Pore Water Characteristics Following a Release of Neat Ethanol onto Pre-existing NAPL

Neat ethanol (75.7 L) was released into the upper capillary zone in a continuous-flow, sand-packed aquifer tank (8.2 m³) with an average seepage velocity of 0.75 m/day. This model aquifer system contained a residual nonaqueous phase liquid (NAPL) that extended from the capillary zone to 10 cm below the water table. Maximum aqueous concentrations of ethanol were 20% v/v in the capillary zone and 0.08% in the saturated zone at 25 and 30 cm downgradient from the emplaced NAPL source, respectively. A bench-scale release experiment was also conducted for a similar size spill (scaled to the plan area). The concentrations of ethanol in ground water for both the bench- and pilot-scale experiments were consistent with advective–dispersive limited mass transfer from the capillary to the saturated zone. Concentrations of monoaromatic hydrocarbons and isooctane increased in the pore water of the capillary zone as a result of both redistribution of residual NAPL (confirmed by visualization) and enhanced hydrocarbon dissolution due to the cosolvent effect exerted by ethanol. In the tank experiment, higher hydrocarbon concentrations in ground water were also attributed to decreased hydrocarbon biodegradation activity caused by preferential microbial utilization of ethanol and the resulting depletion of oxygen. These results infer that spills of highly concentrated ethanol will be largely confined to the capillary zone due to its buoyancy, and ethanol concentrations in near-source zone ground water will be controlled by mass transfer limitations and hydrologic conditions. Furthermore, highly concentrated ethanol releases onto pre-existing NAPL will likely exacerbate impacts to ground water, due to NAPL mobilization and dissolution, and decreased bioattenuation of hydrocarbons.     

Consequences of change and variability in sea ice on marine ecosystem and biogeochemical processes during the 2007–2008 Canadian International Polar Year program

Change and variability in the timing and magnitude of sea ice geophysical and thermodynamic state have consequences on many aspects of the arctic marine system. The changes in both the geophysical and thermodynamic state, and in particular the timing of the development of these states, have consequences throughout the marine system. In this paper we review the ??consequences?? of change in sea ice state on primary productivity, marine mammal habitats, and sea ice as a medium for storage and transport of contaminants and carbon exchange across the ocean-sea-ice-atmosphere interface based upon results from the International Polar Year. Pertinent results include: 1) conditions along ice edges can bring deep nutrient-rich ??pacific?? waters into nutrient-poor surface waters along the arctic coast, affecting local food webs; 2) both sea ice thermodynamic and dynamic processes ultimately affect ringed seal/polar bear habitats by controlling the timing, location and amount of surface deformation required for ringed seal and polar bear preferred habitat 3) the ice edges bordering open waters of flaw leads are areas of high biological production and are observed to be important beluga habitat. 4) exchange of climate-active gases, including CO₂, is extremely active in sea ice environments, and the overall question of whether the Arctic Ocean is (or will be) a source or sink for CO₂ will be dependent on the balance of competing climate-change feedbacks.     

Holocene millennial/centennial‐scale multiproxy cyclicity in temperate eastern Australian estuary sediments

We have undertaken a comparative study of down‐core variation in multiproxy palaeoclimate data (magnetic susceptibility, calcium carbonate content and total organic carbon) from two coastal water bodies (Myall and Tuggerah Lakes) in temperate eastern Australia to identify local, regional and global‐forcing factors within Holocene estuarine sediments. The two lakes lie within the same temperate climate zone adjacent to the Tasman Sea, but are not part of the same catchment and drain different geological provinces. One is essentially a freshwater coastal lake whereas the other is a brackish back‐barrier lagoon. Despite these differences, data from two sites in each of the two lakes have allowed us to investigate and compare cyclicity in otherwise uniform, single facies sediments within the frequency range of 200–2000 years, limited by the sedimentation rate within the lakes and our sample requirements. We have auto‐ and cross‐correlated strong periodicities at ～360 years, ～500–530 years, ～270–290 years, 420–450 years and ～210 years, and subordinate periods of ～650 years, 1200–1400 years and ～1800 years. Our thesis is that climate is the only regionally available mechanism available to control common millennial and centennial scale cyclicity in these sediments, given the geographical and other differences. However, regional climate may not be the dominant effect at any single time and either location. Within the range of frequency spectral peaks we have identified, several fall within known long‐term periodical fluctuations of sun spot activity; however, feedback loops associated with short‐term orbital variation, such as Dansgaard–Oeschger cycles, and the relationship between these and palaeo‐ENSO variation, are also possible contributors. Copyright © 2005 John Wiley & Sons, Ltd.     

A Social–Ecological Systems Approach to Assessing Conservation and Fisheries Outcomes in Fijian Locally Managed Marine Areas

Locally managed marine areas (LMMAs) are often recommended as a strategy to achieve conservation and fisheries management, though few studies have evaluated their performance against these objectives. We assessed the effectiveness of eight periodically harvested closures (PHCs), the most common form of management within Fijian LMMAs, focusing on two outcomes: protection of resource units and biodiversity conservation. Of the eight PHCs, only one provided biodiversity benefits, whereas three were moderately successful in protecting resource units (targeted fish biomass). Protection of resource units was more likely when PHCs were harvested less frequently, less recently, and when total fish biomass in open areas was lower. Our findings further suggest that monitoring, enforcement, and clearly defined boundaries are critical, less frequent harvesting regimes are advised, and culturally appropriate management incentives are needed. Although PHCs have some potential to protect resource units, they are not recommended as a single strategy for broad-scale biodiversity conservation.     

Deep crustal source of gneiss dome revealed by eclogite in migmatite (Montagne Noire,French Massif Central)

In orogens worldwide and throughout geologic time, large volumes of deep continental crust have been exhumed in domal structures. Extension-driven ascent of bodies of deep, hot crust is a very efficient mechanism for rapid heat and mass transfer from deep to shallow crustal levels and is therefore an important mechanism in the evolution of continents. The dominant rock type in exhumed domes is quartzofeldspathic gneiss (typically migmatitic) that does not record its former high-pressure (HP) conditions in its equilibrium mineral assemblage; rather, it records the conditions of emplacement and cooling in the mid/shallow crust. Mafic rocks included in gneiss may, however, contain a fragmentary record of a HP history, and are evidence that their host rocks were also deeply sourced. An excellent example of exhumed deep crust that retains a partial HP record is in the Montagne Noire dome, French Massif Central, which contains well-preserved eclogite (garnet+omphacite+rutile+quartz) in migmatite in two locations: one in the dome core and the other at the dome margin. Both eclogites record P ~ 1.5 ± 0.2 GPa at T  ~  700 ± 20°C, but differ from each other in whole-rock and mineral composition, deformation features (shape and crystallographic preferred orientation, CPO), extent of record of prograde metamorphism in garnet and zircon, and degree of preservation of inherited zircon. Rim ages of zircon in both eclogites overlap with the oldest crystallization ages of host gneiss at c. 310 Ma, interpreted based on zircon rare earth element abundance in eclogite zircon as the age of HP metamorphism. Dome-margin eclogite zircon retains a widespread record of protolith age (c. 470–450 Ma, the same as host gneiss protolith age), whereas dome-core eclogite zircon has more scarce preservation of inherited zircon. Possible explanations for differences in the two eclogites relate to differences in the protolith mafic magma composition and history and/or the duration of metamorphic heating and extent of interaction with aqueous fluid, affecting zircon crystallization. Differences in HP deformation fabrics may relate to the position of the eclogite facies rocks relative to zones of transpression and transtension at an early stage of dome development. Regardless of differences, both eclogites experienced HP metamorphism and deformation in the deep crust at c. 310 Ma and were exhumed by lithospheric extension—with their host migmatite—near the end of the Variscan orogeny. The deep crust in this region was rapidly exhumed from ~50 to <10 km, where it equilibrated under low-P/high-T conditions, leaving a sparse but compelling record of the deep origin of most of the crust now exposed in the dome.     

Geostatistical Rock Physics Inversion for Predicting the Spatial Distribution of Porosity and Saturation in the Critical Zone

Mathematical Geosciences - Understanding the subsurface structure and function in the near-surface groundwater system, including fluid flow, geomechanical, and weathering processes, requires...     

Intercomparison and analyses of the climatology of the West African Monsoon in the West African Monsoon Modeling and Evaluation project (WAMME) first model intercomparison experiment

This paper briefly presents the West African Monsoon (WAM) Modeling and Evaluation Project (WAMME) and evaluates WAMME general circulation models’ (GCM) performances in simulating variability of WAM precipitation, surface temperature, and major circulation features at seasonal and intraseasonal scales in the first WAMME experiment. The analyses indicate that models with specified sea surface temperature generally have reasonable simulations of the pattern of spatial distribution of WAM seasonal mean precipitation and surface temperature as well as the averaged zonal wind in latitude-height cross-section and low level circulation. But there are large differences among models in simulating spatial correlation, intensity, and variance of precipitation compared with observations. Furthermore, the majority of models fail to produce proper intensities of the African Easterly Jet (AEJ) and the tropical easterly jet. AMMA Land Surface Model Intercomparison Project (ALMIP) data are used to analyze the association between simulated surface processes and the WAM and to investigate the WAM mechanism. It has been identified that the spatial distributions of surface sensible heat flux, surface temperature, and moisture convergence are closely associated with the simulated spatial distribution of precipitation; while surface latent heat flux is closely associated with the AEJ and contributes to divergence in AEJ simulation. Common empirical orthogonal functions (CEOF) analysis is applied to characterize the WAM precipitation evolution and has identified a major WAM precipitation mode and two temperature modes (Sahara mode and Sahel mode). Results indicate that the WAMME models produce reasonable temporal evolutions of major CEOF modes but have deficiencies/uncertainties in producing variances explained by major modes. Furthermore, the CEOF analysis shows that WAM precipitation evolution is closely related to the enhanced Sahara mode and the weakened Sahel mode, supporting the evidence revealed in the analysis using ALMIP data. An analysis of variability of CEOF modes suggests that the Sahara mode leads the WAM evolution, and divergence in simulating this mode contributes to discrepancies in the precipitation simulation.     

Sampling, Sample Preparation and ICP-MS Chemical Analysis of Lake Baikal Sponges

Procedures for sampling, sample preparation and ICP-MS analysis of endemic sponges from Lake Baikal have been developed. Sample decomposition was carried out using an open acid decomposition with ultrasound treatment. The distribution of nineteen elements (Mg, Al, P, Ca, Ti, Mn, Co, Ni, Cu, Rb, Sr, Y, Cd, Ba, La, Ce, Pb, Th and U) in different parts of a sponge's body (outer and inner layers and layers adjacent to the substratum) was studied. Detection limits were determined; these ranged from 0.013 to 4.12 μg g^-1 for trace elements and from 23 to 130 μg g^-1 for biogenic elements. The degree of elemental uptake by living substances is discussed with regard to the environment.     

Sampling soil water along the pF curve for δ2H and δ18O analysis

Soil water stable isotopes are widely used across disciplines (e.g., hydrology, ecology, soil science, and biogeochemistry). However, the full potential of stables isotopes as a tool for characterizing the origin, flow path, transport processes and residence times of water in different eco-, hydro-, and geological compartments has not yet been exploited. This is mainly due to the large variety of different methods for pore water extraction. While recent work has shown that matric potential affects the equilibrium fractionation, little work has examined how different water retention characteristics might affect the sampled water isotopic composition. Here, we present a simple laboratory experiment with two well-studied standard soils differing in their physico-chemical properties (e.g., clayey loam and silty sand). Samples were sieved, oven-dried and spiked with water of known isotopic composition to full saturation. For investigating the effect of water retention characteristics on the extracted water isotopic composition, we used pressure extractors to sample isotopically labelled soil water along the pF curve. After pressure extraction, we further extracted the soil samples via cryogenic vacuum extraction. The null hypothesis guiding our work was that water held at different tensions shows the same isotopic composition. Our results showed that the sampled soil water differed isotopically from the introduced isotopic label over time and sequentially along the pF curve. Our and previous studies suggest caution in interpreting isotope results of extracted soil water and a need to better characterize processes that govern isotope fractionation with respect to soil water retention characteristics. In the future, knowledge about soil water retention characteristics with respect to soil water isotopic composition could be applied to predict soil water fractionation effects under natural and non-stationary conditions. In this regard, isotope retention characteristics as an analog to water retention characteristics have been proposed as a way forward since matric potential affects the equilibrium fractionation between the bound water and the water vapour.