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61.
Roberto Ventura Santos Edilton J. dos Santos João Adauto de Souza Neto Luis Christian Montreuil Carmona Alcides Nóbrega Sial Luis Henrique Mancini Lauro Cézar Montefalco de Lira Santos Gilzênia Henrique do Nascimento Lucas UpaDafubigin Santos Mendes Emerson Marcello Ferreira Anastácio 《Gondwana Research》2013,23(1):380-389
Strongly-deformed marbles may be easily confused with linear and elongated carbonatite intrusions. Both rocks may present similar texture and foliation to the host rock, or even cross cutting field relationships, which could be interpreted either as igneous or high-grade metamorphosed marble. Diagnostic criteria are even more complex when there is evidence of melting of the metasedimentary carbonate rock, such as has been described in the Himalayas and in the Eastern Ghats, India.In the Alto Moxotó Terrane, a high-grade gneissic domain of the Borborema Province, Northeastern Brazil, there are metacarbonates associated with banded gneisses and different metaplutonic rocks. Field evidence indicates the absence of other metasedimentary rocks associated with these marbles, thus suggesting that these carbonates were separated from other siliciclastic metasedimentary rocks. The presence of marble also suggests that it may represent the initial stage of a crustal carbon recycling into the mantle. These marbles present many field similarities to carbonatites (e.g., fluid-flow structure) and, together with metagranites and metamafic intrusions, may represent a major collisional tectonic suture.A detailed study of the carbon, oxygen and strontium isotopic composition of these marbles is presented. This study aims to identify the origin of the different isotopic components. It is argued that these rocks were subjected to temperature and pressure conditions that were sufficiently high to have melted them. The isotopic data presented here support this interpretation and indicate the mixing of two components: (i) one characterized by radiogenic Sr isotopes and mantle-like carbon isotopes, which is associated with the gneissic and mafic rocks, and (ii) another characterized by low 87Sr/86Sr ratios and highly positive δ13C values. Available geochemical data for the upper Paleoproterozoic indicate that the 87Sr/86Sr ratio of ocean water, varying between 0.7050 (2.25 ± 0.25 Ga) and 0.7047 (1.91 Ga), falls within the lower range of the samples from Itatuba and thus reinforces the interpretation that these marbles are sedimentary-derived and were partially contaminated by interaction with the host gneissic and mafic rocks. 相似文献
62.
Problems of dissolution of the so-called secondary copper sulphides are very important for dynamic as well as percolation leaching of ores. This paper deals with dissolution kinetics of sulphides in an alkaline medium, using complex-forming agents in connection with possibility to leach basic, partially oxidized ores. Natural minerals and their polydispersions were investigated and the so-called geometrical model was used for evaluation. Basic dependences of the dissolution rate on the reagent concentration and pH value of the leaching solution were found and an attempt at their mathematical expression and physical interpretation was made. The first part of this work refers to the systems of covellite-ethylene diamine tetra-acetic acid (EDTA) and covellite-ethylene diamine (EDA). The established dependences are not only of theoretical but also of practical importance. 相似文献
63.
Methylene blue and rhodamine 6G were used as molecular sensors for the spectrophotometric titrations of the aqueous colloids
of clay minerals (montmorillonite, illite and kaolinite). The dyes adsorbed on colloid particles form molecular aggregates,
which exhibit spectral properties significantly different from those of dye solutions. Spectrophotometric titrations provide
the most sensitive detection of smectites in aqueous colloids (sub-ppm concentrations); and the sensitivity further increases
using second derivative spectroscopy. The endpoint of spectrophotometric titrations can be used for the determination of exchange
capacity of the mineral in colloids and in this way to estimate its amount. The method is selective only to expandable clays,
which was proven by experiments with kaolinite and illite. Spectrophotometric titrations have promising future in the analysis
of clays and can be applied in many fields of geology, mineralogy, chemistry, material sciences or in industry. Its application
may expand to the analysis of other nanomaterials built from charged particles and exhibiting metachromasy in the systems
with organic dyes. 相似文献
64.
M. G. García K. L. Lecomte Y. Stupar S. M. Formica M. Barrionuevo M. Vesco R. Gallará R. Ponce 《Environmental Earth Sciences》2012,65(2):535-545
Symptoms of dental fluorosis have been observed in rural communities located in the Sierras Pampeanas de Córdoba, a mountainous
area in Central Argentina. The clinical assessment was performed in the Charbonier Department, where the fluoride (F−) intake was determined to be 3.90 ± 0.20 mg day−1 (n = 16). In this community, mild and severe fluorosis reach an incidence of 86.7% (total teeth surface = 636 teeth) among the
children population. To determine the origin and distribution of fluorine in natural waters from the Charbonier Department
and nearby regions, sampling was performed in the area covering the San Marcos River basin. The obtained results show that
F− concentrations vary between ~1 to ~2.5 mg l−1, with an outlier value of 8 mg l−1. The spatial distribution of F− shows that the lowest concentrations are found at the basin’s catchments. Maximum values are located in two sectors of the
basin: the Charbonier depression in the eastern part and at the San Marcos village, downstream the main collector, in the
western part of the basin. In these two regions, the F− contents in ground- and surface waters are >2.0 mg l−1 and nearly constant. Dissolved F− in natural waters from the study area has its origin in the weathering of F-bearing minerals present in the region’s dominant
lithology. The extent of mineral weathering is mostly determined by the residence time of water within the aquatic reservoir.
Longer residence times and a major solid–water interaction lead to enhanced release of F−. This explains the higher F− concentrations found in basin areas with lower run off. The removal of F− from water appears to occur by neither fluorite precipitation, nor by adsorption. Hence, variations in F− concentrations seem to be more related to regional hydrological conditions. 相似文献
65.
Terrinha Pedro Pueyo Emilio L. Aranguren Aitor Kullberg José Carlos Kullberg Maria Carla Casas-Sainz Antonio Azevedo Maria do Rosário 《International Journal of Earth Sciences》2018,107(5):1807-1833
International Journal of Earth Sciences - The geometry and emplacement of the ~ 96 km2, Late Cretaceous Sintra Igneous complex (SIC, ca. 80 Ma) into the West Iberian passive... 相似文献
66.
Ramacciotti Carlos D. Casquet César Baldo Edgardo G. Galindo Carmen Pankhurst Robert J. Verdecchia Sebastián O. Rapela Carlos W. Fanning Mark 《International Journal of Earth Sciences》2018,107(7):2605-2625
International Journal of Earth Sciences - The Western Sierras Pampeanas (WSP) of Argentina record a protracted geological history from the Mesoproterozoic assembly of the Rodinia supercontinent to... 相似文献
67.
Péter Ozsvárt Lajos Dosztály Georgios Migiros Vassilis Tselepidis Sándor Kovács 《International Journal of Earth Sciences》2012,101(6):1487-1501
The Avdella Mélange in the northern Pindos Mountains and its equivalent formation, the Loggitsion Unit in the Othris Mountains expose early Mesozoic (Mid-Late Triassic) oceanic fragments beneath the Western Greek Ophiolite Belt of the Inner Hellenides, Northern Greece. The mélange consists of locally interfingering blocks and slices of ribbon radiolarite, radiolarian chert and pillow basalt and is usually overthrust by Jurassic ophiolites. New Middle and Upper Triassic radiolarian biostratigraphic data are presented from radiolarites and basalt-radiolarite sequences within mélange blocks. Pillow basalts associated with the radiolarites provide clues to the opening of the Neotethyan ocean basin. The radiolarians indicate a Middle Triassic age (latest Anisian, probably early Illyrian), which is documented for the first time in the northern Pindos Mountains. The new radiolarian biostratigraphic data suggest that rift-type basalt volcanism already began in pre-Ladinian time (late Scythian?—Anisian). These basalts were then overlain by Upper Anisian to Carnian (?Norian) radiolarites. 相似文献
68.
Jaroslava Hajná Ji?í ?ák Václav Kachlík Martin Chadima 《International Journal of Earth Sciences》2012,101(7):1855-1873
The Teplá–Barrandian unit (TBU) has long been considered as a simply bivergent supracrustal ‘median massif’ above the Saxothuringian subduction zone in the Variscan orogenic belt. This contribution reveals a much more complex style of the Variscan tectonometamorphic overprint and resulting architecture of the Neoproterozoic basement of the TBU. For the first time, we describe the crustal-scale NE–SW-trending dextral transpressional Krakovec shear zone (KSZ) that intersects the TBU and thrusts its higher grade northwestern portion severely reworked by Variscan deformation over a southeastern very low grade portion with well-preserved Cadomian structures and only brittle Variscan deformation. The age of movements along the KSZ is inferred as Late Devonian (~380–370?Ma). On the basis of structural, microstructural, and anisotropy of magnetic susceptibility data from the KSZ, we propose a new synthetic model for the deformation partitioning in the Teplá–Barrandian upper crust in response to the Late Devonian to early Carboniferous subduction and underthrusting of the Saxothuringan lithosphere. We conclude that the Saxothuringian/Teplá–Barrandian convergence was nearly frontal during ~380–346?Ma and was partitioned into pure shear dominated domains that accommodated orogen-perpendicular shortening alternating with orogen-parallel high-strain domains that accommodated dextral transpression or bilateral extrusion. The synconvergent shortening of the TBU was terminated by a rapid gravity-driven collapse of the thickened lithosphere at ~346–337?Ma followed by, or partly simultaneous with, dextral strike-slip along the Baltica margin-parallel zones, driven by the westward movement of Gondwana from approximately 345?Ma onwards. 相似文献
69.
Francisco González-Sánchez Antoni Camprubí Eduardo González-Partida Rafael Puente-Solís Carles Canet Elena Centeno-García Viorel Atudorei 《Mineralium Deposita》2009,44(3):343-361
Northeastern Mexico hosts numerous epigenetic stratabound carbonate-hosted low-temperature hydrothermal deposits of celestine,
fluorite, barite and zinc-lead, which formed by replacement of Mesozoic evaporites or carbonate rocks. Such deposits can be
permissively catalogued as Mississippi Valley-type (MVT) deposits. The deposits studied in the state of Coahuila are associated
with granitic and metasedimentary basement highs (horsts) marginal or central to the Mesozoic Sabinas Basin. These horsts
controlled the stratigraphy of the Mesozoic basins and subsequently influenced the Laramide structural pattern. The Sabinas
Basin consists of ~6,000-m-thick Jurassic to Cretaceous siliciclastic, carbonate and evaporitic series. The MVT deposits are
mostly in Barremian and in Aptian-Albian to Cenomanian formations and likely formed from basinal brines that were mobilized
during the Laramide orogeny, although earlier diagenetic replacement of evaporite layers (barite and celestine deposits) and
lining of paleokarstic cavities in reef carbonates (Zn–Pb deposits) is observed. Fluid inclusion microthermometry and isotopic
studies suggest ore formation due to mixing of basinal brines and meteoric water. Homogenization temperatures of fluid inclusions
range from 45°C to 210°C; salinities range from 0 to 26 wt.% NaCl equiv., and some inclusions contain hydrocarbons or bitumen.
Sulfur isotope data suggest that most of the sulfur in barite and celestine is derived from Barremian to Cenomanian evaporites.
Regional geology and a compilation of metallogenic features define the new MVT province of northeastern Mexico, which comprises
most of the state of Coahuila and portions of the neighboring states of Nuevo León, Durango and, perhaps extends into Zacatecas
and southern Texas. This province exhibits a regional metal zonation, with celestine deposits to the south, fluorite deposits
to the north and barite and Zn–Pb deposits mostly in the central part. 相似文献
70.
Patricia Vázquez Ana Luque Francisco J. Alonso Carlota M. Grossi 《Environmental Earth Sciences》2013,69(4):1237-1248
This study assesses the changes on the surface of crystalline stones due to salt crystallisation. Efflorescence was forced to grow on the surface of granite and marbles through 60 cycles of salt crystallisation with sodium sulphate. Changes on surface roughness, gloss and colour were measured every 15 cycles and the specimens were examined with naked eye and SEM. Sodium sulphate produces damage which depends on mineral composition. Results show that granites experience a mechanical decay with an increase in roughness. Peaks of mica can be observed on the surface and cracks widen and grow deeper. Colour and gloss do not show any significant change, although gloss decreases with an increase in surface roughness. In marbles, the decay is mainly chemical. Surface roughness increases due to dissolution of the calcite. White marbles exhibit yellowing. Gloss decreases during the first cycles—as grain boundaries become more visible—but tends to regain almost its initial value as the number of cycles increases. In this case, gloss does not show any relation with surface roughness. 相似文献