Monitoring Large-Scale Tests for Nuclear Waste Disposal

Two large-scale “in situ” demonstration experiments and their instrumentation are described. The first test (FEBEX Experiment) involves the hydration of a compacted bentonite barrier under the combined effect of an inner source of heat and an outer water flow from the confining saturated granite rock. In the second case, the progressive de-saturation of Opalinus clay induced by maintained ventilation of an unlined tunnel is analyzed. The paper shows the performance of different sensors (capacitive cells, psychrometers, TDR’s) and a comparison of fill behaviour with modelling results. The long term performance of some instruments could also be evaluated specially in the case of FEBEX test. Capacitive sensors provide relative humidity data during long transient periods characterised by very large variations of suction within the bentonite.     

Middle Carboniferous crustal melting in the Variscan Belt: New insights from U–Th–Pbtot. monazite and U–Pb zircon ages of the Montagne Noire Axial Zone (southern French Massif Central)

In France, the Devonian–Carboniferous Variscan orogeny developed at the expense of continental crust belonging to the northern margin of Gondwana. A Visean–Serpukhovian crustal melting has been recently documented in several massifs. However, in the Montagne Noire of the Variscan French Massif Central, which is the largest area involved in this partial melting episode, the age of migmatization was not clearly settled. Eleven U–Th–Pb_tot. ages on monazite and three U–Pb ages on associated zircon are reported from migmatites (La Salvetat, Ourtigas), anatectic granitoids (Laouzas, Montalet) and post-migmatitic granites (Anglès, Vialais, Soulié) from the Montagne Noire Axial Zone are presented here for the first time. Migmatization and emplacement of anatectic granitoids took place around 333–326 Ma (Visean) and late granitoids emplaced around 325–318 Ma (Serpukhovian). Inherited zircons and monazite date the orthogneiss source rock of the Late Visean melts between 560 Ma and 480 Ma. In migmatites and anatectic granites, inherited crystals dominate the zircon populations. The migmatitization is the middle crust expression of a pervasive Visean crustal melting event also represented by the “Tufs anthracifères” volcanism in the northern Massif Central. This crustal melting is widespread in the French Variscan belt, though it is restricted to the upper plate of the collision belt. A mantle input appears as a likely mechanism to release the heat necessary to trigger the melting of the Variscan middle crust at a continental scale.     

Landslide detection and susceptibility mapping using LiDAR and an artificial neural network approach: a case study in the Cuyahoga Valley National Park,Ohio

The purpose of this study was to detect shallow landslides using hillshade maps derived from light detection and ranging (LiDAR)-based digital elevation model (DEM) derivatives. The landslide susceptibility mapping used an artificial neural network (ANN) approach and backpropagation method that was tested in the northern portion of the Cuyahoga Valley National Park (CVNP) located in northeast Ohio. The relationship between landslides and predictor attributes, which describe landform classes using slope, profile and plan curvatures, upslope drainage area, annual solar radiation, and wetness index, was extracted from LiDAR-based DEM using geographic information system (GIS). The approach presented in this paper required a training study area for the development of the susceptibility model and a validation study area to test the model. The results from the validation showed that within the very high susceptibility class, a total of 42.6 % of known landslides that were associated with 1.56 % of total area were correctly predicted. In contrast, the very low susceptibility class that represented 82.68 % of the total area was associated with 1.20 % of known landslides. The results suggest that the majority of the known landslides occur within a small portion of the study area, consistent with field investigation and other studies. Sample probabilistic maps of landslide susceptibility potential and other products from this approach are summarized and presented for visualization to help park officials in effective management and planning.     

激光拉曼光谱法分析多种显微组分荧光变化及其应用

利用激发488 nm激光的氩离子激光器作为RENISHAW inVia型激光拉曼光谱仪的光源,建立了多种显微组分荧光变化(FAMM)分析方法,并对镜质体反射率明显抑制的东营凹陷有效烃源岩进行了测定。结果表明,东营凹陷有效烃源岩的有机质类型越好,镜质体反射率抑制程度越高,有效烃源岩的真实成熟度应主要处于0.64%~1.30%,而不是实测镜质体反射率所反映的0.37%~1.10%。     

Containment criterion for contaminant isolation by cutoff walls

A rigorous solution is developed from first principles to guide the preliminary design of cutoff walls installed to contain the migration of contaminants from source zones. The full analytic solution is used to develop a criterion for determining the configuration and hydraulics of optimal wall designs. The solution is used to demonstrate the interaction between the properties of the wall, the Darcy flux, and the concentration of contaminants at the outside face of the well. For a particular wall design, the containment criterion can be used to estimate the long-term concentration that will develop at the outside face of the wall. Alternatively, for a given concentration on the outside face of the cutoff wall, the containment criterion can be used to estimate the Darcy flux required to balance the outward diffusion of contaminants. The results of numerical simulations are presented to evaluate the analytic approach. The numerical results confirm that for a wall with known transport properties, a specified Darcy flux is associated with a unique outside contaminant concentration.     

Activity-composition relations in the system CaCO3-MgCO3 predicted from static structure energy calculations and Monte Carlo simulations

Thermodynamic mixing properties and subsolidus phase relations of the rhombohedral carbonate system, (1 − x) · CaCO₃ − x · MgCO₃, were modelled in the temperature range of 623-2023 K with static structure energy calculations based on well-parameterised empirical interatomic potentials. Relaxed static structure energies of a large set of randomly varied structures in a 4 × 4 × 1 supercell of calcite (a = 19.952 Å, c = 17.061 Å) were calculated with the General Utility Lattice Program (GULP). These energies were cluster expanded in a basis set of 12 pair-wise effective interactions. Temperature-dependent enthalpies of mixing were calculated by the Monte Carlo method. Free energies of mixing were obtained by thermodynamic integration of the Monte Carlo results. The calculated phase diagram is in good agreement with experimental phase boundaries.     

Towards a quantitative model of downstream dilution of point source geochemical anomalies

The quantitative relation between point source soil geochemical anomalies and their response in stream sediments is linked through the concept of productivity (area × concentration). The equation proposed by Hawkes in 1976 is shown to be a subset of a wider range of equations proposed by Russian workers. These workers introduced two coefficients to account for the contrasting behaviour of different elements and the position of the soil anomaly within the drainage catchment. The calculation of these coefficients requires a series of samples downstream from the ending of anomalous soil input. The concept of productivity has particular application where multiple samples and anomalies are present in catchments. Plotting of productivity allows the discrimination of anomalous areas not detectable from raw element concentrations. The usefulness of these techniques is demonstrated from a small detailed stream sediment survey in NW Scotland. Dispersion from a gossan shows deviation from the Hawkes equation with the result that detailed sampling is required to detect soil anomalies. Plotting productivity allows the detection at the base of major slopes of anomalies that are diluted by upslope sediment.