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21.
N. V. Chukanov A. A. Mukhanova R. K. Rastsvetaeva D. I. Belakovsky S. M?ckel O. V. Karimova S. N. Britvin S. V. Krivovichev 《Geology of Ore Deposits》2011,53(7):583-590
Oxyphlogopite is a new mica-group mineral with the idealized formula K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2. The holotype material came from a basalt quarry at Mount Rothenberg near Mendig at the Eifel volcanic complex in Rhineland-Palatinate,
Germany. The mineral occurs as crystals up to 4 × 4 × 0.2 mm in size encrusting cavity walls in alkali basalt. The associated
minerals are nepheline, plagioclase, sanidine, augite, diopside, and magnetite. Its color is dark brown, its streak is brown,
and its luster is vitreous. D
meas = 3.06(1) g/cm3 (flotation in heavy liquids), and D
calc = 3.086 g/cm3. The IR spectrun does not contain bands of OH groups. Oxyphlogopite is biaxial (negative); α = 1.625(3), β = 1.668(1), and
γ = 1.669(1); and 2V
meas = 16(2)° and 2V
calc = 17°. The dispersion is strong; r < ν. The pleochroism is medium; X > Y > Z (brown to dark brown). The chemical composition is as follows (electron microprobe, mean of 5 point analyses, wt %; the ranges
are given in parentheses; the H2O was determined using the Alimarin method; the Fe2+/Fe3+ was determined with X-ray emission spectroscopy): Na2O 0.99 (0.89–1.12), K2O 7.52 (7.44–7.58), MgO 14.65 (14.48–14.80), CaO 0.27 ((0.17–0.51), FeO 4.73, Fe2O3 7.25 (the range of the total iron in the form of FeO is 11.09–11.38), Al2O3 14.32 (14.06–14.64), Cr2O3 0.60 (0.45–0.69), SiO2 34.41 (34.03–34.66), TiO2 12.93 (12.69–13.13), F 3.06 (2.59–3.44), H2O 0.14; O=F2 −1.29; 99/58 in total. The empirical formula is (K0.72Na0.14Ca0.02)(Mg1.64Ti0.73Fe0.302+ Fe0.273+Cr0.04)Σ2.98(Si2.59Al1.27Fe0.143+ O10) O1.20F0.73(OH)0.07. The crystal structure was refined on a single crystal. Oxyphlogopite is monoclinic with space group C2/m; the unit-cell parameters are as follows: a = 5.3165(1), b = 9.2000(2), c = 10.0602(2) ?, β = 100.354(2)°. The presence of Ti results in the strong distortion of octahedron M(2). The strongest lines of the X-ray powder diffraction pattern [d, ? (I, %) [hkl]] are as follows: 9.91(32) [001], 4.53(11) 110], 3.300(100) [003], 3.090(12) [112], 1.895(21) [005], 1.659(12) [−135], 1.527(16)
[−206, 060]. The type specimens of oxyphlogopite are deposited at the Fersman Mineralogical Museum in Moscow, Russia; the
registration numbers are 3884/2 (holotype) and 3884/1 (cotype). 相似文献
22.
23.
Matthieu?E.?GalvezEmail author Olivier?Beyssac Karim?Benzerara Nicolas?Menguy Sylvain?Bernard Simon?C.?Cox 《Contributions to Mineralogy and Petrology》2012,164(5):895-914
Understanding the mobility of chemical elements during fluid–rock interactions is critical to assess the geochemical evolution of a rock undergoing burial and metamorphism and, more generally, to constrain the geochemical budget of the subduction factory. In particular, determining the behavior and mobility of Ti in aqueous fluids constitutes a great challenge that is still under scrutiny. Here, we study plant fossils preserved in blueschist metasedimentary rocks from the Marybank Formation (New Zealand). Using scanning and transmission electron microscopies (SEM and TEM), we show that the carbonaceous material (CM) composing the fossils contains abundant nano-inclusions of Ti- and Fe-oxides. These nanocrystals are mainly anatase, rutile, and Fe–Ti oxides. The mineral composition observed within the fossils is significantly different from that detected in the surrounding rock matrix. We propose that Ti and Fe might have been mobilized by the alteration of a detrital Ti–Fe-rich protolith during an early diagenetic event under acidic and reducing conditions. Aqueous fluids rich in organic ligands released by the degradation of organic matter may have been involved. Moreover, using mass balance and petrological observations, we show that the contrasted mineralogy between the rock matrix and the fossil CM might be the consequence of the chemical isolation of fossil CM during the prograde path of the rock. Such an isolation results from the early formation of quartz and Fe-rich phyllosilicate layers enclosing the fossil as characterized by SEM and TEM investigations. Overall, this study shows that investigating minerals associated with CM down to the nanometer scale in metamorphic rocks can provide a precious record of early prograde geochemical conditions. 相似文献
24.
C. Lorz G. Abbt-Braun F. Bakker P. Borges H. B?rnick L. Fortes F. H. Frimmel A. Gaffron N. Hebben R. H?fer F. Makeschin K. Neder L. H. Roig B. Steiniger M. Strauch D. Walde H. Wei? E. Worch J. Wummel 《Environmental Earth Sciences》2012,65(5):1575-1586
Land-use/cover change (LUCC) and climate change are major controlling factors for water resources in the Distrito Federal in Western Central Brazil. Dynamic LUCC in the region has severe impacts on water resources, while climate changes during the last three decades is thought to have only moderate effects. LUCC affects water quantity mostly during base flow conditions. River basins with substantial expansion of agriculture since the end 1970s show a dramatic decrease of base flow discharge by 40?C70%, presumably due to irrigation. In contrast, the effects of urbanization on runoff are less distinct, since factors controlling runoff generation might be more variable. For water quality, we found urban areas to have a strong influence on the parameters CSB, NH4 +, and suspended solids. In addition, we assume emerging pollutants, e.g. organic (micro)pollutants, might play a major role in the future. The project IWAS-áGUA DF focuses on creating the scientific base to face these problems in frame of an IWRM concept for the region. Results of our study will be a contribution to an IRWM concept for the Distrito Federal and will help to maintain high standards in water supply for the region. 相似文献
25.
Y. Pousada-Ferradás S. Seoane-Labandeira A. Mora-Gutierrez A. Nú?ez-Delgado 《International Journal of Environmental Science and Technology》2012,9(1):21-29
The purpose of this work was to study the risks of water pollution due to the use of mixtures containing wood ash and sewage sludge. Mixtures including sludge and ash may be recycled as fertilizers, and they are economical as they do not integrate commercial limes, but Escherichia coli counts may keep significantly high in such mixtures, because their pH is not alkaline enough. In view of that, it seems interesting to study the E. coli survival in lixiviate from ash?Csludge mixtures including limes rather than from ash?Csludge mixtures alone. Two kinds of experiments were performed using laboratory column trials under saturated flow conditions. The first experiment investigated the chemical leaching behaviour of a mixture of 70% timber-industry wood ashes and 30% urban sewage sludge (% dry weight) at doses equivalent to 10 and 30?Mg/ha. The second experiment studied the survival of E. coli in lixiviates generated from 30?Mg/ha of a mixture consisting in 75% wood ash, 20% sewage sludge and 5% quicklime (% dry weight). In the first experiment, admixture of the ash and sludge achieved a stabilization of elements such as aluminium, iron, magnesium, nickle, carbon monoxide, cadmium, chromium and molybdenum that reduced their solubility compared with that in the ash or sludge alone. Significant solubilisation of heavy metals was not observed, with overall minor risk of chemical water pollution. In the second experiment, although including quicklime E. coli counts were still detected in the lixiviate, indicating risk of water contamination. 相似文献
26.
The rapid spread ofPhragmites australis in the coastal marshes of the Northeastern United States has been dramatic and noteworthy in that this native species appears to have gained competitive advantage across a broad range of habitats, from tidal salt marshes to freshwater wetlands. Concomitant with the spread has been a variety of human activities associated with coastal development as well as the displacement of nativeP. australis with aggressive European genotypes. This paper reviews the impacts caused by pure stands ofP. australis on the structure and functions of tidal marshes. To assess the determinants ofP. australis expansion, the physiological tolerance and competitive abilities of this species were examined using a field experiment.P. australis was planted in open tubes paired withSpartina alterniflora, Spartina patens, Juncus gerardii, Lythrum salicaria, andTypha angustifolia in low, medium, and high elevations at mesohaline (14‰), intermediate (18‰), and salt (23‰) marsh locations. Assessment of the physiological tolerance ofP. australis to conditions in tidal brackish and salt marshes indicated this plant is well suited to colonize creek banks as well as upper marsh edges. The competitive ability ofP. australis indicated it was a robust competitor relative to typical salt marsh plants. These results were not surprising since they agreed with field observations by other researchers and fit within current competition models throught to structure plant distribution within tidal marshes. Aspects ofP. australis expansion indicate superior competitive abilities based on attributes that fall outside the typical salt marsh or plant competition models. The alignment of some attributes with human impacts to coastal marshes provides a partial explanation of how this plant competes so well. To curb the spread of this invasive genotype, careful attention needs to be paid to human activities that affect certain marsh functions. Current infestations in tidal marshes should serve as a sentinel to indicate where human actions are likely promoting the invasion (e.g., through hydrologic impacts) and improved management is needed to sustain native plant assemblages (e.g., prohibit filling along margins). 相似文献
27.
A water quality model for the Patuxent estuary: Current conditions and predictions under changing land-use scenarios 总被引:1,自引:0,他引:1
A water quality model was developed for the Patuxent estuary using the modeling framework CE-QUAL-W2 (called W2) to address the impact of current and projected land-use changes (stress) on the water quality. The W2 code, supported by the Army Corps of Engineers Waterways Experiment Station, is a two-dimensional (longitudinalvertical) model designed for hydrodynamic and water quality simulations of reservoirs and estuaries. The code was configured for the Patuxent estuary using a finite-difference grid for the water column. Also incorporated into the model calculations are flow and nutrient load results from a watershed model. The integrated model was calibrated with data of 1 yr from 1997 to 1998 by matching results with measured temperature, dissolved oxygen, chlorophylla, and nutrient levels in the water column. The calibrated model was used to predict the water quality effects of different watershed land-use scenarios. Model projection results suggest that reductions of nutrient loads would lead to improvement of anoxic conditions in the bottom waters of the lower Patuxent estuary. 相似文献
28.
During the last two decades, there has been growing interest in the integration of existing ideas and data to produce new
synthetic models and hypotheses leading to discovery and advancement in estuarine and coastal science. This essay offers an
integrated definition of what is meant by synthesis research and discusses its importance for exploiting the rapid expansion
of information availability and for addressing increasingly complex environmental problems. Approaches and methods that have
been used in published synthetic coastal research are explored and a list of essential steps is developed to provide a foundation
for conducting synthetic research. Five categories of methods used widely in coastal synthesis studies are identified: (1)
comparative cross-system analysis, (2) analysis of time series data, (3) balance of cross-boundary fluxes, (4) system-specific
simulation modeling, and (5) general systems simulation modeling. In addition, diverse examples are used to illustrate how
these methods have been applied in previous studies. We discuss the urgent need for developing curricula for classroom and
experiential teaching of synthesis in coastal science to undergraduate and graduate students, and we consider the societal
importance of synthetic research to support coastal resource management and policy development. Finally, we briefly discuss
the crucial challenges for future growth and development of synthetic approaches to estuarine and coastal research. 相似文献
29.
Methylene blue and rhodamine 6G were used as molecular sensors for the spectrophotometric titrations of the aqueous colloids
of clay minerals (montmorillonite, illite and kaolinite). The dyes adsorbed on colloid particles form molecular aggregates,
which exhibit spectral properties significantly different from those of dye solutions. Spectrophotometric titrations provide
the most sensitive detection of smectites in aqueous colloids (sub-ppm concentrations); and the sensitivity further increases
using second derivative spectroscopy. The endpoint of spectrophotometric titrations can be used for the determination of exchange
capacity of the mineral in colloids and in this way to estimate its amount. The method is selective only to expandable clays,
which was proven by experiments with kaolinite and illite. Spectrophotometric titrations have promising future in the analysis
of clays and can be applied in many fields of geology, mineralogy, chemistry, material sciences or in industry. Its application
may expand to the analysis of other nanomaterials built from charged particles and exhibiting metachromasy in the systems
with organic dyes. 相似文献
30.
With the over-exploitation of water resources, water pollution and poor management of water infrastructures are exacerbated.
Ecosystem degradation is apparent at the basin level. The Tarim River Basin in northwest China has seen intensive confrontation
between environmental protection and economic development over the past five decades. Ambitious agricultural development and
land reclamation projects implemented by the Chinese government in the early 1960s led to several influences. For example,
the construction of dams like the Daxihaizi Reservoir disrupted the stream-flow to the lower reaches. Water resource reproducible
ability (WRRA) refers to the ability of water resources to be continually added by the natural water cycle. It includes the
supplementation of water quantity and the self-purification of water quality in the natural cycle of water resources. This
study discusses the WRRA index and introduces the computational method for calculating the WRRA index for the Tarim River
Basin. The following conclusions are observed: (1) from 1956 to 2005, the indices of WRRA in the Hotan River Basin, Yarkand
and Aksu River Basin are 0.26, 0.55, 0.58, respectively, which are between 0 and 1. The results indicate that the hydrological
cycle in these three sub-basins is in a reproducible state. (2) The WRRA index in the Kaidu-Kong River Basin is 1.23 > 1,
which indicates that floods may occur in the Kaidu-Kong River Basin. (3) The index of WRRA in the main stream is 0, which
indicates that the WRRA is very weak at this location, and zero-flow may occur. Calculating the WRRA of a basin can provide
a basis for corresponding basin water resources management. 相似文献