Lithological and physical properties of core samples from the Sagara oil field: Oil occurrence in Sagara core samples

Abstract   A drilling and coring investigation of the Sagara oil field, central Honshu, Japan, was conducted to contribute to the understanding of hydrocarbon migration processes in a forearc basin. Core samples were analyzed to determine lithology, physical properties (specifically gas permeability) and the characteristics of oil occurrence. Gas permeability values greater than approximately 10⁻¹¹ m² constitute the basic precondition for any lithology to serve as a potential fluid conduit or reservoir in the Sagara oil field. Cores recovered from the 200.6-m-deep borehole were primarily composed of alternating siltstone, sandstone and conglomerate, all of which are correlated to the late Miocene Sagara Group. Both sandstone and conglomerate can be classified into two types, carbonate-cemented and poorly to non-cemented, based on matrix material characteristics. Oil stains are generally absent in the former lithology and more common in the latter. Variations in physical properties with respect to gas permeability values are directly related to the presence and character of carbonate cement, with higher permeabilities common in poorly to non-cemented rocks. The relationships between lithology, oil-staining, cementation and permeability indicate that cementation preceded oil infiltration and that cementation processes exerted significant control on the evolution of the reservoir.     

Oxygen isotope fractionation factors between anhydrite and water from 100 to 550°C

Oxygen isotope exchange between anhydrite and water was studied from 100 to 550°C, using the partial equilibrium method. The exchange rate was extremely low in NaCl solution. In the lower-temperature range, acid solutions were used to produce sufficient reaction to determine the oxygen isotope fractionation factors. The fractionation factors obtained in the present study are definitely different from those given by Lloyd [8]. They are similar to those for the HSO₄^?-water system studied by Mizutani and Rafter [19], and are consistently 2‰ higher than those of the barite-water system by Kusakabe and Robinson [5]. The temperature dependence of the oxygen isotope fractionation factors was calculated by the least squares method in which the weight was taken to be inversely proportional to the experimental error. The fractionation is given by:10³lnαanhydrite-water=3.21×(10³/T)²?4.72Available δ¹⁸O values of natural anhydrite were used to test the validity of this expression. It is shown that this newly revised geothermometer can be successfully applied to natural hydrothermal anhydrite.     

Distribution of <Emphasis Type="Italic">Nemopilema nomurai</Emphasis> in the southwestern Sea of Japan related to meandering of the Tsushima Warm Current

We investigated the horizontal distribution of Nemopilema nomurai medusae using a midwater trawl in the southwestern Sea of Japan from September to October of each year from 2006 to 2012. Numerous medusae of this species found in 2006, 2007, and 2009 were mainly distributed far (>40 km) from the mainland of Japan in the western part of the survey area, but were distributed in the stations closest (<25 km) to the mainland in the eastern part, particularly in 2006 and 2009. These distribution patterns were associated with the path of the second branch of the Tsushima Warm Current (TWC) that flows offshore to the west of Oki Islands and usually approaches the mainland of Japan to the east of Oki Islands. Differences in jellyfish distribution across the survey periods were related to the distribution of the second branch being associated with types, position and intensity of eddies in the eastern part of the survey area. Hence, the formations of eddies and consequent variation in the path of the TWC would be responsible for transporting medusae from offshore to near the mainland to the east of Oki Islands. Individuals with large bells accumulated in the northwestern part of the survey area, where a cyclonic eddy was present downstream of the third branch of the TWC. This variation in bell size distribution may be ascribed to differences in the physical and/or biological factors among the three branches of the TWC.     

Nature of the Ore-Forming Fluid at the Quaternary Noya Gold Deposit in Kyushu,Japan

We discuss the nature of the ore-forming hydrothermal fluid in the Noya gold-bearing calcite-quartz-adularia veins of central Kyushu, Japan on the basis of oxygen, carbon, and strontium isotope ratios, and aqueous speciation calculations for the present-day geothermal fluid. The isotopic values of the Noya ore-forming fluid were estimated to be −6.5‰ for δ¹³C and −7.5‰ for δ¹⁸O. The oxygen isotopic equilibrium temperatures for vein calcite are more than 180°C at the bottom of the Noya mineralization zone, and decrease with increasing elevation. As the temperature decreased, the dominant carbon species in the fluid changed from H₂CO₃ to HCO₃^- at about 120°C. The equilibrium temperatures for vein quartz are consistent with the calcite calculations. The carbon and oxygen isotope trends of the Noya vein calcite and the isotope ratios of strontium suggest that the fluids that precipitated the Noya veins were controlled by an andesite-dominated geology. Chondrite-normalized REE patterns for the white-colored veins from wells 51-WT-1 and 51-WT-2 displayed a light REE-rich pattern with positive Eu anomalies, suggesting the existence of a reducing environment for the fluid. The pyrite-rich gray-colored veins and a silicified rock from well 51-WT-2 showed higher REE concentrations than did the white veins. Altered host andesitic rocks have similar REE patterns to that of the silicified rock, and have higher REE contents than the others in the drill cores. Aqueous speciation calculations showed that the fluid in the hydrothermal reservoir is currently in muscovite stability. The fluid at the ore-mineralization stage may have contained more potassium or have had a higher pH, so that adularia precipitated with calcite and quartz, as well as gold. Fluid boiling at depth in the system produced the gold-bearing calcite-quartz-adularia veins.     

Total organic carbon and nitrogen contents in surface sediments of Harima Nada,eastern Seto Inland Sea,Japan: a comparison under two different trophic states

Phytoplankton abundance in the surface waters of Harima Nada, eastern Seto Inland Sea of Japan, decreased after around the late 1970s following a reduction of terrestrial phosphorous inputs, and relatively low levels persisted thereafter. This symptom of de-eutrophication in recent decades might have reduced organic matter storage in surficial sediments. To test this possibility, we examined total organic carbon (TOC) and nitrogen (TN) contents of Harima Nada sediments in 2011, and compared the results to past data from more eutrophic states. In 2011, the TOC and TN varied horizontally within the basin, in relation to physicochemical properties (water and mud content) and phytoplankton remnants (pheo-pigments) of the sediments. These horizontal patterns were fundamentally similar to those of the early 1980s (1982–1983), although discrepancies between the periods were observed in some areas. Differences of mean TOC and TN in the 0–2 cm layer at 63 stations from 1982–1983 to 2011 were consequently <10 %. Hence, the recent de-eutrophication in Harima Nada was associated with little overall change of TOC and TN storage in the sediment. In Harima Nada, changes in water clarity and particle size composition of the sediment seem to have occurred during recent decades. The aforementioned paradoxical phenomenon may therefore be explained by factors that are affected by these environmental changes. Such factors include the ratio of export flux to the seafloor to phytoplankton production, phytoplankton biomass and production in the entire euphotic zone, and accumulation rate of surface sediment.     

Relations between load and settlement of circular foundations on or in a dense sand expressed by a function of diameter and depth

When load acts on a circular foundation on or in a dense sand, average contact pressure on the lower surface of the foundation is q and settlement of the foundation is s. Diameter and depth of the foundation are B and D_f. When the sand, B and D_f are given, we can know the relation between q and s/B by, e.g. a loading test, i.e. the relation is determined by B and D_f for the sand. Using the results of numerical analyses, we express a relation between q and s/B up to s=0.1B by functions of a single variable which is a linear combination of B and D_f. Consequently when two foundations have different B's and different D_f's but have the same value of the variable, the relations are the same. Then we examine whether the functions can express the results of eleven tests of model foundations of wide range of B and/or D_f. In all the tests, the relations are expressed with sufficient accuracy. Copyright © 2005 John Wiley & Sons, Ltd.     

Evaluation of urban thermal environments in commercial and residential spaces in Okayama City, Japan, using the wet-bulb globe temperature index

We estimated wet-bulb globe temperature (WBGT) using measured meteorological data to understand the bioclimates of human living spaces during the summer season. Our research focused on commercial and residential areas of Okayama City, Japan (population ～700,000). The commercial spaces (CO) mainly consisted of multi-story office buildings, whereas the residential spaces (RE) consisted of one- or two-story residential buildings. On a fine day with southeast winds, the spatially averaged WBGT measured in the CO was higher than that in the RE. The difference was statistically significant and would have caused noticeable discomfort and a high risk of heat disorder for occupants of the CO over the long term. For instance, at 1900 Japan Standard Time (JST), the maximum difference in the WBGT between the CO and RE sites was 2.0°C (23.5°C for the CO and 21.5°C for the RE). From 1800 to 1900 JST, the wet-bulb temperature in the CO was still 1.5–2.0°C higher than that in the RE, even though both areas had the same dry-bulb temperature. This indicates that the CO retained greater amounts of water vapor for longer periods compared to the RE. The wet-bulb temperature in the CO increased rapidly at most observation points when the southeast sea breeze arrived. In contrast, in the RE, the wet-bulb temperature decreased until evening. This difference was caused by moist air transported from a river about 1 km upwind from the CO. The moist air forced an increase in the WBGT and elevated the risk of heat disorder in the CO. The spatially averaged globe temperature of the CO at 1500 JST was 6.2°C lower than that at the RE, causing the WBGT of the CO to decrease. The results suggest that the higher WBGT in the CO was caused by higher wet-bulb temperatures. On a day with southwest winds, the CO and RE showed no difference in WBGT because the river was not included in the upwind source area.     

Seasonal variation of volatile organic iodine compounds in the water column of Funka Bay,Hokkaido, Japan

Volatile organic iodine compounds (VOIs) emitted from the ocean surface to the air play an important role in atmospheric chemistry. Shipboard observations were conducted in Funka Bay, Hokkaido, Japan, bimonthly or monthly from March 2012 to December 2014, to elucidate the seasonal variations of VOI concentrations in seawater and their sea-to-air iodine fluxes. The bay water exchanges with the open ocean water of the North Pacific twice a year (early spring and autumn). Vertical profiles of CH₂I₂, CH₂ClI, CH₃I, and C₂H₅I concentrations in the bay water were measured bimonthly or monthly within an identified water mass. The VOI concentrations began to increase after early April at the end of the diatom spring bloom, and represented substantial peaks in June or July. The temporal variation of the C₂H₅I profile, which showed a distinct peak in the bottom layer from April to July, was similar to the PO₄ ^3? variation profile. Correlation between C₂H₅I and PO₄ ^3? concentrations (r = 0.93) suggests that C₂H₅I production was associated with degradation of organic matter deposited on the bottom after the spring bloom. CH₂I₂ and CH₂ClI concentrations increased substantially in the surface and subsurface layers (0–60 m) in June or July resulted in a clear seasonal variation of the sea-to-air iodine flux of the VOIs (high in summer or autumn and low in spring).     

亚洲通量观测网建立的回顾与展望

1IntroductionTheelucidationofthebudgetsofcarbon,waterandothermassesatvariouslandecosystemshasbecomeanimportantsubjectintheglobalwarmingissue.Forthisstudy,thedatafrompreciseandlong-termobservationsofcarbondioxide,watervapor,andheatfluxtakeninvariouslandsur…     

原地应力状态三维分布估算方法的发展及初步应用

日本原子能机构(Japan Atomic Energy Agency)提出了一种方法,即通过地表原地应力测量所得的有限数据精确估算任意一点的实际原地应力状态分布.我们假定实际地应力是由上覆岩层压力和板块构造力的综合作用形成的,并建立了两种模型:三维有限元模型和边界元模型,模型考虑了地质情况的不均匀性,如岩石类型的变化和...