Compositional variability on the surface of 4 Vesta revealed through GRaND measurements of high‐energy gamma rays

Measurements of the high‐energy gamma‐ray flux emanating from asteroid 4 Vesta by the Dawn Gamma‐Ray and Neutron Detector (GRaND) have revealed variability in the near‐surface elemental composition of the Vestan surface. These observations are consistent with the presence of large (≥8 × 10⁴ km²) regions with distinct, HED‐like elemental compositions. The results agree broadly with other global measurements, such as the macroscopic neutron absorption cross section and spectral reflectance‐derived mineralogic maps. Two distinct regions with eucrite‐like elemental compositions have been identified, the first located primarily within the Lucaria and Marcia quadrangles and the second within Oppia quadrangle. The former region is collocated with some of the oldest, most heavily cratered terrain on Vesta. The interior of the 500 km diameter Rheasilvia impact basin is found to have a composition that is consistent with diogenite‐like material. Taken together, these observations support the hypothesis that Vesta's original crust was composed of basaltic outflows in the form of eucritic‐like material and that the Rheasilvia‐basin‐forming impact exposed lower‐crustal, diogenite‐like material. These measurements also constrain the maximum amount of mesosiderite‐like material to <10% for each 15 × 15° surface element.     

Removal of trace metals from seawater during a phytoplankton bloom as studied with sediment traps in Funka Bay,Japan

To study biological effects on the particulate removal of chemical elements from seawater, sediment trap experiments were carried out successively ten times throughout the spring phytoplankton bloom in Funka Bay. Sediment traps were deployed every one to two weeks at 1, 40 and 80 m depths. The settling particles obtained were analyzed for trace metals, phosphate and silicate. The propagation of diatoms in spring results in larger particulate fluxes than that of dinoflagellates. The biogenic silicate concentration is higher in the earlier period, when diatoms are predominant, than in the subsequent period, when dinoflagellates are predominant. The concentrations of aluminum, iron, manganese and cobalt in the settling particles comprising largely biogenic particles are lower during phytoplankton bloom. The concentration of copper is not reduced by the addition of biogenic particles, and its vertical flux is approximately proportional to the total flux, indicating that its concentration in the biogenic particles is nearly equal to that in the non-biogenic particles. The results for nickel and lead show the same tendency as for copper. Cadmium is more concentrated in biogenic particles than in non-biogenic particles, and the concentration of cadmium in the settling particles decreases with depth, similarly to phosphate and organic matter. Thus, metals in seawater are segregated by biological affinities, and the degree of incorporation into biogenic particles is in the order Cd > Pb, Ni, Cu > Co > Mn, Fe, Al. Biogenic particles are the most important agent controlling the vertical distribution of metals in the ocean. They remove the metals from the surface water, transport them through the water column, and regenerate them in the deep.     

Uranium in coastal sediments of Tokyo Bay and Funka Bay

The sediment cores from Tokyo Bay and Funka Bay were analyzed for U and its isotopic ratio,²³⁴U/²³⁸U, after dissolving them in 0.1 M HCl, and 30% H₂O₂ in 0.05 M HCl. A small fraction of U in the anoxic sediments was dissolved in 0.1M HCl and even the added yield tracer,²³²U, was lost. The isotopic ratio of H₂O₂ soluble U in the sediments was equal to that of seawater, suggesting that the H₂O₂ soluble U in the sediments is authigenic. The 6M HCl solution dissolved part of the lithogenic U besides the authigenic U. The depth profiles of U from the two bays resembled each other. The authigenic U comprised more than half of the total U even at the surface and increased with depth down to 70 cm, showing small maxima at about 20 cm. The concentration of refractory U was nearly constant with depth and similar to that of the pelagic sediments. The highest U concentration, 6 µg g^–1 which was about 5 times that of the pelagic sediments, was observed in the layer between 70 and 160 cm depth in Tokyo Bay. The annual sedimentation rates of U in the Tokyo Bay sediments were 2.6 tons at the surface and 7.0 tons at the 70–160 cm depth. The increase in U with depth should be due to the deposition of interstitial U either diffusing downward from the surface indicating the trapping of seawater U, or otherwise diffusing upward from the deeper layer indicating the internal cycling of U within the sediments.     

H 0 from an orientation-unbiased sample of Sunyaev–Zel'dovich and X-ray clusters

We have observed the Sunyaev–Zel'dovich (SZ) effect in a sample of five moderate-redshift clusters with the Ryle Telescope, and used them in conjunction with X-ray imaging and spectral data from ROSAT and ASCA to measure the Hubble constant. This sample was chosen with a strict X-ray flux limit using both the Bright Cluster Sample and the Northern ROSAT All-Sky Survey (RASS) cluster catalogues to be well above the surface brightness limit of the RASS, and hence to be unbiased with respect to the orientation of the cluster. This controls a major potential systematic effect in the SZ/X-ray method of measuring H ₀. Taking the weighted geometric mean of the results and including the main sources of error, namely the noise in the SZ measurement, the uncertainty in the X-ray temperatures and the unknown ellipticity and substructure of the clusters, we find   H ₀= 59⁺¹⁰₋₉ (random)⁺⁸₋₇(systematic) km s⁻¹ Mpc⁻¹  assuming a standard cold dark matter model with  Ω_M= 1.0, Ω_Λ= 0.0  or   H ₀= 66⁺¹¹₋₁₀ ⁺⁹₋₈ km  s⁻¹ Mpc⁻¹  if  Ω_M= 0.3, Ω_Λ= 0.7  .     

Complex Earthquake Cycle Simulations Using a Two-Degree-of-Freedom Spring-Block Model with a Rate- and State-Friction Law

Numerical simulations of complex earthquake cycles are conducted using a two-degree-of-freedom spring-block model with a rate- and state-friction law, which has been supported by laboratory experiments. The model consisted of two blocks coupled to each other and connected by elastic springs to a constant-velocity, moving driver. By widely and systematically varying the model parameters, various slip patterns were obtained, including the periodic recurrence of seismic and aseismic slip events, and several types of chaotic behaviour. The transition in the slip pattern from periodic to chaotic is examined using bifurcation diagrams. The model system exhibits typical period-doubling sequences for some parameter ranges, and attains chaotic motion. Simple relationships are found in iteration maps of the recurrence intervals of simulated earthquakes, suggesting that the simulated slip behaviour is deterministic chaos. Time evolutions of the cumulative slip distance in chaotic slip patterns are well approximated by a time-predictable model. In some cases, both seismic and aseismic slip events occur at a block, and aseismic slip events complicate the earthquake recurrence patterns.     

Development of new drain method for protection of existing pile foundations from liquefaction effects

Pile foundation as well as other underground structures could be seriously affected by soil liquefaction during strong earthquakes. Damages on pile foundation due to liquefaction can be reduced by implementation of some soil improvement method. Main objective of present study is developing of drain method that can improve the soil in order to mitigate the destructiveness of liquefaction on superstructure supported by pile foundation. Series of shaking table tests were conducted on 2×2 pile foundation and soil model was improved by drains. Configurations of drains around piles, intensity of shaking were one of the parameters that were changing during the tests in order to investigate the response of pile foundation in improved soil condition.Shaking table tests and performed On-site experiment showed the following effects of the new drain method. (1) When the intensity of earthquake motion is 200 gal or less, generation of excess pore water pressure is reduced and the pile bending moment is decreased, (2) when the intensity of earthquake motion is stronger (300 gal or more), drainage effect prevents disappearance of subgrade reaction, and (3) proposed new type of drain can control excess pore water pressure without clogging.     

Continuing observation of disturbed reproductive cycle and ovarian spermatogenesis in the giant abalone, Haliotis madaka from an organotin-contaminated site of Japan

Histological examination of gonads as well as chemical analysis of organotin compounds in tissues of the giant abalone, Haliotis madaka, was conducted to evaluate continuing endocrine disruption in abalone populations in Japan. Abalone specimens were collected from two different areas, Tsushima as a reference site and Jogashima as a site representative of declining abalone populations where serious organotin contamination had been observed, each month from January 1998 to March 1999. Scores were given to the development stages of reproductive cells in the ovary and testis. The degree of sexual maturation was evaluated by calculating the mean value of a histogram of these scores for the reproductive cells of each abalone. The temporal variations in degree of sexual maturation showed that female and male abalone from Tsushima matured synchronously, while those from Jogashima did not, which were similar to results of the previous study during September 1995–November 1996. Approximately 19% of the female abalone from Jogashima were masculinized with an ovo-testis, which was also similar to the result of the previous study. The masculinization of female abalone is reported to be induced by tributyltin (TBT) and triphenyltin (TPhT) from antifouling paints. Concentrations of the sum of butyltins (TBT, dibutyltin (DBT) and monobutyltin (MBT): ΣBTs) and the sum of phenyltins (TPhT, diphenyltin (DPhT) and monophenyltin (MPhT): ΣPhTs) in the muscle of abalone from Jogashima (n = 73) of 7.8 ± 9.0 ng/g wet wt. and 4.5 ± 6.8 ng/g wet wt., respectively, were significantly higher than those from Tsushima (n = 87) of 4.7 ± 4.9 ng/g wet wt. and 0.8 ± 1.7 ng/g wet wt., respectively (p < 0.05 for ΣBTs; p < 0.001 for ΣPhTs), although concentrations of TBT and TPhT in the muscle of abalone from Jogashima (n = 73) of 2.2 ± 2.5 ng/g wet wt. and 5.8 ± 5.1 ng/g wet wt., respectively, were insignificantly and significantly higher than those from Tsushima (n = 87) of 0.4 ± 0.6 ng/g wet wt. and 0.5 ± 0.9 ng/g wet wt., respectively, (p > 0.05 for TBT; p < 0.001 for TPhT). Thus, endocrine disruption as well as contamination by organotins in the giant abalone from Jogashima is still persisting.     

Characteristics of alkenones synthesized by a bloom of emiliania huxleyi in the Bering Sea

We investigated the characteristics of the alkenones produced by a bloom of Emiliania huxleyi in the eastern Bering Sea in 2000. Alkenones were detected in surface waters between 57°N and 63°N, where phosphate concentrations were low and the ammonium/nitrate ratio was high. The total alkenone content (C_37:2, C_37:3, and C_37:4) ranged from 22.0 to 349 μg g⁻¹ in suspended particles and from 0.109 to 1.42 μg g⁻¹ in surface sediments. This suggests that a large proportion of the particulate alkenones synthesized in the surface water rapidly degraded within the water column and/or at the water-sediment interface of the Bering Shelf. The change in the stable carbon isotopic composition (δ¹³C) of C_37:3 alkenone could not be explained only by variation in [CO₂(aq)] in the surface water but also depended on the growth rate of E. huxleyi. The alkenone unsaturation index (U^K′₃₇) was converted into an alkenone “temperature” with three equations [Prahl et al 1988], [Sikes et al 1997] and [Müller et al 1998]; Sikes et al.’s (1997) equation gave the best correlation with the observed sea surface temperature (SST) in the eastern Bering Sea. However, some temperatures estimated by Sikes et al.’s (1997) equation from the U^K′₃₇ varied from the observed SST, possibly because of the rapidly changing rate of alkenone synthesis in the logarithmic growth stage or the low rate of alkenone synthesis when nutrients were limiting. Temperatures estimated from U^K′₃₇ in the surface sediments (6.8-8.2°C) matched the observed SST in September (7-8°C) but differed from the annual average SST of 4 to 5°C, suggesting that most of the alkenone in the eastern Bering Sea was synthesized during limited periods, for instance, in September. The relative amounts of C_37:4 alkenone as proportions of the total alkenones (referred to as C_37:4%) were high, ranging from 18.3 to 41.4%. Low-salinity water (<32 psu) within the study area would have contributed to the high C_37:4% because a negative linear relationship between C_37:4% and salinity was found in this study.