Isotopic fractionation of methane in the martian atmosphere

The existence of methane in the martian atmosphere may be an indicator of subsurface life. Biological processes are known to fractionate the common isotopologues of methane, and hence measuring these isotopic ratios may yield constraints on the nature of the methane source. Any measurement of the isotopic ratios of atmospheric methane must consider the additional fractionation due to photochemistry in order to quantify the isotopic ratios of the source. Using a one-dimensional photochemical model, we find that photochemistry has a small (4.5‰) contribution to δ¹³C(CH₄) but has a large (114‰) contribution to δD(CH₄). Confirmation of these fractionation values will require additional laboratory data on key model inputs, particularly the ultraviolet absorption cross sections of ¹³CH₄ and kinetic rate coefficients for the reactions of ¹³CH₄ and CH₃D with OH and O(¹D) at pressures and temperatures relevant to the martian atmosphere.     

Influence of circulation parameters on the AOD variations over the Bay of Bengal during ICARB

MODIS (Moderate Resolution Imaging Spectroradiometer) level-3 aerosol data, NCEP (National Centers for Environmental Prediction) reanalysis winds and QuikSCAT ocean surface winds were made use of to examine the role of atmospheric circulation in governing aerosol variations over the Bay of Bengal (BoB) during the first phase of the ICARB (Integrated Campaign for Aerosols, gases and Radiation Budget) campaign (March 18–April 12, 2006). An inter-comparison between MODIS level-3 aerosol optical depth (AOD) data and ship-borne MICROTOPS measurements showed good agreement with correlation 0.92 (p < 0.0001) and a mean MODIS underestimation by 0.01. During the study period, the AOD over BoB showed high values in the northern/north western regions, which reduced towards the central and southern BoB. The wind patterns in lower atmospheric layers (> 850 hPa) indicated that direct transport of aerosols from central India was inhibited by the presence of a high pressure and a divergence over BoB in the lower altitudes. On the other hand, in the upper atmospheric levels, winds from central and northern India stretched south eastwards and converged over BoB with a negative vorticity indicative of a downdraft. These wind patterns pointed to the possibility of aerosol transport from central India to BoB by upper level winds. This mechanism was further confirmed by the significant correlations that AOD variations over BoB showed with aerosol flux convergence and flux vorticity at upper atmospheric levels (600–500 hPa). AOD in central and southern BoB away from continental influences displayed an exponential dependence on the QuikSCAT measured ocean surface wind speed. This study shows that particles transported from central and northern India by upper atmospheric circulations as well as the marine aerosols generated by ocean surface winds contributed to the AOD over the BoB during the first phase of ICARB.     

Aircraft measurements of aerosol black carbon from a coastal location in the north-east part of peninsular India during ICARB

During the Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB) over India, high-resolution airborne measurements of the altitude profiles of the mass concentrations (M_B) of aerosol black carbon (BC) were made off Bhubaneswar (BBR, 85.82°E, 20.25°N), over northwest Bay of Bengal, in the altitude region upto 3 km. Such high-resolution measurements of altitude profiles of aerosols are done for the first time over India. The profiles showed a near-steady vertical distribution of MB modulated with two small peaks, one at 800m and the other at ～2000m. High resolution GPS (Global Positioning System) sonde (Vaisala) measurements around the same region onboard the research vessel Sagar Kanya (around the same time of the aircraft sortie) revealed two convectively well mixed layers, one from ground to ～700m with an inversion at the top and the other extends from 1200m to ～2000m with a second inversion at ～2200m and a convectively stable region in the altitude range 700–1200m. The observed peaks in the M_B profile are found to be associated with these temperature inversions. In addition, long-range transport from the Indo-Gangetic Plain (IGP) and deserts lying further to the west also influence the vertical profile of BC. Latitudinal variation of MB showed a remarkable land ocean contrast at the 500m altitude (within the well mixed region) with remarkably lower values over oceans, suggesting the impact of strong sources over the mainland. However, above the ABL (at 1500m), the latitudinal variations were quite weak, and this appears to be resulting from the impact of long-range transport. Comparison of the altitude profiles of M_B over BoB off BBR with those obtained during the earlier occasion over the inland stations of Hyderabad and Kanpur showed similarities above ～500m, with M_B remaining around a steady value of ～1 μg m^?3. However, large differences are seen within the ABL. Even though the observed M_B values are not unusually high, their near constancy in the vertical column will have important implications to radiative forcing.     

Seasonal dimethylsulfoniopropionate (DMSP) variability in Dona Paula bay

Data on temporal variations of total dimethylsulfoniopropionate (DMSP_t) and the environmental factors that influence DMSP_t concentrations are important in understanding the biogeochemical cycling of organic sulfur compounds. Annual and diurnal variations of DMSP_t were investigated in relation to environmental variables at a fixed station in Dona Paula bay (west coast of India). DMSP concentrations were high in the day and low at night and ranged from 3.69 to 84 nM with a maximum at 17.00 h. The high concentrations of DMSP_t during daytime closely followed that of Chl a concentrations. The DMSP utilizers averaged 0.8 ± 0.3 × 10³ cells l^?1 during night and 0.4 ± 0.1 × 10³ cells l^?1 during the day. The diel variation of DMSP_t was influenced more by biological variables than hydrographic parameters. In the year-round study, the concentrations ranged from 0.69 to 15.8 nM. It was fourfold higher during the southwest monsoon season (13.4 ± 2 nM) and threefold higher during the post-monsoon season (9.96 ± 5 nM) compared to the pre-monsoon season (3.1 ± 1 nM). DMSP_t concentrations showed temporal variability, both during diurnal and annual studies. Diatoms were identified as producers of DMSP in Dona Paula bay. Dinoflagellates also contributed during the non-monsoon seasons. Another factor involved in the variability of DMSP_t was DMSP utilizing bacteria, which ranged from 1 to 10% of the total heterotrophic count.     

Tidal Constituents in the Shallow Waters of the Southwest Indian Coast

A two-dimensional hydrodynamic model was set up and validated for the west coast of India. The spatio-temporal variation of the tidal constituents for a 110 km stretch of the southwest coast of India was then studied by setting up a fine grid model. The study brings out variability in the shallow water constituents and their selective amplification. Within the Cochin estuary, the amplitudes of almost all the major tidal constituents show a gradual reduction upstream compared to other locations. The shallow water constituents show significant amplification and Z0, the constituent related to mean sea level shows five-fold amplification within the estuary.     

Response of Sedimentary Nucleic Acids to Benthic Disturbance in the Central Indian Basin

Information on the response of nucleic acids (i.e., DNA and RNA) to simulated benthic disturbance was obtained from samples collected from eight sediment cores (0–10 cm) located in the Central Indian Basin (CIB). In general the total sedimentary DNA (DNA) increased with depth (from 380.09 to 408.99 μg·g^?1), while total sedimentary RNA (RNA) decreased (from 878.13 to 484.16 μg·g^?1). Following the simulated benthic disturbance brought about by the benthic hydraulic disturber, DNA decreased by 10% along the disturbed track while the RNA increased by around 75%. The RNA/DNA ratio decreased nearly 10%. However, the ratio doubled along the disturbed track suggesting that the activity was stimulated at molecular level following artif icial disturbance. The nucleic acid ratio thus shows that the CIB sediments are metabolically active, and with disturbance the activity tends to increase further.     

Intra-Seasonal Oscillation (ISO) of south Kerala rainfall during the summer monsoons of 1901–1995

Time series of daily averaged rainfall of about 40 rain gauge stations of south Kerala, situated at the southern-most part of peninsular India between latitudes about 8‡N and 10‡N were subjected to Wavelet Analysis to study the Intra Seasonal Oscillation (ISO) in the rainfall and its inter-annual variability. Of the 128 days, 29th May to 3rd October of each of the 95 years 1901-1995 were analysed. We find that the period of ISO does not vary during a monsoon season in most of the years, but it has large inter-annual variability in the range 23 to 64 days. Period-wise, the years cluster into two groups of ISO, the SHORT consisting of periods 23, 27 and 32 days and the LONG with a single period of 64 days, both the sets at a significance level of 99%. During the 95 years at this level of significance there are 44 years with SHORT and 20 years with LONG periods. 11 years have no ISO even at the 90% level of significance. We composited NCEP SST anomalies of the summer monsoon season June to September for two groups of years during the period 1965–1993. The first group is of 5 years with a LONG ISO period of 64 days for south Kerala rainfall at significance level of 99% and the second group is of 12 years with SHORT ISO periods of 23, 27 and 32 days at the same level of significance. The SST anomaly for the LONG (SHORT) ISO resembles that for an El Nino (La Nina).