The Potential of Eleocharis acicularis for Phytoremediation: Case Study at an Abandoned Mine Site

Phytoremediation, a plant‐based and cost‐effective technology for the cleanup of contaminated soil and water, is receiving increasing attention. In this study, the aquatic macrophyte Eleocharis acicularis was examined for its ability to take up multiple heavy metals and its potential application for phytoremediation at an abandoned mining area in Hokkaido, Japan. Elemental concentrations were measured in samples of E. acicularis, water, and soil collected from areas of mine tailing and drainage. The results reveal that Pb, Fe, Cr, Cu, Ni, and Mn accumulation in the plants increased over the course of the experiment, exceeding their initial concentrations by factors of 930, 430, 60, 25, 10, and 6, respectively. The highest concentrations of Fe, Pb, Zn, Mn, Cr, Cu, and Ni within the plants were 59500, 1120, 964, 388, 265, 235, and 47.4 mg/kg dry wt., respectively, for plants growing in mine drainage after 11 months of the experiment. These results indicate that E. acicularis is a hyperaccumulator of Pb. We also found high Si concentrations in E. acicularis (2.08%). It is likely that heavy metals exist in opal‐A within cells of the plant. The bioconcentration factors (BCF: ratio of metal concentration in the plant shoots to that in the soil) obtained for Cr, Cu, Zn, Ni, Mn, and Pb were 3.27, 1.65, 1.29, 1.26, 1.11, and 0.82, respectively. The existence of heavy metals as sulphides is thought to have restricted the metal‐uptake efficiency of E. acicularis at the mine site. The results of this study indicate that E. acicularis shows great potential in the phytoremediation of mine tailing and drainage rich in heavy metals.     

Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.     

Anisotropic porothermoelastic solution and hydro‐thermal effects on fracture width in hydraulic fracturing

In this study, the effects of the temperature difference between hydraulic fracturing fluid and rock formation on the time‐dependent evolution of fracture width were investigated using a newly derived one‐dimensional anisotropic porothermoelastic analytical solution. The solution is shown to correctly reproduce existing solutions for special cases and corrections for an earlier publication are provided. An analysis of time‐dependent fracture width evolution using Woodford Shale data was also presented. It was found that when the fracturing fluid has the same temperature as the shale formation, the fracture gradually closes back after the initial opening due to the invasion of the fracturing fluid. Practically, in this scenario, proppants should be pumped into the fracture as soon as possible to obtain maximum fracture conductivity. On the other hand, with a fracturing fluid 60 °C colder than the formation, the thermal contraction of the rock dominates the fracture aperture evolution, resulting in a fracture aperture approximately 70% larger than that produced by the hotter fracturing fluid. Consequently, in this case, it is beneficial to delay proppant placement to take advantage of the widening fractures. Finally, it was found that the fracture aperture is directly controlled by the spacing of natural fractures. Therefore, the presence of natural fractures in the shale formation and their spacing influence not only the type of hydraulic fractures created but also what kind and size of proppants should be used to keep them open. Copyright © 2013 John Wiley & Sons, Ltd.     

Palaeo-hydrogeological control on groundwater As levels in Red River delta,Vietnam

To study the geological control on groundwater As concentrations in Red River delta, depth-specific groundwater sampling and geophysical logging in 11 monitoring wells was conducted along a 45 km transect across the southern and central part of the delta, and the literature on the Red River delta’s Quaternary geological development was reviewed. The water samples (n = 30) were analyzed for As, major ions, Fe²⁺, H₂S, NH₄, CH₄, δ¹⁸O and δD, and the geophysical log suite included natural gamma-ray, formation and fluid electrical conductivity. The SW part of the transect intersects deposits of grey estuarine clays and deltaic sands in a 15–20 km wide and 50–60 m deep Holocene incised valley. The NE part of the transect consists of 60–120 m of Pleistocene yellowish alluvial deposits underneath 10–30 m of estuarine clay overlain by a 10–20 m veneer of Holocene sediments. The distribution of δ¹⁸O-values (range −12.2‰ to −6.3‰) and hydraulic head in the sample wells indicate that the estuarine clay units divide the flow system into an upper Holocene aquifer and a lower Pleistocene aquifer. The groundwater samples were all anoxic, and contained Fe²⁺ (0.03–2.0 mM), Mn (0.7–320 μM), SO₄ (<2.1 μM–0.75 mM), H₂S (<0.1–7.0 μM), NH₄ (0.03–4.4 mM), and CH₄ (0.08–14.5 mM). Generally, higher concentrations of NH₄ and CH₄ and low concentrations of SO₄ were found in the SW part of the transect, dominated by Holocene deposits, while the opposite was the case for the NE part of the transect. The distribution of the groundwater As concentration (<0.013–11.7 μM; median 0.12 μM (9 μg/L)) is related to the distribution of NH₄, CH₄ and SO₄. Low concentrations of As (?0.32 μM) were found in the Pleistocene aquifer, while the highest As concentrations were found in the Holocene aquifer. PHREEQC-2 speciation calculations indicated that Fe²⁺ and H₂S concentrations are controlled by equilibrium for disordered mackinawite and precipitation of siderite. An elevated groundwater salinity (Cl range 0.19–65.1 mM) was observed in both aquifers, and dominated in the deep aquifer. A negative correlation between aqueous As and an estimate of reduced SO₄ was observed, indicating that Fe sulphide precipitation poses a secondary control on the groundwater As concentration.     

Turbidites and their association with past earthquakes in the deep Çınarcık Basin of the Marmara Sea

Two gravity cores (CAG-3 and C-15) from the tectonically active, 1,276-m deep Çınarcık Basin of the Marmara Sea each include three sandy turbiditic mud units (1 mm–2 cm thick) with sharp basal contacts. The high benthic foraminifer content of these units suggests that the sediments were transported by turbidity currents from the upper slope region. These units represent the thin edges of turbidites thickening towards the subsiding north-eastern part of the basin, and contain quartz, detrital calcite, intact shells and shell fragments, smectite, pyrite framboids, muscovite, biotite, epidote and garnet. Their clay fractions are more enriched in smectite than those of adjacent layers. AMS 14C ages (957±43 a.d. and 578±31 a.d.) of two upper and middle turbiditic units in core C15 overlap with the historical İstanbul-Thrace (intensity=10) and İstanbul-Kocaeli (intensity=9) earthquakes of 26 October 986 and 15 August 553, respectively. This overlap, together with sedimentological characteristics, strongly suggests that the turbiditic units are related to the tectono-seismic activity of the North Anatolian Fault. The age of the lowest turbiditic unit in core C-3 was found to be 6,573±87 a b.p. (calendar) by AMS 14 C. In terms of chronostratigraphic relationships and lithological composition, the turbiditic units in core CAG-3 cannot be correlated with those in C15. This can be explained by gravity-controlled sedimentation causing wedging out of turbidites towards the edge of the basin.     

An efficient finite–discrete element method for quasi‐static nonlinear soil–structure interaction problems

An efficient finite–discrete element method applicable for the analysis of quasi‐static nonlinear soil–structure interaction problems involving large deformations in three‐dimensional space was presented in this paper. The present method differs from previous approaches in that the use of very fine mesh and small time steps was not needed to stabilize the calculation. The domain involving the large displacement was modeled using discrete elements, whereas the rest of the domain was modeled using finite elements. Forces acting on the discrete and finite elements were related by introducing interface elements at the boundary of the two domains. To improve the stability of the developed method, we used explicit time integration with different damping schemes applied to each domain to relax the system and to reach stability condition. With appropriate damping schemes, a relatively coarse finite element mesh can be used, resulting in significant savings in the computation time. The proposed algorithm was validated using three different benchmark problems, and the numerical results were compared with existing analytical and numerical solutions. The algorithm performance in solving practical soil–structure interaction problems was also investigated by simulating a large‐scale soft ground tunneling problem involving soil loss near an existing lining. Copyright © 2011 John Wiley & Sons, Ltd.     

Multi‐depth monitoring of electrical conductivity and temperature of groundwater at a multilayered coastal aquifer: Jeju Island,Korea

To supplement conventional geophysical log data, this study presents temporal variations in electrical conductivity (EC) and temperature with depth in a multilayered coastal aquifer, on the eastern part of Jeju Island, Korea. One‐month time‐series data obtained at eight points from a multi‐depth monitoring system showed that semidiurnal and semimonthly tidal variations induced dynamic fluctuations in EC and temperature. At some depths, EC ranged from 1483 to 26 822 µS cm^?1, while some points showed no significant variations. The results of EC log and time‐series data revealed that a sharp fresh‐saltwater interface occurred at low tide, but the diffusion zone broadened to 20 m at high tide. EC, temperature, and tide level data were used for the cross‐correlation analysis. The response time of EC and temperature to tide appears to range from less than 30 min to 11 h. Using end‐member mixing analysis (EMMA), the fraction of variations of chloride concentration in the multilayered aquifer was explained, and a conceptual model was developed which subdivided the coastal aquifer into four vertical zones. The percentage of water derived from seawater varied from 2 to 48 at specific depth, owing to tidal fluctuations. Continuous observations of EC and temperature at multiple depths are powerful tools for quantifying the transport of saline water by tidal variations in multilayered coastal aquifers. Copyright © 2008 John Wiley & Sons, Ltd.