The relative effects of deformation and thermal advection on fluid pathways in basin-related mineralization

The migration of basinal brines into basement material has been proposed as a means of scouring or leaching metals for subsequent ore deposition. Here we address this issue by numerically examining competing processes, namely deformation, fluid flow and thermal gradients, to describe potential fluid pathways leading to enrichment of metals and ore deposition. Stable convective fluid patterns may be established across the cover/basement interfaces if permeability contrasts are minimized, however, at the onset of extensional deformation these convective patterns quickly collapse. On cessation of the deformation, convection cells again develop, which are oscillatory with time. Input to the thermal budget from a radiogenic heat source suggests that basinal fluids can be drawn down around the margins of granite intrusions and fluid mixing processes may take place due to small and localised convective patterns. Fluid migration from basin into basement and back is highly likely given the right conditions, however, the rate and extent of fluid flow are determined by thermal and deformation processes.     

http://www.sciencedirect.com/science/article/pii/S1674987113000601

The intrusions of the Panzhihua-Xichang(Panxi) region in southwest China have become well known in the past decade because they host large and rich magmatic oxide deposits that are mined for Fe,Ti and V.These intrusions form part of the Emeishan large igneous province(ELIP),which is commonly believed to be the product of melting in a mantle plume.The ELIP was emplaced about 260 Ma ago,at the same time as the end-Guadalupian mass extinction.The investigation of the Panxi intrusions therefore provides information relevant to three broad areas of the earth sciences:(1)the petrogenesis of mafic magmas, (2) the impact of major magmatic events and global climate and     

Dissolution rates of talc as a function of solution composition, pH and temperature

Steady-state talc dissolution rates, at far-from-equilibrium conditions, were measured as a function of aqueous silica and magnesium activity, pH from 1 to 10.6, and temperature from 25 to 150 °C. All rates were measured in mixed flow reactors and exhibited stoichiometric or close to stoichiometric dissolution. All measured rates at pH > 2 obtained at a fixed ionic strength of 0.02 M can be described to within experimental uncertainty using

     

Surface geochemical and biogeochemical expression of base‐metal mineralization at Woodlawn,New South Wales,Australia

The presence of base‐metal mineralization at Woodlawn was first recognised early in 1968 when a roadside reconnaissance geochemical sampling survey, conducted over felsic volcanic rocks in the Goulburn‐Tarago area, encountered anomalous B horizon soils containing up to 200 ppm Cu, 800 ppm Pb and 300 ppm Zn. Regional soil thresholds have been determined at 50 ppm Cu, 90 ppm Pb and 50 ppm Zn. Chip samples from the subsequently located gossan revealed up to 2000 ppm Cu, 8000 ppm Pb and 2000 ppm Zn, 500 ppm Sn, 25 ppm Ag and 3000 ppm As.

The first grid B horizon soil geochemical survey was conducted in 1968 over the gossan and surrounding area, and repeated with closer spaced sampling in the first half of 1970. The first survey delineated strong Cu (to 1000 ppm) and Pb (to 2500 ppm) anomalies coincident with the gossan zone, and intense hydromorphic zinc anomalies (to 3000 ppm) located down slope from the gossan in residual clay‐soils derived from dolerite bedrock. Threshold values have been determined at 140 ppm Cu, 700 ppm Pb and 580 ppm Zn. Ag and Sn in B horizon soils show pronounced anomalies coincident with the gossan and are suitable metals for geochemical target definition. Of fourteen trace elements determined in 1974 from B and C horizon soils on two lines across the ore zone Cu, Pb, Zn, Se, Ba, Sn and Ag show direct correlation with the mineralization, whereas Cd and Mn show moderate hydromorphic dispersion, having accumulated principally in clay soils derived from dolerite weathering. As, Sb and Bi, whilst responding over the ore zone, show elevated values in soils over hanging‐wall units; Ni and Co show maximum levels in soils over dolerite bedrock.

Bark and leaves of Acacia mearnsii, collected from a line across the gossan, contain anomalous levels of Cu, Pb, Zn, Sn and Ti near the ore zone, and weaker, but clearly anomalous Mn and Ni levels over dolerite bedrock. Both bark and leaves of Acacia mearnsii reflect the presence of concealed mineralization. The shrub Solanum linearifolium grows preferentially over and close to the Woodlawn ore zone, where it contains up to 840 ppm Cu, 250 ppm Pb, 7300 ppm Zn, 6 ppm Sn and 250 ppm Ti in leaf ash compared with levels of 200 ppm Cu, 2 ppm Pb, 400 ppm Zn, 0.8 ppm Sn and 60 ppm Ti in plants growing 1.5 km from the ore zone. This shrub has potential as an indicator of base‐metal mineralization.     

Analytical hydrologic models and the design of policy instruments for groundwater-quality management

This paper explores how analytical hydrologic models can inform the effective design and choice of policy instruments to manage groundwater quality by coupling a social-planner’s problem of optimal groundwater-quality management with analytical solutions from the hydrology literature. A theoretical analysis is performed in order to characterize the properties of an optimal emissions policy. The model is then applied in a numerical analysis of groundwater contamination by chloride from highway deicers, demonstrating the relevance of the theoretical results to practical management settings. This analytical approach can help determine which policy instruments are likely to be effective in controlling groundwater pollution, especially if costly numerical groundwater models are not available for the aquifer in question. Unlike previous economic studies of groundwater contamination, this approach defines optimal emissions policies as a function of geophysical parameters employed by hydrologists such as distance between source and sink, groundwater velocity, and aquifer dispersivity. The theoretical section of this paper also demonstrates that the relationship between geophysical parameters and optimal emissions levels may be ambiguous.     

Internal structure and significance of ice‐marginal moraine in the Kebnekaise Mountains,northern Sweden

Despite a long history of glaciological research, the palaeo‐environmental significance of moraine systems in the Kebnekaise Mountains, Sweden, has remained uncertain. These landforms offer the potential to elucidate glacier response prior to the period of direct monitoring and provide an insight into the ice‐marginal processes operating at polythermal valley glaciers. This study set out to test existing interpretations of Scandinavian ice‐marginal moraines, which invoke ice stagnation, pushing, stacking/dumping and push‐deformation as important moraine forming processes. Moraines at Isfallsglaciären were investigated using ground‐penetrating radar to document the internal structural characteristics of the landform assemblage. Radar surveys revealed a range of substrate composition and reflectors, indicating a debris‐ice interface and bounding surfaces within the moraine. The moraine is demonstrated to contain both ice‐rich and debris‐rich zones, reflecting a complex depositional history and a polygenetic origin. As a consequence of glacier overriding, the morphology of these landforms provides a misleading indicator of glacial history. Traditional geochronological methods are unlikely to be effective on this type of landform as the fresh surface may post‐date the formation of the landform following reoccupation of the moraine rampart by the glacier. This research highlights that the interpretation of geochronological data sets from similar moraine systems should be undertaken with caution.     

On Northern Hemisphere Wave Patterns Associated with Winter Rainfall Events in China

During extended winter(November–April),43% of the intraseasonal rainfall variability in China is explained by three spatial patterns of temporally coherent rainfall.These patterns were identified with empirical orthogonal teleconnection(EOT) analysis of observed 1982–2007 pentad rainfall anomalies and connected to midlatitude disturbances.However,examination of individual strong EOT events shows that there is substantial inter-event variability in their dynamical evolution,which implies that precursor patterns found in regressions cannot serve as useful predictors.To understand the physical nature and origins of the extratropical precursors,the EOT technique is applied to six simulations of the Met Office Unified Model at horizontal resolutions of 200–40 km,with and without air–sea coupling.All simulations reproduce the observed precursor patterns in regressions,indicating robust underlying dynamical processes.Further investigation into the dynamics associated with observed patterns shows that Rossby wave dynamics can explain the large inter-event variability.The results suggest that the apparently slowly evolving or quasi-stationary waves in regression analysis are a statistical amalgamation of more rapidly propagating waves with a variety of origins and properties.     

Occurrence ofSpartina macrodetritus in Bay of Fundy waters

Suspended macrodetritus (>600 μm) from extensiveSpartina alterniflora marshes is widespread in the Cumberland Basin region of the macrotidal upper Bay of Fundy. The average concentration is about 5 mg C per m³ and most is found in the lower two-thirds of the water column. The total amount in the Basin at high tide is approximately 8 metric tonnes of organic carbon which is less than 1% of the annual net aerial primary production of the fringingS. alterniflora marshes. The high visibility ofSpartina detritus in Cumberland Basin is caused by the extreme tides (average tidal range about 11 m) which export marsh vegetation and distribute it widely about the estuary, and by the pronounced turbidity which has been shown to limit phytoplankton growth.     

Late Holocene sea-surface temperature and precipitation variability in northern Patagonia, Chile (Jacaf Fjord, 44°S)

A high-resolution multi-proxy study including the elemental and isotopic composition of bulk organic matter, land plant-derived biomarkers, and alkenone-based sea-surface temperature (SST) from a marine sedimentary record obtained from the Jacaf Fjord in northern Chilean Patagonia (44°20′S) provided a detailed reconstruction of continental runoff, precipitation, and summer SST spanning the last 1750 yr. We observed two different regimes of climate variability in our record: a relatively dry/warm period before 900 cal yr BP (lower runoff and average SST 1°C warmer than present day) and a wet/cold period after 750 cal yr BP (higher runoff and average SST 1°C colder than present day). Relatively colder SSTs were found during 750–600 and 450–250 cal yr BP, where the latter period roughly corresponds to the interval defined for the Little Ice Age (LIA). Similar climatic swings have been observed previously in continental and marine archives of the last two millennia from central and southern Chile, suggesting a strong latitudinal sensitivity to changes in the Southern Westerly Winds, the main source of precipitation in southern Chile, and validating the regional nature of the LIA. Our results reveal the importance of the Chilean fjord system for recording climate changes of regional and global significance.