Geochemistry,provenance, and metamorphic evolution of Gabal Samra Neoproterozoic metapelites,Sinai, Egypt

Metapelites are exposed at Wadi Ba’ba, east of Abu Zenima city; represent the northwestern extension of the Fieran-Solaf Metamorphic Complex, Sinai Peninsula, Egypt. The metapelites are characterized by qtz + pl (An_24–28) + bt + grt ± crd ± sil mineral assemblage, indicating upper amphibolite facies with peak metamorphic conditions of 700 °C and pressures of 7 kbar, as determined by conventional geothermobarometeric methods. This resulted in incipient migmatization, forms patches of leucosomes and melanosomes. Geochemical investigation indicates that the precursor sediments of the metapelites had been deposited as immature Fe-rich shales from source materials of dominantly intermediate composition. Source area exhibited weak to moderate chemical weathering in a tectonically active continental marginal basin within a continental-arc system. A strong shallow-dipping foliation, characterizing the metapelites, was folded around an open antiform with sub-horizontal south plunging hinge.Phase equilibria calculations in the KFMASH system indicate that the peak metamorphic conditions formed at 730–750 °C and 6.8–7.9 kbar. This was followed by a retrogression formed at 770–785 °C and 3.9–4.5 kbar. Hence, this implies an isothermal decompression and rapid exhumation of the metapelites from depth (25–29 km) in the lower crustal level at peak conditions, continuous to include shallow to middle crustal level (14–17 km), at overprint retrograde conditions. Subsequent isobaric cooling took place at 720–750 °C and 3.6–4.5 kbar. The resulting isothermal decompression followed by isobaric cooling clockwise P–T path of the metapelites is more likely, in which the high-temperatures attained maximum conditions during isothermal decompression were enhanced by heat flux, due to the presence of an active magmatic arc that formed on top of subducting young lithosphere. This is supported by a moderate geothermal gradient of 27–43 °C/km and dating compatibility of the Sinai granitoids and the metamorphic complexes. The P–T path segment records the tectonothermal histories of crustal thickening as a result of the East and West Gondwana collision at the metamorphic peak. This was subsequent by extensional and crustal thinning with syn-metamorphic magmatic intrusions, during P–T path retrogression, which resulted in the final assembly of the Arabian–Nubian Shield during Neoproterozoic.     

Patterns in the local assembly of Egyptian rodent faunas: Co-occurrence and nestedness

We studied co-occurrence patterns of 29 rodents across 308 sites in Egypt to evaluate spatial variation and non-randomness in community assembly (co-occurrence and nestedness). There was strong evidence for negative species association in the entire fauna. Negative associations can be traced to habitat segregation among species, the discreteness of habitats, low species richness at local assemblages due to aridity and low primary productivity, and allopatry of sibling species. Nevertheless, high degree of nestedness characterizes the entire collection, as tested by BINMATNEST and Aninhado. Species ranks in the packed matrix were significantly correlated with incidence, total abundance, number of coexisting species, total number of species combinations, and range size. Analyses of the assemblages by region and sampling intensity using Aninhado simulations confirmed the nestedness for the whole fauna and showed little or no nested structure in species incidences.Egyptian rodent faunas appear to be structured by a dynamic interplay of biotic and abiotic factors operating on distinct sets of species with shared habitat preferences and requirements. Local assembly patterns may result from interspecific interactions coupled with aridity and low productivity, habitat requirements, and historical factors. The harsh conditions of these arid regions led to the prevalence of species exclusion.     

Taphonomic and diagenetic aspects of the Late Cretaceous Libycoceras ismaeli (Zittel) from Northern Jordan

Taphonomy and diagenesis of the ammonoid Libycoceras ismaeli (Zittel) have been approached in order to interpret the post-mortem depositional history during the Late Cretaceous of Jordan based on the comparative analysis of composition and taphonomy. The Campanian–Maastrichtian Al-Hisa Phosphorite Formation is exposed in northwestern and central Jordan is rich in cephalopods. It consists of alternating thin-bedded limestone, more or less silicified or calcified phosphorite layers, thick- and cross-bedded oyster lumachells, and lenses and layers of minable phosphate. The sphenodiscid ammonite L. ismaeli (Zittel) predominantly occurs in the middle part of this formation. L. ismaeli is associated with different nautiloid and baculitid species. The mode of occurrence of the studied ammonoids suggesting that they are best interpreted to been nektobenthic, not nektoplanktic. Taphonomic and diagenetic studies of transversely sliced specimens were carried out by means of polarizing and scanning electron microscope.     

Removal of zinc(II) from aqueous solutions using modified agricultural wastes: kinetics and equilibrium studies

In recent years, the need for safe and economical methods to eliminate heavy metals from contaminated waters has necessitated research on the production of low-cost alternatives to commercially available activated carbon. In the present work, in order to enhance the removal of heavy metals from contaminated water, Zizyphus vulgaris wastes were modified chemically to produce an adsorbent rich in carboxylic groups to enhance the removal of heavy metals from contaminated water. Adsorption of Zn(II) ions on the produced adsorbent was then optimized. The optimal ratio for esterification involved the treatment of Z. vulgaris wastes (1 g) with 0.0037 mmol malic acid in the presence of a very small amount of water for 2 h at 140 °C. The maximum values for adsorption capacity, q _max, were 28.7 and 164.6 mg/g on native and modified Z. vulgaris wastes, respectively, at pH 5 and 30 °C with a contact time 2 h and an initial metal ion concentration of 400 mg/L. The equilibrium data were well fitted by the Langmuir and Freundlich adsorption models and demonstrated the significant capacity for Z. vulgaris wastes in the removal of Zn(II) ions from aqueous solutions.     

Assessing the engineering properties of concrete made with fine dune sands: an experimental study

Sand dunes cover an area of 16.6% of the total area of Egypt. This paper presents the results of an extensive laboratory testing that was carried out to determine the engineering properties of concrete. The concrete fine aggregate is fine dune sands obtained from three sites in the Kharga Oasis, Western Desert, Egypt. All samples were classified as poorly graded sand according to the Unified Soil Classification system. Fineness modulus values of the studied dune sands range from 0.89 to 0.97. The percentage of sulfates and chlorides are very low and nearly negligible. Sodium and calcium hydroxides were recorded in some samples with scarce concentration. Organic impurities were not recorded. The degree of workability of the studied dune sands ranged from low to medium, which are suitable for normal reinforced work without vibration and heavily reinforced section with vibration. The measured compressive strength of concrete decreases with increasing dune sand content.     

Lead in drinking water and human blood in Riyadh City, Saudi Arabia

Concentrations of lead (Pb) in domestic water and blood plasma in the Olya and Al-Batha regions of Riyadh City, Saudi Arabia were correlated (r ²?=?0.03, p?<?0.0072 and r ²?=?0.37, p?<?0.00092, respectively). Greater concentrations of Pb in domestic water of Olya and Al-Batha (0.0119 and 0.03 mg/l, respectively) were greater than concentrations of Pb in bottled water and was also greater than the concentration of 0.01 mg Pb/l recommended by both the World Health Organization US Environmental Protection Agency (USEPA). In Al-Batha, 52.2 % of the population had concentrations of Pb in blood that exceeded 10 μg Pb/dl, which is the concentration used by USEPA to classify people as being at risk from effects of Pb. In Al-Batha, 17.5 and 22.5 % of the population exceeded 20–40 and >40 μg Pb/dl, respectively. In Olya, 37 and 10 % of the population had concentrations of Pb in blood that exceeded 10 and 20–40 μg Pb/dl, respectively, while none of the concentrations of PB exceeded 40 μg Pb/dl.     

Machine Learning Approach to Predict Sediment Load – A Case Study

In this study, a novel machine learning technique called the support vector machine (SVM) method is proposed as a new predictive model to predict sediment loads in three Malaysian rivers. The SVM is employed without any restriction to an extensive database compiled from measurements in the Muda, Langat, and Kurau rivers. The SVM technique demonstrated a superior performance compared to other traditional sediment‐load methods. The coefficient of determination, 0.958, and the mean square error, 0.0698, of the SVM method are higher than those of the traditional method. The performance of the SVM method demonstrates its predictive capability and the possibility of the generalization of the model to nonlinear problems for river engineering applications.     

Neoproterozoic podiform chromitites in serpentinites of the Abu Meriewa–Hagar Dungash district, Eastern Desert, Egypt: Geotectonic implications and metamorphism

Podiform chromitites hosted in serpentinites (after harzburgite and dunite) and talc‐carbonate rocks from the Abu Meriewa–Hagar Dungash district (MHD), Eastern Desert of Egypt, together with metagabbros, pillow metavolcanics, and metasediments, form an ophiolitic mélange formed during the Neoproterozoic Pan‐African Orogeny. The chromitites show massive, disseminated, and nodular textures. Chromite cores in chromitites have high and restricted ranges of Cr# (0.65–0.75) and Mg# (0.64–0.83), implying primary compositions not affected by metamorphism. Therefore, they are used as reliable indicators of parent magma composition and tectonic affinities of these highly metamorphosed rocks. On the contrary, the altered rims are high‐Cr, low‐Fe³⁺ spinel (rather than ferritchromit) enriched in Cr, Fe, and Mn, and depleted in Al and Mg (Cr# = 0.75–0.97, Mg# = 0.29–0.79), due to equilibration with interstitial silicates during regional metamorphism up to transitional greenschist–amphibolite facies at about 500–550°C. The primary chromite compositions suggest derivation from a high‐Mg tholeiitic, to possibly boninitic, parental magma in a supra‐subduction zone (arc–marginal basin) environment, similar to the spatially associated metavolcanic rocks. The MHD chromitites are most probably formed by melt–rock interaction mechanisms. The high Cr# of the investigated chromites suggests high degrees of partial melting of a depleted harzburgite source by interaction with primitive basaltic melt of deeper origin followed by mixing. Such Cr‐rich chromites are common in chromitites from the Eastern Desert of Egypt, implying broad thermal anomalies, possibly linked to an important geodynamic feature of the Arabian–Nubian Shield (ANS) evolution. This could revive interest in models that involve asthenospheric uprise, related to plume interaction or most probably due to oblique convergence of arc terranes during early evolution of the ANS.