Possible variation in methane flux caused by gas hydrate formation on the northeastern continental slope off Sakhalin Island, Russia

The Sakhalin Slope Gas Hydrate Project (SSGH) is an international collaborative effort by scientists from Japan, Korea, and Russia to investigate natural gas hydrates (GHs) that have accumulated on the continental slope off Sakhalin Island, Okhotsk Sea. From 2009 to 2011, field operations of the SSGH-09, -10, and -11 projects were conducted. GH-bearing and -free sediment cores were retrieved using steel hydro- and gravity corers. The concentrations of sulfate ions in sediment pore waters were measured to investigate sulfate concentration–depth profiles. Seventeen cores showed linear depth profiles of sulfate concentrations. In contrast, eight cores and two cores showed concave-up and -down profiles plausibly explained by sudden increase and decrease in methane flux from below, respectively, presumably caused by the formation of gas hydrate adjacent to the core sampling sites.     

Modeling the initial stage of the displacement of oil or gas in porous media

The initial stage of evolution of the displacement front is studied as a part of the nonlinear filtration model. Concentration and density profiles in the normal direction to the front are obtained. It turns out that the concentration changes relatively quickly, whereas the density rather slowly. The stability criterion of the displacement front is formulated. The conditions, under which the front retains the initial shape, are determined.     

A petrological and geochemical study on time-series samples from Klyuchevskoy volcano,Kamchatka arc

To understand the generation and evolution of mafic magmas from Klyuchevskoy volcano in the Kamchatka arc, which is one of the most active arc volcanoes on Earth, a petrological and geochemical study was carried out on time-series samples from the volcano. The eruptive products show significant variations in their whole-rock compositions (52.0–55.5 wt.% SiO₂), and they have been divided into high-Mg basalts and high-Al andesites. In the high-Mg basalts, lower-K and higher-K primitive samples (>9 wt.% MgO) are present, and their petrological features indicate that they may represent primary or near-primary magmas. Slab-derived fluids that induced generation of the lower-K basaltic magmas were less enriched in melt component than those associated with the higher-K basaltic magmas, and the fluids are likely to have been released from the subducting slab at shallower levels for the lower-K basaltic magmas than for higher-K basaltic magmas. Analyses using multicomponent thermodynamics indicates that the lower-K primary magma was generated by ~13% melting of a source mantle with ~0.7 wt.% H₂O at 1245–1260?°C and ~1.9 GPa. During most of the evolution of the volcano, the lower-K basaltic magmas were dominant; the higher-K primitive magma first appeared in AD 1932. In AD 1937–1938, both the lower-K and higher-K primitive magmas erupted, which implies that the two types of primary magmas were present simultaneously and independently beneath the volcano. The higher-K basaltic magmas evolved progressively into high-Al andesite magmas in a magma chamber in the middle crust from AD 1932 to ~AD 1960. Since then, relatively primitive magma has been injected continuously into the magma chamber, which has resulted in the systematic increase of the MgO contents of erupted materials with ages from ~AD 1960 to present.     

Carbon flows in the benthic food web at the deep-sea observatory HAUSGARTEN (Fram Strait)

The HAUSGARTEN observatory is located in the eastern Fram Strait (Arctic Ocean) and used as long-term monitoring site to follow changes in the Arctic benthic ecosystem. Linear inverse modelling was applied to decipher carbon flows among the compartments of the benthic food web at the central HAUSGARTEN station (2500 m) based on an empirical data set consisting of data on biomass, prokaryote production, total carbon deposition and community respiration. The model resolved 99 carbon flows among 4 abiotic and 10 biotic compartments, ranging from prokaryotes up to megafauna. Total carbon input was 3.78±0.31 mmol C m⁻² d⁻¹, which is a comparatively small fraction of total primary production in the area. The community respiration of 3.26±0.20 mmol C m⁻² d⁻¹ is dominated by prokaryotes (93%) and has lower contributions from surface-deposit feeding macro- (1.7%) and suspension feeding megafauna (1.9%), whereas contributions from nematode and other macro- and megabenthic compartments were limited to <1%. The high prokaryotic contribution to carbon processing suggests that functioning of the benthic food web at the central HAUSGARTEN station is comparable to abyssal plain sediments that are characterised by strong energy limitation. Faunal diet compositions suggest that labile detritus is important for deposit-feeding nematodes (24% of their diet) and surface-deposit feeding macrofauna (∼44%), but that semi-labile detritus is more important in the diets of deposit-feeding macro- and megafauna. Dependency indices on these food sources were also calculated as these integrate direct (i.e. direct grazing and predator–prey interactions) and indirect (i.e. longer loops in the food web) pathways in the food web. Projected sea-ice retreats for the Arctic Ocean typically anticipate a decrease in the labile detritus flux to the already food-limited benthic food web. The dependency indices indicate that faunal compartments depend similarly on labile and semi-labile detritus, which suggests that the benthic biota may be more sensitive to changes in labile detritus inputs than when assessed from diet composition alone. Species-specific responses to different types of labile detritus inputs, e.g. pelagic algae versus sympagic algae, however, are presently unknown and are needed to assess the vulnerability of individual components of the benthic food web.     

Hydrothermal synthesis of pyrochlores and their characterization

Pyrochlores, microlites, and U-betafites of pyrochlore group minerals were obtained from mixing experiments of the corresponding oxides and fluorides by hydrothermal synthesis at T = 800 °C and P = 200 MPa in the solution of 1.0 M NaF. The presence of U⁴⁺ in pyrochlore does not affect the cell parameter, which for the phases of pyrochlore–microlite series is 10.42 ± 0.01 Å. In a system with an excess of UO₂, pyrochlores and microlites, containing uranium up to 0.2–0.3 atoms per formula unit (apfu), are formed. In the uranium-free system of betafites composition, perovskites and Ti-bearing pyrochlores are formed. U-pyrochlores of betafite series, containing 2Ti = Nb + Ta in moles, have cubic cell parameters of 10.26 ± 0.02 Å and U⁴⁺ isomorphic capacity of 0.4–0.5 apfu. In the pyrochlore structure, U⁴⁺ may substitute for Ca²⁺ and Na⁺ cations in the eightfold site. In pyrochlores of pyrochlore–microlite series, Ca²⁺ is replaced by U⁴⁺, while in pyrochlores of betafite series, U⁴⁺ replaces Na⁺. Phases with pyrochlore structure, containing U⁵⁺ and U⁶⁺ in the sixfold site, usually occupied by Nb⁵⁺, Ta⁵⁺, and Ti⁴⁺, are formed under oxidizing conditions (Cu–Cu₂O buffer). They are characterized by low content of Nb⁵⁺, Ta⁵⁺ (<0.1 apfu), and anomalous behavior of the crystal lattice (compression, instead of expansion). Under natural conditions, the formation of pyrochlores containing a significant amount of U⁵⁺ and U⁶⁺ is unlikely.     

High-resolution modelling of a large-scale river plume

Evolution of a large-scale river plume is studied numerically using the Massachusetts Institute of Technology general circulation model. The model parameters were set close to those observed in the area of the Columbia River mouth. The fine-resolution grid along with the non-hydrostatic dispersion included in the model allowed for the reproduction of detailed inner plume structure, as well as a system of internal waves radiated from the plume’s boundary. It was found that not only first-mode but also second- and third-mode internal waves are radiated from the plume at the latest stages of its relaxation when the velocity of the front propagation drops below an appropriate wave phase speed of internal baroclinic mode. The model output shows that the amplitude of these high-mode waves is of the same order as the leading first-mode waves, which in combination with the specific vertical structure (location of the maximum structure function beyond the pycnocline layer) creates favourable conditions for the generation of shear instabilities. High-resolution model output also reveals evidence of a fine internal structure of the plume characterized by the presence of secondary fronts inside the plume and secondary internal wave systems propagated radially from the lift-off area to the outer boundary. These structures intensify the mixing processes within the propagating plume with predominance of the entrainment mechanism developing on the lower boundary between the plume’s body and underlying waters. The scheme of horizontal circulation in the plume was reproduced by the methodology of Lagrange drifters released near the mouth at different depths.     

Modelling tidally induced larval dispersal over Anton Dohrn Seamount

Massachusetts Institute of Technology general circulation model is used for the analysis of larval dispersal over Anton Dohrn Seamount (ADS), North Atlantic. The model output validated against the in situ data collected during the 136th cruise of the RRS ‘James Cook’ in May–June 2016 allowed reconstruction of the details of the baroclinic tidal dynamics over ADS. The obtained velocities were used as input data for a Lagrangian-type passive particle tracking model to reproduce the larval dispersal of generic deep-sea water invertebrate species. It was found that the residual tidal flow over ADS has a form of a pair of dipoles and cyclonic and anti-cyclonic eddies located at the seamount periphery. In the vertical direction, tides form upward motions above the seamount summit. These currents control local larval dispersal and their escape from ADS. The model experiment with a large number of particles (7500) evenly seeded on the ADS surface has shown that the trajectory of every individual particle is sensitive to the initial position and the tidal phase where and when it is released. The vast majority of the particles released above 1000 m depth remain seated in the same depth band where they were initially released. Only 8% of passive larvae were able to remain in suspension until competent to settle (maximise dispersal capability) and settle (make contact with the bottom) within the specified limits for this model. It was found that every tenth larval particle could leave the seamount and had a chance to be advected to any other remotely located seamount.     

Model studies of dense water overflows in the Faroese Channels

The overflow of dense water from the Nordic Seas through the Faroese Channel system was investigated through combined laboratory experiments and numerical simulations using the Massachusetts Institute of Technology General Circulation Model. In the experimental study, a scaled, topographic representation of the Faroe-Shetland Channel, Wyville-Thomson Basin and Ridge and Faroe Bank Channel seabed bathymetry was constructed and mounted in a rotating tank. A series of parametric experiments was conducted using dye-tracing and drogue-tracking techniques to investigate deep-water overflow pathways and circulation patterns within the modelled region. In addition, the structure of the outflowing dense bottom water was investigated through density profiling along three cross-channel transects located in the Wyville-Thomson Basin and the converging, up-sloping approach to the Faroe Bank Channel. Results from the dye-tracing studies demonstrate a range of parametric conditions under which dense water overflow across the Wyville-Thomson Ridge is shown to occur, as defined by the Burger number, a non-dimensional length ratio and a dimensionless dense water volume flux parameter specified at the Faroe-Shetland Channel inlet boundary. Drogue-tracking measurements reveal the complex nature of flow paths and circulations generated in the modelled topography, particularly the development of a large anti-cyclonic gyre in the Wyville-Thompson Basin and up-sloping approach to the Faroe Bank Channel, which diverts the dense water outflow from the Faroese shelf towards the Wyville-Thomson Ridge, potentially promoting dense water spillage across the ridge itself. The presence of this circulation is also indicated by associated undulations in density isopycnals across the Wyville-Thomson Basin. Numerical simulations of parametric test cases for the main outflow pathways and density structure in a similarly-scaled Faroese Channels model domain indicate excellent qualitative agreement with the experimental observations and measurements. In addition, the comparisons show that strong temporal variability in the predicted outflow pathways and circulations have a strong influence in regulating the Faroe Bank Channel and Wyville-Thomson Ridge overflows, as well as in determining the overall response in the Faroese Channels to changes in the Faroe-Shetland Channel inlet boundary conditions.     

Late Albian–Coniacian planktic foraminifera and biostratigraphy of the northeastern Caucasus

This paper presents a considerably revised biostratigraphy for Upper Albian through Coniacian pelagic limestone and shale sequences in the northeastern Caucasus region based primarily on planktic foraminiferal distributions. The use of concentrated acetic acid for the extraction of microfossils from the hard limestones has yielded a much more detailed planktic foraminiferal biostratigraphy than has been documented previously. Because of the low latitude location of the study area the high diversity assemblages contain many of the biomarkers used to identify standard Tethyan biozones ranging from the Rotalipora appenninica Zone through the Dicarinella concavata Zone. A key result of this study is the recognition of an apparently continuous Cenomanian/Turonian boundary interval within a laminated, dark marl that is enriched in organic carbon. Extinction of the single-keeled rotaliporids corresponds with the onset of deposition of the laminated marl beds.     

Numerical investigation of deep water circulation in the Faroese Channels

The overflow of dense water from the Nordic Seas through the Faroese Channels is investigated numerically using the Massachusetts Institute of Technology General Circulation Model. The model is forced by the removal of a barrier that separates different water masses in the bottom layer of the Faroe-Shetland Channel at the north-eastern boundary. An analysis of the output reveals that during its adjustment in the rotating channel the propagating flow is unstable and forms cyclonic and anti-cyclonic eddies in the Faroese Channels. The life-time of the cyclonic eddy is about 10 days, but an anti-cyclonic eddy that is formed upstream of the sill crest of the Faroe Bank Channel has a longer life-time. However, after 50 days it eventually loses its structure below 400 m due to the decay of a counter-rotating current. In the upper 400 m layer this anti-cyclonic eddy remains persistent for longer. Observational evidence of the eddy is confirmed by the tracks of experimental drifters released in the area and by the temperature and salinity fields observed in the Faroese Channels.The pinching of isotherms along the Wyville Thomson Ridge results in the concentration of cold water on the southern side of the Faroese Channels that overflows into the Rockall Trough. The model results demonstrate that the main part of the cold water outflows through the Faroe Bank Channel, rather than across the Wyville Thompson Ridge, due to Earth rotation. The apparent similarity of modelled temperature, salinity and velocity sections to recent measurements in this area adds confidence to these results.