New typologies for estuarine morphology

New theories to explain how tides and river flow determine estuarine bathymetries have been developed. The range of validity of these theories has been subsequently assessed against a recently available observational data set.Success in reproducing the evolution of estuarine bathymetries that has occurred over the last 10 000 years provides the basis for the translation, here, of these theories into new typologies. These then provide reference frameworks to enhance our perspective on existing morphologies and identify ‘anomalous’ estuaries. Further refinement of these new theories requires analyses of causal factors responsible for such anomalies drawing on classical morphological experience. These frameworks can also be used for calculating likely future bathymetric adjustments for prescribed changes in mean sea level, tidal amplitudes, river flow and sediment supply.     

HUMBOLDT'S MEXICAN TEXTS AND LANDSCAPES*

ABSTRACT. While in New Spain from 1803 to 1804, Alexander von Humboldt interacted with some of its landscapes and the texts that represented them. Analysis of those interactions regarding the Basin of Mexico and the Gulf lowlands demonstrates what purely text‐based studies of the production of places cannot: The contrasting landscape elements and patterns that had emerged over millennia during precolonial times in those two places, their relative degrees of depopulation during the colonial era, and the relative degrees of rigor Humboldt applied to interacting with the resulting landscapes and the texts that represented them greatly affected his representations of those places in his 1811 Essai politique sur le royaume de la Nouvelle‐Espagne. His representations of the precolonial Basin of Mexico as productively developed and of the precolonial Gulf lowlands as pristine have influenced the transformations of those places in the two centuries after New Spain became the Mexican republic through its wars of independence (1810–1821).     

Lake Sediment Core Records of Sulphur Accumulation and Sulphur Isotopic Composition in Central Ontario, Canada Lakes

Stable isotopic compositions and concentrations of total sedimentary sulphur (S) were determined in cores from 6 lakes in the acid-sensitive Muskoka-Haliburton region of south-central Ontario. The isotopic composition of S in deep sediment (> ~ 20 cm) was approximately constant in all lakes, and indicated a pre-industrial δ ³⁴S value between +4.0 and +5.3‰, which is similar to current bulk deposition. Similarly, total S concentrations in deep sediment were relatively low (1.9–5 mg S g⁻¹ dwt) and approximately constant with depth within cores. All lakes exhibited up-core increases in total S and decreases in δ ³⁴S at a depth corresponding to the beginning of industrialization in the Great Lakes region ( ~ 1900), resulting in a generally reciprocal depth pattern between total S concentration and δ ³⁴S ratios. While initial shifts in total S and δ ³⁴S were likely due to enhanced SO₄ reduction of newly available anthropogenic SO₄, both the magnitude and pattern of up-core S enrichment and shifts in δ ³⁴S varied greatly among lakes, and did not match changes in S deposition post 1900. Differences between lakes in total S and δ ³⁴S were not related to any single hydrologic (e.g., residence time) or physical (e.g., catchment-area-to-lake area ratio) lake characteristic. This work indicates that sediment cores do not provide consistent records of changes in post-industrial S deposition in this region, likely due to redox-related mobility of S in upper sediment.     

Late Holocene linkages between decade–century scale climate variability and productivity at Lake Tanganyika, Africa

Microlaminated sediment cores from the Kalya slope region of Lake Tanganyika provide a near-annually resolved paleoclimate record between ∼∼2,840 and 1,420 cal. yr B.P. demonstrating strong linkages between climate variability and lacustrine productivity. Laminae couplets comprise dark, terrigenous-dominated half couplets, interpreted as low density underflows deposited from riverine sources during the rainy season, alternating with light, planktonic diatomaceous ooze, with little terrigenous component, interpreted as windy/dry season deposits. Laminated portions of the studied cores consist of conspicuous dark and light colored bundles of laminae couplets. Light and dark bundles alternate at decadal time scales. Within dark bundles, both light and dark half couplets are significantly thinner than within light bundles, implying slower sediment accumulation rates during both seasons over those intervals.Time series analyses of laminae thickness patterns demonstrate significant periodicities at interannual–centennial time scales. Longer time scale periodicities (multidecadal to centennial scale) of light and dark half couplet thicknesses are coherent and in some cases are similar to solar cycle periods on these time scales. Although laminae thickness cycles do not strongly covary with the actual Δ¹⁴C record for this same time period, two large Δ¹⁴C anomalies are associated with substantial decreases in both light and dark laminae thickness. In contrast to the multidecadal– centennial time scale, significant annual to decadal periodicities, which are broadly consistent with ENSO/PDO forcing and their impact on East African climate, are not coherent between light and dark half couplets. The coherency of light–dark couplets at decadal–centennial time scales, but not at shorter time scales, is consistent with a model of a long-term relationship between precipitation (recorded in wet season dark laminae thickness) and productivity (light laminae thickness), which is not manifest at shorter time scales. We hypothesize that this coupling results from long-term recharging of internal nutrient loading during wet periods (higher erosion of soil P) and reduced loading during drought intervals. The relationship is not expressed on short time scales during which the dominant control on productivity is wind-driven, dry season upwelling, which is uncorrelated with wet-season precipitation. Our record greatly extends the temporal record of this quasi-periodic behavior throughout the late Holocene and provides the first evidence linking decade- to century-scale episodes of enhanced productivity to enhanced precipitation levels and nutrient recharge in a productive tropical lake.     

Mineralogical and chemical evolution of the Ernest Henry Fe oxide–Cu–Au ore system, Cloncurry district, northwest Queensland, Australia

The Ernest Henry Cu–Au deposit was formed within a zoned, post-peak metamorphic hydrothermal system that overprinted metamorphosed dacite, andesite and diorite (ca 1740–1660 Ma). The Ernest Henry hydrothermal system was formed by two cycles of sodic and potassic alteration where biotite–magnetite alteration produced in the first cycle formed ca 1514±24 Ma, whereas paragenetically later Na–Ca veining formed ca 1529 +11/−8 Ma. These new U–Pb_titanite age dates support textural evidence for incursion of hydrothermal fluids after the metamorphic peak, and overlap with earlier estimates for the timing of Cu–Au mineralization (ca 1540–1500 Ma). A distal to proximal potassic alteration zone correlates with a large (up to 1.5 km) K–Fe–Mn–Ba enriched alteration zone that overprints earlier sodic alteration. Mass balance analysis indicates that K–Fe–Mn–Ba alteration—largely produced during pre-ore biotite- and magnetite-rich alteration—is associated with K–Rb–Cl–Ba–Fe–Mn and As enrichment and Na, Ca and Sr depletion. The aforementioned chemical exchange almost precisely counterbalances the mass changes associated with regional Na–Ca alteration. This initial transition from sodic to potassic alteration may have been formed during the evolution of a single fluid that evolved via alkali exchange during progressive fluid-rock interaction. Cu–Au ore, dominated by co-precipitated magnetite, minor specular hematite, and chalcopyrite as breccia matrix, forms a pipe-like body at the core of a proximal alteration zone dominated by K-feldspar alteration. Both the core and K-feldspar alteration overprint Na–Ca alteration and biotite–magnetite (K–Fe) alteration. Ore was associated with the concentration of a diverse range of elements (e.g. Cu, Au, Fe, Mo, U, Sb, W, Sn, Bi, Ag, F, REE, K, S, As, Co, Ba and Ca). Mineralization also involved the deposition of significant barite, K(–Ba)–feldspar, calcite, fluorite and complexly zoned pyrite. The complexly zoned pyrite and variable K–(Ba)–feldspar versus barite associations are interpreted to indicate fluctuating sulphur and/or barium supply. Together with the alteration zonation geochemistry and overprinting criteria, these data are interpreted to indicate that Cu–Au mineralization occurred as a result of fluid mixing during dilation and brecciation, in the location of the most intense initial potassic alteration. A link between early alteration (Na–Ca and K–Fe) and the later K-feldspathization and the Cu–Au ore is possible. However, the ore-related enrichments in particular elements (especially Ba, Mn, As, Mo, Ag, U, Sb and Bi) are so extreme compared with earlier alteration that another fluid, possibly magmatic in origin, contributed the diverse element suite geochemically independently of the earlier stages. Structural focussing of successive stages produced the distinctive alteration zoning, providing a basis both for exploration for similar deposits, and for an understanding of ore genesis.     

Quantification of karst aquifer discharge components during storm events through end-member mixing analysis using natural chemistry and stable isotopes as tracers

Karst aquifer components that contribute to the discharge of a water supply well in the Classical Karst (Kras) region (Italy/Slovenia) were quantitatively estimated during storm events. Results show that water released from storage within the epikarst may comprise as much as two-thirds of conduit flow in a karst aquifer following rainfall. Principal components analysis (PCA) and end-member mixing analysis (EMMA) were performed using major ion chemistry and the stable isotopes of water (δ¹⁸O, δ²H) and of dissolved inorganic carbon (δ¹³C_DIC) to estimate mixing proportions among three sources: (1) allogenic river recharge, (2) autogenic recharge, and (3) an anthropogenic component stored within the epikarst. The sinking river most influences the chemical composition of the water-supply well under low-flow conditions; however, this proportion changes rapidly during recharge events. Autogenic recharge water, released from shallow storage in the epikarst, displaces the river water and is observed at the well within hours after the onset of precipitation. The autogenic recharge end member is the second largest component of the well chemistry, and its contribution increases with higher flow. An anthropogenic component derived from epikarstic storage also impacts the well under conditions of elevated hydraulic head, accounting for the majority of the chemical response at the well during the wettest conditions.     

Mixing and differentiation in the Oruanui rhyolitic magma, Taupo, New Zealand: evidence from volatiles and trace elements in melt inclusions

Large pyroclastic rhyolites are snapshots of evolving magma bodies, and preserved in their eruptive pyroclasts is a record of evolution up to the time of eruption. Here we focus on the conditions and processes in the Oruanui magma that erupted at 26.5 ka from Taupo Volcano, New Zealand. The 530 km³ (void-free) of material erupted in the Oruanui event is comparable in size to the Bishop Tuff in California, but differs in that rhyolitic pumice and glass compositions, although variable, did not change systematically with eruption order. We measured the concentrations of H₂O, CO₂ and major and trace elements in zoned phenocrysts and melt inclusions from individual pumice clasts covering the range from early to late erupted units. We also used cathodoluminescence imaging to infer growth histories of quartz phenocrysts. For quartz-hosted inclusions, we studied both fully enclosed melt inclusions and reentrants (connecting to host melt through a small opening). The textures and compositions of inclusions and phenocrysts reflect complex pre-eruptive processes of incomplete assimilation/partial melting, crystallization differentiation, magma mixing and gas saturation. ‘Restitic’ quartz occurs in seven of eight pumice clasts studied. Variations in dissolved H₂O and CO₂ in quartz-hosted melt inclusions reflect gas saturation in the Oruanui magma and crystallization depths of ∼3.5–7 km. Based on variations of dissolved H₂O and CO₂ in reentrants, the amount of exsolved gas at the beginning of eruption increased with depth, corresponding to decreasing density with depth. Pre-eruptive mixing of magma with varying gas content implies variations in magma bulk density that would have driven convective mixing. Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.     

Combined Digital Photogrammetry and Time-of-Flight Laser Scanning for Monitoring Cliff Evolution

Although cliffs form approximately 75% of the world's coastline, the understanding of the processes through which they evolve remains limited because of a lack of quantitative data on the morphological changes they undergo. In this paper the combination of terrestrial time-of-flight laser scanning with high-resolution digital photogrammetry is examined to generate high-quality data-sets pertaining to the geomorphic processes governing cliff development. The study was undertaken on a section of hard rock cliffs in North Yorkshire, UK, which has been monitored over a 12-month period. High-density, laser-scanned point clouds have been used to produce an accurate representation of these complex surfaces, free from the optical variations that degrade photographic data. These data-sets have been combined with high-resolution photographic monitoring, resampled with the fixed accuracies of the terrestrial laser survey, to generate a new approach to recording the volumetric changes in complex coastal cliffs. This has led to significant improvements in the understanding of the activity patterns of coastal cliffs.     

Effective and Equitable Dissemination of Seasonal-to-Interannual Climate Forecasts: Policy Implications from the Peruvian Fishery during El Niño 1997–98

The development of seasonal-to-interannual climate predictions has spurred widespread claims that the dissemination of such forecasts will yield benefits for society. Based on the use as well as non-use of forecasts in the Peruvian fishery during the 1997–98 El Niño event, weidentify: (1) potential constraints on the realization of benefits, such aslimited access to and understanding of information, and unintended reactions; (2) theneed for an appropriately detailed definition of societal benefit, considering whose welfare counts as a benefit among groups such as labor, industry, consumers, citizens of different regions, and future generations.We argue that consideration of who benefits, and an understanding of potential socioeconomic constraints and how they might be addressed, should be brought to bear on forecast dissemination choices. We conclude with examples of relevant dissemination choices made using this process.