Natural Radioactivity at the Sin Quyen Iron-Oxide-Copper-Gold Deposit in North Vietnam

The field radiometric and laboratory measurements were performed at the Sin Quyen copper deposit in North Vietnam. The field gamma-ray spectrometry indicated the concentration of uranium ranging from 5.5 to 87 ppm, thorium from 5.6 to 33.2 ppm, and potassium from 0.3 to 4.7%. The measured dose rates ranged from 115 to 582 nGy/h, the highest doses being at the copper ore. Concentrations in the solid samples were in the range of 20–1700 Bq/kg for uranium, 20–92.7 Bq/kg for thorium, and 7–1345 Bq/kg for potassium. The calculated doses were from 22 to 896 nGy/h; both measured and calculated dose rates are mostly related to uranium. Concentrations of radium in water samples were below 0.17 Bq/L. Uranium in water samples was significantly higher than the hydrogeological background; the maximum of 13 Bq/L was at the waste zone pool, but neither radium nor uranium were present in tap water. Radon concentration in the dwelling air was from 42 to 278 Bq/m³ for ²²²Rn and from 8 to 193 Bq/m³ for ²²⁰Rn. The estimated committed dose rates were principally related to ²²²Rn concentration and ranged from 1.1 to 8.1 mSv/y.     

Adsorption of Complex Pollutants from Aqueous Solutions by Nanocomposite Materials

In view of water pollutants becoming more complex, both anionic and cationic pollutants need to be removed. The multi‐pollutants simultaneous removal is paid more and more attention. Hence, development composite materials for treatment complex wastewater are the aim of this study. In this research, iron–nickel nanoparticles deposited onto aluminum oxide (α‐Al₂O₃) and carbon nanotubes (CNTs) to form nanocomposite materials Fe–Ni/Al₂O₃ and Fe–Ni/CNTs, respectively, were used as adsorbents. The adsorption capacities of Fe–Ni/Al₂O₃ and Fe–Ni/CNTs for AO7, HSeO, and Pb²⁺ were observed to be 5.46, 8.28, 27.02, and 25.6 mg/g, 15.29 and 17.12 mg/g, separately. The composite materials with negative charges were superior in adsorption of anionic pollutants. Using orthogonal experimental design and analysis of variance to co‐treat dye AO7, HSeO and Pb²⁺ in aqueous solutions, seven testing factors were included: (1) adsorbent types, (2) amount of iron, (3) solution pHs, (4) AO7 concentrations, (5) Pb²⁺ concentrations, (6) HSeO concentrations and (7) reaction time. The experimental results showed that the removal of complex pollutants AO7, HSeO, and Pb²⁺ on Fe–Ni/CNTs could reach up to 90% in the optimal treatment conditions. When using Fe–Ni/CNTs as the adsorbent, the sorption isothermals were well fitted in the Freundlich isotherm, and R² could reach up to 0.98.     

Geophysical techniques to aquifer locating and monitoring for industrial zones in North Hanoi, Vietnam

Geophysical methods were applied for hydrogeological targets in many countries including Vietnam. This paper presents results of using complex geophysical techniques as well as 2D electrical resistivity imaging (ERI), vertical electrical sounding (VES), very low frequency (VLF), and seismic refraction for geological structure investigation for locating the aquifers and assessing the hydrogeological conditions for groundwater potential in industrial zones of North Hanoi, Vietnam. The locations of two aquifers are determined by their depth and thickness on the basis of resistivity and seismic velocity values which were proved by stratifications of three boreholes to 40–60 m of depth on the study area. There are connections from surface water to shallow aquifer by hydraulic windows, as follows from VLF data. The deeper aquifer can be considered as a potential groundwater supply, but the water level is descending in time, as shown by hydrological monitoring. However, with careful use and by reducing sources of pollution, groundwater can continue to be an important natural resource for future.     

Topography of the Moho and earth crust structure beneath the East Vietnam Sea from 3D inversion of gravity field data

The Moho depth, crustal thickness and fault systems of the East Vietnam Sea (EVS) are determined by 3D interpretation of satellite gravity. The Moho depth is calculated by 3D Parker inversion from residual gravity anomaly that is obtained by removing the gravity effects of seafloor and Pre-Cenozoic sediment basement topographies from the free air anomaly. The 3D inversion solution is constrained by power density spectrum of gravity anomaly and seismic data. The calculated Moho depths in the EVS vary from 30–31 km near the coast to 9 km in the Central Basin. A map of the lithosphere extension factor in the Cenozoic is constructed from Moho and Pre-Cenozoic sediment basement depths. The fault systems constructed by the maximum horizontal gradient approach include NE-SW, NW-SE, and N-S oriented faults. Based on the interpretation results, the EVS is sub-divided into five structural zones which demonstrated the different characteristics of the crustal structure.     

Catchment storm runoff modelling using the geomorphologic instantaneous unit hydrograph

A lumped empirical model, the Geomorphologic Instantaneous Unit Hydrograph (GIUH) rainfall-runoff model, is developed for the Can Le catchment in the upstream region of the Sai Gon river Basin (Vietnam). This model can serve to simulate catchment runoff into the Dau Tieng Reservoir and can be used as a flood forecasting tool for the ungauged Can Le catchment. The GIUH couples geomorphology and hydrology quantitatively. The obtained Unit Hydrograph is based on Horton's morphometric parameters; bifurcation, length and area ratios. A new functionality within the ILWIS GIS-RS package, namely ‘DEM-hydro processing’, is applied to effectively process a Digital Elevation Model to extract these ratios from the drainage network. To supplement the limited field data available, various satellites images have been used such as ASTER, SRTM (Shuttle Radar Topography Mission) and METEOSAT 5. A short field campaign to collect missing ground data was executed between September and October 2005. The data collected included discharge (and stage – discharge curve), meteorological data, soil, land use information that are used for paramerisation, calibration and validation of the GIUH. The model was successfully applied for the Can Le catchment. Using the Horton's morphometric parameters derived from the DEM with estimated overland and stream flow velocities, the model is easy-to-use.     

Investigation of earthquake tsunami sources, capable of affecting Vietnamese coast

Based on the analysis of tectonic feature and geodynamic characteristics of regional faults systems in the southeast Asia, 9 source zones capable of generating tsunamis affecting Vietnamese coast were delineated in the South China Sea and adjacent sea areas. Statistical methods were applied to estimate the seismic hazard parameters for each source zone, which can be used for the detail tsunami hazard assessment in the future. Maximum earthquake magnitude is predicted for the Manila Trench (8.3?C8.7), the Sulu Sea (8.0?C8.4), and the Selebes Sea source zones (8.1?C8.5). Among the source zones, the Manila Trench, west of the Philippines is considered as a most potential tsunami source, affecting the Vietnamese coast. The estimated M _max values were used to develop simple scenarios (with a point source assumption) to calculate the tsunami travel time from each source zone to the Vietnamese coast. The results show that for the Manila Trench source zone, tsunami can hit the Vietnamese coast in 2?h at the earliest.     

The first peak ground motion attenuation relationships for North of Vietnam

The first attenuation relationships of peak ground acceleration (PGA) and peak ground velocity (PGV) for northern Vietnam are obtained in this study. Ground motion data are collected by a portable broadband seismic network in northern Vietnam as a part of cooperation between the Institute of Geophysics, Vietnamese Academy of Science and Technology, Vietnam and Institute of Earth Sciences, Academia Sinica, Taiwan. The database comprises a total of 330 amplitude records by 14 broadband stations from 53 shallow earthquakes, which were occurred in and around northern Vietnam in the period between 01/2006 and 12/2009. These earthquakes are of local magnitudes between 1.6 and 4.6, focal depths less than 30 km, and epicentral distances less than 500 km. The new attenuation relationships for PGA and PGV are:

log₁₀(PGA)=-0.987+0.7521M_L-log₁₀(R)-0.00475R,     

Image smoothing of multispectral imagery based on the HNN and geo-statistics

A new method for image down-scaling using geostatistical interpolation or smoothing based on the Hopfi eld Neural Network (HNN) and zero semivariance value is introduced. The method utilises the smoothing effect of the semivariogram matching process to produce the smoothened sub-pixel multispectral (MS) image with smaller RMSEs in comparison with the bilinear interpolation. In fact, the zero semivariograms increase the spatial correlation between the adjacent sub-pixels of the superresolution image. Containing higher spatial correlation, the resulting super-resolution MS image has smaller RMSEs compared with the original coarse image.     

PCBs in Central Vietnam coastal lagoons: levels and trends in dynamic environments

PCBs were analysed in surficial sediments and selected sediment cores collected between 2002 and 2008 in Central Vietnam coastal lagoons. The aim was to determine contamination levels and trends, and to evaluate the effects of anthropogenic pressures and natural events. Samples were mostly fine-grained with low total PCB concentrations (0.367-44.7 μg kg⁻¹). Atmospheric transport and post depositional processes modify to some degree the fingerprint of PCB inputs to the environment favouring the predominance of 3, 4 and 5 chlorinated congeners. The similarity of congener distributions in contemporary surficial samples also suggests the presence of a unique source over the entire study area, probably connected to mobilisation and long range transports from land-based stocks. The removal of consistent sediment layers is hypothesised based on repeated samplings of the same area. Natural meteorological events (such as typhoons) are suspected to be responsible for these sediment losses.     

Stable isotope-guided analysis of biomagnification profiles of arsenic species in a tropical mangrove ecosystem

We performed stable carbon and nitrogen-guided analyses of biomagnification profiles of arsenic (As) species, including total As, lipid-soluble As, eight water-soluble As compounds (arsenobetaine (AB), arsenocholine (AC), tetramethylarsonium ion (TETRA), trimethylarsine oxide (TMAO), dimethylarsinic acid (DMA), monomethylarsonic acid (MMA), arsenate (As[V]), and arsenite (As[III])), and non-extracted As in a tropical mangrove ecosystem in the Ba Ria Vung Tau, South Vietnam. Arsenobetaine was the predominant As species (65-96% of water-soluble As). Simple linear regression slopes of log-transformed concentrations of total As, As fractions or individual As compounds on stable nitrogen isotopic ratio (δ15N) values are regarded as indices of biomagnification. In this ecosystem, lipid-soluble As (slope, 0.130) and AB (slope, 0.108) were significantly biomagnified through the food web; total As and other water-soluble As compounds were not. To our knowledge, this is one of the first reports on biomagnification profiles of As compounds from a tropical mangrove ecosystem.