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21.
Jochen Vogl Yong‐Hyeon Yim Kyoung‐Seok Lee Heidi Goenaga‐Infante Dmitriy Malinovskiy Sarah Hill Tongxiang Ren Jun Wang Robert D. Vocke Karen E. Murphy Naoko Nonose Olaf Rienitz Janine Noordmann 《Geostandards and Geoanalytical Research》2019,43(1):23-37
Lead isotope amount ratios are commonly used in diverse fields such as archaeometry, geochemistry and forensic science. Currently, five reference materials with certified lead isotope amount ratios are available, namely NIST SRM 981, 982 and 983, GBW‐04442 and NMIJ 3681‐a. Only NIST SRM 981 and NMIJ 3681‐a have approximately natural isotopic compositions, and NIST SRM 981 is predominantly used for correcting mass discrimination/mass fractionation in the applied mass spectrometric procedures. Consequently, there is no other certified reference material available to be used for validation and/or quality control of the analytical procedures applied to lead isotope amount ratio measurements. To fill this gap, two new reference materials have been produced and certified for their lead isotope amount ratios. For both certified reference materials, complete uncertainty budgets have been calculated and SI traceability has been established. This provides the users with independent means for validating and verifying their analytical procedures and for conducting quality control measures. ERM‐EB400 is a bronze material with a nominal lead mass fraction of 45 mg kg?1 and certified lead isotope amount ratios of n(206Pb)/n(204Pb) = 18.072(17) mol mol?1, n(207Pb)/n(204Pb) = 15.578(18) mol mol?1 and n(208Pb)/n(204Pb) = 38.075(46) mol mol?1 with the associated expanded uncertainties (k = 2) given in brackets. ERM‐AE142 is a high‐purity solution of lead in 2% nitric acid with a nominal mass fraction of 100 mg kg?1 and certified Pb isotope amount ratios of n(206Pb)/n(204Pb) = 21.114(17) mol mol?1, n(207Pb)/n(204Pb) = 15.944(17) mol mol?1 and n(208Pb)/n(204Pb) = 39.850(44) mol mol?1 with the associated expanded uncertainties (k = 2) given in brackets. Both materials are specifically designed to fall within the natural lead isotopic variation and to assist users with the validation and verification of their analytical procedures. Note that while one of these reference materials requires the chemical separation of Pb from its matrix (ERM‐EB400), the other does not (ERM‐AE142). As additional information, δ208/206PbNIST SRM981 values are provided for both materials. For ERM‐AE142, a delta value of δ208/206PbNIST SRM981 = ?28.21(30)‰ was obtained, and for ERM‐EB400, a delta value of δ208/206PbNIST SRM981= ?129.47(38)‰ was obtained, with the associated expanded uncertainties (k = 2) given in brackets. 相似文献
22.
Marryanna Lion Yoshiko Kosugi Satoru Takanashi Shoji Noguchi Masayuki Itoh Masanori Katsuyama Naoko Matsuo Siti‐Aisah Shamsuddin 《水文研究》2017,31(24):4338-4353
To evaluate water use and the supporting water source of a tropical rainforest, a 4‐year assessment of evapotranspiration (ET) was conducted in Pasoh Forest Reserve, a lowland dipterocarp forest in Peninsular Malaysia. The eddy covariance method and isotope signals of rain, plant, soil, and stream waters were used to determine forest water sources under different moisture conditions. Four sampling events were conducted to collect soil and plant twig samples in wet, moderate, dry, and very dry conditions for the identification of isotopic signals. Annual ET from 2012 to 2015 was quite stable with an average of 1,182 ± 26 mm, and a substantial daily ET was observed even during drought periods, although some decline was observed, corresponding with volumetric soil water content. During the wet period, water for ET was supplied from the surface soil layer between 0 and 0.5 m, whereas in the dry period, approximately 50% to 90% was supplied from the deeper soil layer below 0.5‐m depth, originating from water precipitated several months previously at this forest. Isotope signatures demonstrated that the water sources of the plants, soil, and stream were all different. Water in plants was often different from soil water, probably because plant water came from a different source than water that was strongly bound to the soil particles. Plants showed no preference for soil depth with their size, whereas the existence of storage water in the xylem was suggested. The evapotranspiration at this forest is balanced and maintained using most of the available water sources except for a proportion of rapid response run‐off. 相似文献
23.
Keiko Sasaki Yoshitaka Uejima Atsushi Sakamoto Qianqian Yu Junichiro Ishibashi Naoko Okibe Tsuyoshi Hirajima 《Resource Geology》2013,63(2):155-165
Microbiological contribution to the formation of the manganese deposits in Sambe hot springs, Shimane, was investigated in combination with water chemistry, characterization of sediments and microbial community structure. Analysis of bacterial and fungal community structure based on DNA extracted from a Mn‐oxidizing enrichment culture indicated close matches with Pseudomonas putida, Phoma sp. and Plectosphaerella cucumerina, all Mn‐oxidizing microorganisms. These sediments were poorly crystalline and formed at neutral pH values, which is characteristic of biogenic precipitates. The EPMA results demonstrated a positive correlation between Mn and Ba contents in well‐crystalline Mn oxide grains. Substantial Ba contents were observed inside Mn oxide grains. These findings indicated that Ba contents in sediments are influenced by not only aqueous Ba2+ concentrations but also crystallinity of biogenic birnessite. Barium would be incorporated in birnessite during biomineralization. 相似文献
24.
Takako Masuda Ken Furuya Naoko Kohashi Mitsuhide Sato Shigenobu Takeda Makoto Uchiyama Naho Horimoto Takashi Ishimaru 《Journal of Oceanography》2010,66(6):801-813
Phytoplankton dynamics in the lower euphotic zone were observed by tracking a subsurface water released at 20-m depth from
Takumi, an artificial upwelling device. Takumi continually discharged seawater pumped up from a depth of 205 m: this water was mixed with 5-m depth water to adjust the
density to that of 20-m depth water of Sagami Bay, Japan. The discharged water was pulse-labeled at Takumi with uranine and tracked for 63.9 h with a drifting buoy equipped with a drogue at 20-m depth. We present a simple model
to estimate in situ phytoplankton net growth rates from temporal changes in phytoplankton abundance in the discharged water with correction for
the influence of water exchange between the discharged water and neighboring layers. Lagrangian observation showed active
growth of pico- and nanophytoplankton, especially cryptophytes and Synechococcus (Cyanobacteria), in the subsurface layer. In contrast, diatoms grew little in spite of micromolar concentrations of nutrients.
The active growth of pico- and nanophytoplankton was in good agreement with shipboard serial dilution culture experiments.
The low growth activity of diatoms was suggested to be related to low light availability in the subsurface layer. 相似文献
25.
Estimation of particulate organic carbon flux in relation to photosynthetic production in a shallow coastal area in the Seto Inland Sea 总被引:3,自引:0,他引:3
Sediment trap experiments were carried out three times from 1999 to 2000, in the western part of the Seto Inland Sea (Suo-Sound), Japan. We investigated both the particulate flux and the composition of chemical substances in the sediment trap samples. Based on the results, we discuss the origin of particulate organic carbon (POC) collected by the sediment traps in a coastal area. Moreover, we purposed to estimate the flux of the portion of the POC that is derived from phytoplankton photosynthesis. The fluxes of POC varied between 677 and 3424 mgC m(-2) d(-1). Significant positive correlations between POC and aluminum (Al) fluxes suggested that these components show almost the same behaviour. The mean value of the Al flux was about eight times higher than that of Al burial rates on the sediment surface. Therefore, it seems that the POC flux observed with the sediment traps was considerably overestimated. Moreover, judging from the fact that Al is a typical terriginous element, it seems that most of the POC collected in the sediment traps derived from the re-suspended surface sediment or sediment transported laterally from shallow flanks such as intertidal mudflats. The fluxes of chlorophyll a (Chl a) were independent of the POC fluxes, and a relatively consistent correlation was found between Chl a abundance in the water column and the Chl a flux. Moreover, surface sediment Chl a content was approximately 100 times lower than that of suspended matter. Therefore, resuspension and terriginous contributions to Chl a collected in sediment traps are likely to be negligible. The POC content in the trap samples varied between 22.4 and 70.7 mg g(-1) dry weight. The variations of POC contents were positively correlated with the Chl a contents: POC(mg g(-1))=76.5 x Chl a(mg g(-1)) + 26.0 (r=0.95, p<0.01, n=9). This result shows that POC contents strongly corresponded with phytoplankton and their debris. It was also considered that the fraction of POC derived from phytoplankton primary production could be estimated as Chl a content times a certain factor. In this study, we estimated the flux of the portion of the POC originating from phytoplankton production by multiplying the Chl a fluxes by 76.5 (the mean POC:Chl a ratio in the trap samples). These values varied between 308 and 758 mgC m(-2) d(-1), and accounted for 35.1+/-21.2% of total POC flux. Although the amount of POC that originates from phytoplankton photosynthesis was a small portion of total POC flux, it seems to be a large portion of potential primary production in the water column. 相似文献
26.
It has been frequently observed that the ferromagnetic minerals in volcanic rocks may undergo some physical/chemical changes when they are heated in a laboratory. For paleointensity determinations, it is therefore desirable to use the Thellier method, in which internal consistency of the data assures that such undesirable changes did not take place in a particular sample. The most serious drawback of this method is that it requires a considerable number of heatings and coolings and measurements of the remanent magnetization. Following a suggestion of Kono, a modified version of Thellier's technique was developed and applied to a historical lava flow of Hawaii and Oligocene rhyolites and welded tuffs of San Juan volcanic field, Colorado, U.S.A. Samples were heated only once to each temperature and cooled under a magnetic field applied perpendicular to the NRM directions. Results were compared to those obtained by the conventional Thelliers' technique. It was found that the modified method gives results as satisfactory as the original method. With the selection of appropriate samples, the modified method will cut down the time required for the experiment to almost half of what is required in the original method, without losing the merits of Thelliers' technique. 相似文献
27.
A three-dimensional numerical model of hydrodynamics and water quality in Hakata Bay 总被引:1,自引:0,他引:1
The hydrodynamics and water quality in Hakata Bay, Japan, are strongly affected by the seasonal variations in both the gravitational circulation and the stratification in the bay. The three-dimensional hydrodynamics and water quality model has been developed to simulate the long-term transport and fate of pollutants in the system. The model is unique in that it completely integrates the refined modelling of the hydrodynamics, biochemical reactions and the ecosystem in the coastal areas. It is a 3-dimensional segmented model which is capable of resolving mean daily variations in all the parameters relevant to pollution control. It predicts daily fluctuations in the oxygen content at different depths in water throughout the year. It takes into account transport and settling of pollutant particles. It predicts light penetration from computed turbidity variations. It includes interactions between the ecosystem and water quality, through nutrient cycling and photosynthesis. The model has been calibrated well against the data set of historical water quality observations in Hakata Bay. 相似文献