Deposition of semi-volatile organochlorine compounds in the free troposphere of the eastern North Atlantic Ocean

Deposition samples were taken at a height of 2367 m above sea level (m.a.s.l.) on the Island of Tenerife from May 1999 until July 2000 and analysed for 19 polychlorinated biphenyl (PCB) congeners, hexachlorobenzene (HCB), hexachlorocyclohexanes (HCH) and DDTs. This site is located above the inversion layer, so samples represent background concentrations of the free troposphere. The average deposition fluxes of HCB, total HCH, DDTs and PCBs were 86, 400, 110 and 780 ng m(-2) yr(-1), respectively, being lower than those reported at sea level in continental or marine areas. All compounds are generally found in higher abundance in the wet precipitation samples. However, these samples only represent a fraction, e.g. 33%, of the total deposition load. Annual mass balance calculations show that wet precipitation is essentially responsible for the deposition of the low molecular weight OC whereas dry deposition accounts for more than 50% of the higher molecular weight PCBs.     

A Pulsed Laser Photolysis-Resonance Fluorescence Kinetic Study of the Atmospheric Cl Atom-Initiated Oxidation of Propene and a Series of 3-Halopropenes at Room Temperature

Absolute rate coefficient measurements have been carried out for the reactions of Cl atoms with propene and a series of 3-halopropenes, at room temperature (298 ± 2) K using a newly constructed laser photolysis-resonance fluorescence (PLP-RF) system. The rate coefficients obtained (in units of cm³ molecule^–1 s^–1) are: propene (1.40± 0.24) ×10^–10, 3-fluoropropene (4.92 ± 0.42) ×10^–11, 3-chloropropene (7.47 ± 1.50) × 10^–11, 3-bromopropene (1.23± 0.14) ×10^–10 and 3-iodopropene (1.29± 0.15) ×10^–10. In order to test this new system, the reactions of Cl atoms with acetone and isoprene have also been studied and compared with data previously reported. The rate coefficients determined at room temperature for these last two reactions are (2.93 ± 0.20) ×10^–12 cm³ molecule^–1 s^{– 1} and (3.64± 0.20)×10^–10 cm³ molecule^–1 s^–1, respectively. The measured values were independent of pressure over the range 20–200 Torr. The influence of the different halogen atoms substituents on the reactivity of these alkenes with Cl atoms as well as the atmospheric implications of these measurements are studied and discussed for the first time in this work and compared with the reactivity with NO₃ and OH radicals.     

The hydrothermal system of Nevado del Ruiz volcano,Colombia

Hot springs and steam vents on the slopes of Nevado del Ruiz volcano provide evidence regarding the nature of hydrothermal activity within the summit and flanks of the volcano. At elevations below 3000 m, alkali-chloride water is discharged from two groups of boiling springs and several isolated warm springs on the western slope of Nevado del Ruiz. Chemical and isotopic geothermometers suggest that the boiling springs are fed by an aquifer having a subsurface equilibration temperature of at least 175°C, and the sampled warm spring is fed by an aquifer having a subsurface equilibration temperature near 150°C. Similarities in conservative solute ratios (e.g., B/Cl) indicate that the alkali-chloride waters may be related to a single reservoir at depth. Isotopic ratios of hydrogen and oxygen indicate that recharge for the alkali-chloride aquifers comes mostly from higher elevations on the volcano. Steam vents and steam-heated bicarbonate-sulfate springs at higher elevations, along a linear structural trend with the alkali-chloride springs, may be derived partly from the alkali-chloride water at depth by boiling. Steam from the vents (84°C) yields a gas geothermometer temperature of 209°C. Acid-sulfate-chloride and acid-sulfate waters are discharged widely from warm springs above 3000 m on the northern and eastern slopes of Nevado del Ruiz. Similarities in B/Cl and SO₄/Cl ratios suggest that the acid waters are mixtures of water from an acid-sulfate-chloride reservoir with various proportions of shallow, dilute groundwater. The major source of sulfate, halogens, and acidity for the acid waters may be high-temperature magmatic gases. Available data on hot spring temperatures and compositions indicate that they have remained fairly stable since 1968. However, the eruption of November 13, 1985 apparently caused an increase in sulfate concentration in some of the acid springs that peaked about a year after the eruption. Long-term monitoring of hot spring compositions over many years will be required to better define the effects of volcanic activity on the Nevado del Ruiz hydrothermal system.     

A paleomagnetic study of the Basque Arc (Basque-Cantabrian Basin,Western Pyrenees)

The Basque Arc constitutes the northern segment of the Basque-Cantabrian basin, in the western part of the Pyrenees. The main goal of the present study was to find out by means of paleomagnetic analysis if the arched shape of the Basque Arc has a primary origin, due to the development of sedimentary basins related to the opening of the Bay of Biscay or a secondary origin due to rotations about vertical axes. Nine volcanic flows of late Albian to Santonian age (100–83.5 My) were sampled together with 10 sedimentary sites (marls, limestones, calcarenites and sandstones) of lower Jurassic to early Eocene age in order to carry out paleomagnetic and rock-magnetic experiments, 15 paleodirections being obtained. In order to analyse these results together with data from previous studies, the studied area was subdivided into a western, a central and an eastern sector. While inclinations of all three sectors show a similar value, declinations differ. The western sector displays a 37 ± 16° clockwise rotation of its mean paleodeclination, the central sector is not rotated (4 ± 9°) and both sedimentary sites which make up the eastern sector show counter-clockwise rotations (−25 ± 11° and −68 ± 9°). These results suggest that the shape of the Basque Arc does not have a primary origin, but a secondary origin due to rotations about vertical axes as a result of differential shortening related to post-Lutetian compressive tectonics which resulted in the formation of the Pyrenees.     

Interprétation des cisaillements ductiles vers le NE dans les gneiss de Torrox (Complexe Alpujarride,Cordillères Bétiques)

Résumén

Les Gneiss de Torrox font partie de l’Unité de Sayalonga, appartenant au Complexe Alpujarride des Cordillères Bétiques (Espagne). Ils ont subi une déformation hétérogène par cisaillement simple, caractérisée par le développement de zones mylonitiques à pendage subhorizontal et de linéations d’étirement de direction N070°E. Nous interprétons ces linéations comme la direction de transport dans un contexte de chevauchements ductiles vers l’Kst-Nord-est. Ce sens de mouvement est très répandu dans les Alpujarrides, et permet de mieux comprendre que les nappes Alpujarrides occidentales soient plus métamorphiques que celles des Alpujarrides centrales et orientales.     

The discovery of scapolite marbles in the Biscay Synclinorium (Basque–Cantabrian basin, Western Pyrenees): geodynamic implications

We report the presence of scapolite marbles in the Biscay Synclinorium of the Basque–Cantabrian basin, the link between the mainland Pyrenees and the North Iberian palaeomargin. From their microstructures and mineral assemblages these marbles are correlated with similar marbles formed during the Cretaceous metamorphism representative of the North Pyrenean Zone. Their setting in an area with northward-verging structures leads us to propose a new location of the North Pyrenean Fault through the Basque–Cantabrian basin. Available geophysical information, gravity and magnetic anomalies, is better explained with this new proposal, which elucidates a major outstanding matter of Pyrenean geology.     

Multiple mechanisms driving detachment folding as deduced from 3D reconstruction and geomechanical restoration: the Pico del Águila anticline (External Sierras,Southern Pyrenees)

Three‐dimensional (3D) modelling allows observation of geological features that may not be evident by classical two‐dimensional approaches. This is particularly important in the Pico del Águila anticline (Central External Sierras, Southern Pyrenees, Spain), a structure characterized by important geometrical variability in 3D. The Pico del Águila is a N–S‐trending fold, transverse to the E–W‐trending South‐Pyrenean thrust front, with well‐exposed growth strata that record the evolution of the structure and the influence of the South‐Pyrenean thrust front. Fold kinematics is complex and not precisely quantified. It is characterized by multiple folding mechanisms acting simultaneously in a heterogeneous stratigraphic sequence. To better understand the fold's structural evolution, 3D reconstruction and geomechanical restoration of the structure were performed. The restoration takes into account rock mechanical properties without assuming a specific kinematic model. Our work suggests that the growth of the structure was characterized by variable uplift/sedimentation rates through time and between fold limbs. The restoration also reveals that a combination of multiple folding mechanisms operated simultaneously in different units and structural domains during anti‐clinal growth. This has major implications in the understanding of detachment folds with associated growth strata, as such structures are described in many settings as potential traps for hydrocarbons and natural resources.