measurements of water surface elevation, depth and velocity obtained at low flow were used to validate the model and to optimize the parameterization of bed friction. The main systematic trends in the measured flow variables are reproduced by the model. However, field data are characterized by greater spatial variability than model output reflecting differences in the scale of processes measured in the field and represented by the model. Additional model runs were conducted to simulate flow patterns within the study reach at five higher discharges. The purpose of these simulations was to evaluate the potential for using two‐dimensional hydraulic models to quantify the reach‐scale hydraulic characteristics of braided rivers and their dependence on discharge. Changes in flow depth and velocity with increasing discharge exhibit trends that are consistent with the results of previous field investigations, although the tendency for the wetted area of the braidplain within particular depth and velocity categories to remain fixed as discharge rises, as has been noted for several braided rivers in New Zealand, was not observed. Modelled shear stress frequency distributions fit gamma functions that incorporate a distribution shape parameter, the value of which follows clear systematic trends with rising discharge. These results illustrate both the problems of, and potential for, using two‐dimensional hydraulic models in braided river applications. This leads to something of a paradox in that while such models provide a means of generating hydraulic information that would be difficult to obtain in the field at an equivalent spatial resolution, they are, due to the problems inherent to data collection, difficult to validate conclusively. Despite this limitation, the application of spatially distributed models to investigate relationships between discharge and reach‐scale form and process variables appears to have considerable potential. Copyright © 2003 John Wiley & Sons, Ltd.     

Soil organic carbon enrichment of dust emissions: magnitude,mechanisms and its implications for the carbon cycle

Soil erosion is an important component of the global carbon cycle. However, little attention has been given to the role of aeolian processes in influencing soil organic carbon (SOC) flux and the release of greenhouse gasses, such as carbon dioxide (CO₂), to the atmosphere. Understanding the magnitude and mechanisms of SOC enrichment in dust emissions is necessary to evaluate the impact of wind erosion on the carbon cycle. This research examines the SOC content and enrichment of dust emissions measured using Big Spring Number Eight (BSNE) wind‐vane samplers across five land types in the rangelands of western Queensland, Australia. Our results show that sandy soils and finer particulate quartz‐rich soils are more efficient at SOC emission and have larger SOC dust enrichment than clay‐rich aggregated soils. The SOC enrichment ratios of dusts originating from sites with sand‐rich soil ranged from 2·1–41·9, while the mean enrichment ratio for dusts originating from the clay soil was 2·1. We hypothesize that stronger inter‐particle bonds and the low grain density of the aggregated clay soil explain its reduced capacity to release SOC during saltation, relative to the particulate sandy soils. We also show that size‐selective sorting of SOC during transport may lead to further enrichment of SOC dust emissions. Two dust samples from regional transport events were found to contain 15–20% SOC. These preliminary results provide impetus for additional research into dust SOC enrichment processes to elucidate the impact of wind erosion on SOC flux and reduce uncertainty about the role of soil erosion in the global carbon cycle. Copyright © 2013 John Wiley & Sons, Ltd.     

Photometric,spectral phase and temperature effects on 4 Vesta and HED meteorites: Implications for the Dawn mission

Phase angle and temperature are two important parameters that affect the photometric and spectral behavior of planetary surfaces in telescopic and spacecraft data. We have derived photometric and spectral phase functions for the Asteroid 4 Vesta, the first target of the Dawn mission, using ground-based telescopes operating at visible and near-infrared wavelengths (0.4–2.5 μm). Photometric lightcurve observations of Vesta were conducted on 15 nights at a phase angle range of 3.8–25.7° using duplicates of the seven narrowband Dawn Framing Camera filters (0.4–1.0 μm). Rotationally resolved visible (0.4–0.7 μm) and near-IR spectral observations (0.7–2.5 μm) were obtained on four nights over a similar phase angle range. Our Vesta photometric observations suggest the phase slope is between 0.019 and 0.029 mag/deg. The G parameter ranges from 0.22 to 0.37 consistent with previous results (e.g., Lagerkvist, C.-I., Magnusson, P., Williams, I.P., Buontempo, M.E., Argyle, R.W., Morrison, L.V. [1992]. Astron. Astrophys. Suppl. Ser. 94, 43–71; Piironen, J., Magnusson, P., Lagerkvist, C.-I., Williams, I.P., Buontempo, M.E., Morrison, L.V. [1997]. Astron. Astrophys. Suppl. Ser. 121, 489–497; Hasegawa, S. et al. [2009]. Lunar Planet. Sci. 40. ID 1503) within the uncertainty. We found that in the phase angle range of 0° < α ? 25° for every 10° increase in phase angle Vesta’s visible slope (0.5–0.7 μm) increases 20%, Band I and Band II depths increase 2.35% and 1.5% respectively, and the BAR value increase 0.30. Phase angle spectral measurements of the eucrite Moama in the lab show a decrease in Band I and Band II depths and BAR from the lowest phase angle 13° to 30°, followed by possible small increases up to 90°, and then a dramatic drop between 90° and 120° phase angle. Temperature-induced spectral effects shift the Band I and II centers of the pyroxene bands to longer wavelengths with increasing temperature. We have derived new correction equations using a temperature series (80–400 K) of HED meteorite spectra that will enable interpretation of telescopic and spacecraft spectral data using laboratory calibrations at room temperature (300 K).