Correlative changes in metabolism and DNA damage in turbot (Scophthalmus maximus) exposed to benzo[a]pyrene

Juvenile turbot (Scophthalmus maximus) were injected intraperitoneally with either corn oil or 5 mg/kg benzo[a]pyrene (BaP) dissolved in corn oil and sampled I and 3 days after injection. After 1 day, no elevation of 7-ethoxyresorufin O-deethylase (EROD) activity was observed, however bile metabolites (BaP-7,8 dihydrodiol representing 70% of the total metabolites) and a single hepatic DNA adduct spot (0.47 adducts/10(8) nucleotides) identified by 32P-postlabelling were formed. No BaP metabolites or DNA adducts were observed in either control or carrier control fish. Fish sampled after 3 days reported 5-fold higher (P < 0.05) levels of EROD activity, a shift in the bile metabolite profile towards BaP phenol formation (1OH and 30H BaP comprising up to 60% of total metabolites detected) and the formation of two adduct spots (0.86 and 0.71 adducts/10(8) nucleotides). These results show that BaP can be metabolised and form hydrophobic DNA adducts in turbot without EROD elevation. Following EROD elevation, a shift in the profile of both BaP metabolites and BaP metabolite-DNA interactions occurs indicative of other oxidative processes.     

The spatial distribution of volatiles in the Martian hydrolithosphere

In order to quantify the spatial distribution of volatiles on Mars, 2600 fluidized ejecta craters have been systematically measured, classified and mapped over the planet Mars, using 1 : 2 M scale USGS photomosaics. The latitudinal distribution of ejecta craters reveals that flower ejecta deposits (Type 1), together with low mobility ejecta, are frequently observed in the equatorial region and on ridged plains. Rampart craters (Type 2), with high mobility ejecta, occur at mid latitudes and exhibit a spatial relationship with polygonal patterns and pseudocrater areas. The increase of ejecta mobility with latitude attests for a concentration of volatiles at high latitudes. Statistical analysis shows that cratered uplands and ridged plains contain less volatile material near the surface than the underlying materials. In Chryse Planitia and Utopia Planitia the statistical study and the spatial relationships between polygonally fractured patterns, pseudocraters and the great number of high mobility ejecta deposits suggest the presence of a water-rich alluvial deposit close to the surface near the mouth of Chryse and Elysium channels. This result explains, on a more quantitative basis, the idea that fractured patterns were preferentially developed in a volatile-rich sedimentary deposits. The behaviour of volatiles, at 41 S, 257 W near Reull Vallis, exhibits a strong anomaly, with the presence of an abnormally volatile rich layer close to the surface.     

On the longitudinal distribution of the solar surges

After re-examination of data presented by Verma (1984), some misuse of solar parameteres published in Solar Geophysical Data is presented. Consequently some conclusions made by Verma (1984, 1986) on about the longitudinal distribution of cool solar surges based on these misuses are discussed.     

Stable isotope study of antimony deposits in the Muratdagi region,western Turkey

The Muratdagi region is rich in antimony deposits having the following common characteristics: post Miocene age, location on the down-thrown blocks next to normal faults, in the vicinity of active or fossil thermal springs, and in contact with carbonate rocks. The isotopic composition of — 7. SMOW of the mineralizing fluid calculated from the measured ° ¹⁸O of quartz and the fluid inclusion microthermometry, is indicative of meteoric water origin. The ° ¹³C of the inclusion CO₂ of — 19.1 to — 25.4 PDB is indicative of interaction with organic material-graphite. The ° ³⁴S of stibnite — 3.6 to — 0.7 is, in view of the mineral assemblage, indicative of magmatic origin of the sulphur. A tightly confined set of structural, lithological, hydrological and geochemical features define a sequence of geochemical processes; formation of acid and reducing fluid, leaching and transport of antimony complexes and precipitation of stibnite within defined lithological units. The set of processes seems to have taken place within a space of 5000 m lateral and 1000 m vertical extension.     

Geochemistry and origin of the Proterozoic ultrapotassic rocks of the Churchill Province,Canada

Summary Early Proterozoic ultrapotassic dikes, lava flows, and pyroclastic rocks of the Christopher Island Formation (CIF) erupted throughout an area 600 × 300 km within the Churchill Province of the Canadian Shield at 1.84 Ga. The rocks range from mafic lamprophyres (mg # 60; SiO₂ 47–54%, mean K₂O/Na₂O > 4) with phenocrysts of phlogopite + diopside + apatite ± olivine ± magnetite, to phenocryst-poor felsic rocks and sanidine porphyries (SiO₂55–69%). All samples have high incompatible element contents and display large depletions of high field strength elements relative to K, Rb, Sr, Ba, and Th. The CIF has geochemical and petrographic characteristics of both minettes and lamproites, but overall most closely resembles young Mediterranean lamproites. Felsic rocks of the CIF were produced by crystal fractionation and crustal contamination of mafic ultrapotassic magma, and include both high-silica lamproites strongly enriched in Zr, U, and Th, and weakly potassic to sodic rocks of trachytic composition. Flows and feeder dikes have relatively homogeneous _{Nd, 1840 Ma} (–6 to –11) but highly variable ES., 1840 Ma (–40 to + 100); samples classified as lamproites have higher average _Sr. Dike samples have highly variable present-day Pb isotope compositions, ranging from moderately to strongly nonradiogenic. Geochemical and isotopic data are consistent with contributions from depleted Archean lithospheric mantle, and OIB-type convecting mantle, both metasomatized by subduction-related processes during the Early Proterozoic. The lithospheric mantle probably contained Archean enriched domains as well. Proterozoic enrichment may have accompanied shallow underplating of subducted oceanic lithosphere beneath the Churchill Province during amalgamation of the Laurentian supercontinent. There are strong analogies in isotopic composition, and interpreted source region history, between the CIF and lamproites and minettes of the Wyoming Province and western Greenland, which suggest the existence of a Laurentian ultrapotassic superprovince.

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Geochemie und Entstehung der Proterozoischen ultrapotassischen Gesteine der Churchill Provinz, Kanada

Zusammenfassung Altproterozoische, ultrapotassische Gänge, Lavaströme und pyroklastische Gesteine der Christopher Island Formation (CIF), eruptierten in einem Gebiet von 600 × 300 km in der Churchill Provinz des Kanadischen Schildes vor 1.84 Ga. Die Zusammensetzung dieser Gesteine variiert von mafischen Lamprophyren (mg > 60; SiO₂ = 47–54%, durchschnittliches K₂O/Na₂O > 4) mit Phänokristallent von Phlogopit + Diopsid + Apatit + Olivin + Magnetit, bis zu phänokristallarmen felsischen Gesteinen und Sanidinporphyren (SiO₂ = 55–69%). Alle Proben zeigen hohe Gehalte an inkompatiblen Elementen und zeigen beträchtliche Verarmung an high field strength Elementen relativ zu K, Rb, Sr, Ba und Th. Die CIF hat geochemische und petrographische Eigenschaften sowohl von Minetten wie von Lamproiten, aber im allgemeinen ähnelt sie am stärksten jungen mediterranen Lamproiten. Felsische Gesteine der CIF wurden durch Fraktionierung und Krustenkontamination aus mafischen ultrapotassischen Magmen gebildet. Letztere umfassen sowohl siliziumreiche Lamproite, die deutlich an Zr, U und Th angereichert sind und schwach potassische bis sodische Gesteine von trachytischer Zusammensetzung. Lavenergüsse und zufuhrgänge zeigent ein relativ homogenes _{Nd, 1840 Ma} (–6 bis –11) aber ein sehr variables _{Sr, 1840 Ma} (-40 bis + 100); Proben die als Lamproite klassifiziert wurden, zeigent höhere durchschnittliche _Sr-Werte. Proben von Gängen haben sehr variable Bleiisotopen-Zusammensetzungen, die von mäßig bis stark nichtradiogen variieren. Geochemische und Isotopendaten weisen auf Beiträge aus verarmtem archaischen lithosphärischen Mantel und aus konvektierendem OIB-Typ Mantel hin, die beide während des Alproterozoikums durch Subduktions-Vorgänge metasomatisiert wurden. Der lithosphärische Mantel enthielt wahrscheinlich auch angereicherte archaische Domänen. Proterozoische Anreicherungsvorgänge dürften seichtes Underplating subduzierter ozeanischer Lithosphäre unter der Churchill Provinz während der Amalgamation des laurentischen Superkontinentes begleitet haben. Es gibt starke Analogien in der Isotopenzusammensetzung und in der interpretierten Geschichte der Ursprungsregion, zwischen den CIF und Lamproiten und Minetten der Wyoming Provinz, und des westlichen Grönland. Diese weisen auf die Existenz einer laurentischen ultrapotassischen Superprovinz hin.

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With 7 Figures     

Equation de Szebehely et principes variationnels

Resume On montre l'équivalence entre l'équation de Szebehely du problème inverse et un problème variationnel déduit du principe de Maupertuis.

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Szebehely's equation and principle variations

We show that the inverse problem Szebehely's equations is equivalent to a multiple variation problem deduced from the principle of Maupertuis.

     

Patterns in the Turkish reinsurance claim data, 1998–2002: An application of the extreme value theory

The devastating 1999 Marmara and Düzce earthquakes led to a significant increase in the earthquake studies in Turkey in geological, engineering and financial aspects. Extreme Value Theory (EVT) has a range of applications from stock market changes to natural disasters like floods and hurricanes. Here EVT is fitted to the ordinary and earthquake reinsurance claims of Turkey.     

Paléoenvironnements et caractérisation des roches mères pétrolières des séries pré-salifères du bassin intérieur du Gabon

The Interior Basin of Gabon, created during the break-up between South America and Africa, displays thick Neoproterozoic to Aptian p.p. fluvio-lacustrine deposits overlain by Aptian to Albian marine facies. Rock–Eval analyses from outcrop and drillhole samples show high content in organic matter (up to 25%) related to types I and II. These intervals are encountered within Permian, Neocomian–Barremian as well as Aptian siliciclastic succession. They constitute fairly good to excellent potential petroleum source rocks, which are most probably at the origin of oil indices recognized both in drillholes and in surface.